metallic bonding, Chemistry

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The Crystal Field Theory experiment shows the effects on metal d orbital energies of moving a set of negative point charges close to a metal ion. As one would expect, the energies

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Which of the following sets is possible for quantum numbers : (1) n=4, l=3, m= -2 , s=0  (2) n=4, l=4, m= +2 , s=1/2           (3) n=4, l=3, m= -2 , s=+1/2          (4)

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