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Being simultaneously basic and acidic, water undergoes autoprotolysis, also called self-ionization:
The equilibrium constant is
H3O+ in these equations is general simply written H+. In pure water and in solutions that do not give any additional source of H+ or OH- both ions have molar concentrations exact to 10-7. Addition of an acid decreases [OH-] and hence increases [H3O+]; addition of a base has the reverse effect.
The pH scale is defined by
Neutral water has a pH of 7, acidic solutions have lower values of ph (typically 0-7), and basic solutions or alkaline higher values (7-14). In alkaline or basic solutions [OH-] is thus greater than [H+].
Strong and weak behavior
The equilibrium constant of the protolysis reaction
is known as the acid dissociation constant (Ka) of HA or the acidity constant:
It is often expressed as a pKa value, described as
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which is more acidic among o-methoxy benzoic acid and m-methoxy benzoic acid Ans) o-methoxy benzoic acid is more acidic than m-metoxy benzoic acid.
Benzyne - organic chemistry (1) 1, 2-Didehydrobenzene, C 6 H 6 and its derivatives are known as benzyne or arynes and the simplest member is benzyne. (2) It is neutral re
200 g of water at 30 degrees C is mixed with 20 g of silver at 350 degrees C, what''s the final temp?
Which quantum number will determine the shape of the subshell: (1) Principal quantum number (2) Azimuthal quantum number (3) Magnetic quantum number (4)Spin quantum nu
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Cu 2+ will have the following electronic configuration: (1) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 10 , (2) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 9 , 4s 1 (3) 1s 2 , 2s 2 ,
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