prefixes, Chemistry

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why we consider methyl using prefixes?

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Which of the following sets of quantum number is not possible: (1) n=3, l=+2, m=0,and s = +1/2     (2) n=3, l=0, m=0,and s = -1/2     (3) n=3, l=0, m=-1,and s = +1/2

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