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Nebulisation techniques:
The accuracy, precision and detection limits of flame AAS depend on how the analyte sample is introduced into the atomiser. We need to transfer a reproducible and representative portion of a sample into an atomiser which depends on the physical and chemical state of the analyte and the sample matrix. The sample introduction is achieved with the help of a nebuliser. The generally used nebulisation techniques are ultrasonic nebulisation, pneumatic nebulisation, electrothermal vaporisation and hydride generation.
Atomic absorption spectrophotometry (AAS) is now a routinely and widely employed technique for trace and ultratrace analysis of complex matrices of geological, biological, glass, environmental, industrial, cement, marine sediment, pharmaceutical, engine oil or any other kind of samples. An atomic absorption techniques using flame are rapid and precise and are applicable to about 67 elements. The electrothermal methods of analysis instaed are slower and less precise; thus, these are more sensitive and require much smaller samples
The elements of this group form a number of compounds with halogens. The halogen compounds of S. Se, Te and Po are called as halides. For oxygen, only the fluoro compounds
molecular chlorine and molecular fluorine combine to form a gaseous product.Under the same conditions of temperature and pressure it is found that one volume of Cl2 reacts with thr
role of modifiers in solvent extraction of metal ion
A completely filled d -orbital ( d 10 ): (1) Spherically symmetrical (2) Has octahedral symmetry (3) Has tetrahedral symmetry (4) Depends on the atom Ans: Spherical
The electronic configuration of copper (29 cu) is: (1)1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 9 , 4s 2 (2) 1s 2 , 2s 2 , 2p 6, 3s 2 , 3p 6 , 3d 10 , 4s 1 (3) 1s 2 , 2s
strain theory
If an electron has spin quantum number of +1/2 and a magnetic quantum number of -1 , it cannot be presented in an: (1) d -orbital (2) f -orbital (3) p -orbital (4)s-
Iso-electronic species is: (1) F - ,O -2 (2) F - , O (3) F - , O + (4) F - , O +2 Ans: F - ,O- 2
show work is path function
What is linear geometry The beryllium (Be) bears two groups, and thus has linear geometry. The H-Be-H bond angle is 180°.
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