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The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process.
a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.
conclusion for chemistry in medicine
The angle among the lines joining the nuclei of the bonded atom with a central atom is known as bond angle.
Calculate the free energy change of following reaction at298 kelvin H2+I2=2HI if the enthalpy change is 51.8816kj and the entropy change is 166.15j is this reaction thermodyanamica
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