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The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process.
a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.
A gas contains 350 ppm of H 2 S in CO 2 at 72°F and 1.53 atm pressure. If the gas is liquified, what is the weight fraction H 2 S? You are asked to make up a laboratory soluti
Calculate the pressures required to achieve a density of 220 g dm -3 , 330 g dm -3 , and 440 g dm -3 at temperatures of 305 K and 350 K. Properties, like the solvent powe
Compare the combustion energy stored in a 1 litre bottle of propane and butane. Suppose that the product temperature is 100°C. The density of liquid propane is 0.493 g cm -3
The formation of energy bonds in solids are in accordance with: (1) Heisenberg's uncertainty principle (2)Bohr's theory (3 )Ohm's law (4) Rutherford's atomic model
What are total variables and degrees of freedom of a system of two components, when the number of phases is one, two, three etc.? Ans: For two - component systems, degree of
Q. Define the Normality of solutions? Ans. Sometime normality is used to measure concentration. Normality (abbreviated N) is the number of gram-equivalent masses of solute in 1
do u do prac Report?
1. The pH of a 0.02 M solution of an acid was measured as 4.6. a) What is the [H + ] of the solution? b) What is the acid dissociation constant K an
Q. What are the rules used for round off numbers? 1. If the digit to the instantaneous right of the last significant figure is less than five don't change the last significan
diagonal relationship between b ans si
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