periodic table, Chemistry

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Which of the following sets of quantum number is not possible: (1) n=3, l=+2, m=0,and s = +1/2     (2) n=3, l=0, m=0,and s = -1/2     (3) n=3, l=0, m=-1,and s = +1/2

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This cycloaddition reaction involves sixteen electrons; hence, it must be suprafacial on one component and antarafacial on the other.  Thus, it must be a [14s + 2a] or a [14a + 2s]

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