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Being simultaneously basic and acidic, water undergoes autoprotolysis, also called self-ionization:
The equilibrium constant is
H3O+ in these equations is general simply written H+. In pure water and in solutions that do not give any additional source of H+ or OH- both ions have molar concentrations exact to 10-7. Addition of an acid decreases [OH-] and hence increases [H3O+]; addition of a base has the reverse effect.
The pH scale is defined by
Neutral water has a pH of 7, acidic solutions have lower values of ph (typically 0-7), and basic solutions or alkaline higher values (7-14). In alkaline or basic solutions [OH-] is thus greater than [H+].
Strong and weak behavior
The equilibrium constant of the protolysis reaction
is known as the acid dissociation constant (Ka) of HA or the acidity constant:
It is often expressed as a pKa value, described as
Q. Describe properties and uses of different silicate glasses and also discuss the importance of annealing in the manufacture of glass.
Given that dH for the reaction is -92.2 kJ mol-1, which is larger, the total bond dissociation energy of the reactants or the total bond dissociation energy of the products?
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