mixture analysis, Chemistry

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why HNO3 is not used for detection of acidic radicals of 1st and 2nd group?

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The order of filling of electrons in the orbitals of an atom will be : (1) 3d, 4s, 4p, 4d, 5s,                        (2)  4s, 3d, 4p, 5s, 4d        (3) 5s, 4p, 3d, 4d, 5s

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