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The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process.
a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.
10 g of h2 and 64 g of o2 are filled in a steel vessel and exploded amount of water produced in this reaction
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This is an acid-catalyzed addition to the double bond much like hydration, except that an alcohol rather than water is the nucleophile that reacts with the carbocation intermediate
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