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Q. Explain what do you understand by the terms potential well and potential barrier. How does a particle with energy lesser than the barrier height tunnels through its quantum mechanically? Give one example.
Sol. Consider a particle of energy E is incident from the left on a rectangular potential barrier of height and width and on both sides of this barrier at which means that no force act upon the particle in this regions. Therefore, the potential function is defined as if a particle having energy E less than then classically the particle will always be reflected completely and hence will not penetrate the barrier. But according to wave mechanics the particles has some probability of penetrating this barrier and appear in region III.
This is called quantum mechanical tunneling or tunnel effect. According to this, if a particle is moving towards the barrier with energy E less than the height of potential barrier, then it is not necessary to reflect completely by the barrier but there is always a probability of particle to cross the barrier and continue its forward motion.
Calculate the heat required to melt 316.7kg of potassium metal at 336 K. The enthalpy of fusion of potassium is 2.35 kJ mol -1 .
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