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The second law states that where dS ≥ dQ/T for a reversible process and dS = dQ/T for an irreversible process.
a. Show that since dW12 = -dW21 (dWreverse = -dWforward) for a reversible process, then dQ12 = TdS12
b. An egg, initially at rest, is dropped onto the floor. Prove that this process is irreversible. You can assume that the egg returns to its initial temperature after it breaks.
This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other. Thus, it must be a [14s + 2a] or a [14a + 2s]
8ml of NaOH solution were used to titrate 10ml of H2C2O4.2H2O,C(1/2H2C2O4.2H2O)=0.05ML.
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Explain in words why hydroboration leads to anti-Markovnikov addition of hydrogen whereas most electrophilic addtions to alkenes result in Markovnikov addition.
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