Ionic polarization, Physics

Assignment Help:

The contribution of ionic polarization takes account of the fact that when in a molecule some of the atoms have an excess positive or negative charge (resulting from the ionic character of the bonds),an electric field tend to shift positive ions relative to negative ones. This leads to an induced moment of other origin from the moment induced by electron clouds shifting relative to nuclei. In this case a solid material should have some ionic character. It then automatically has internal dipoles, exactly cancels each other and is unable to rotate. The external field them induces net dipoles by slightly displacing the ions from their rest position. The paradigmatic materials are simple ionic crystal like NaCl. The polarization of a given volume, though, is exactly zero as for every dipole moment there is a neighbouring one with exactly the same magnitude, but with opposite sign. Note that the dipoles cannot dipoles, their direction is permanent. In electric field, the ions feel forces in opposite directions. The Na+ ions moved a bit to the right, the Chlorine ions to the lift. The dipoles moments between adjacent NaCl pairs in field direction are now different and there is a net dipole moment in a finite volume now. It can be observed that it is enough to take one dipole in field direction.


Related Discussions:- Ionic polarization

Joules laws, Joule's laws (J.P. Joule) Joule's first law The he...

Joule's laws (J.P. Joule) Joule's first law The heat Q generated while a current I pass through a resistance R for a particular time t is given by following Q = I2 R

Micrometer simulation, Micrometer Simulation A Micrometer is used to me...

Micrometer Simulation A Micrometer is used to measure the external dimensions of objects that are 3 cm or smaller, this provides precise measurements to inside 0.01 mm. The

Capacitor, explain the capacitance of spherical capacitor when the inner su...

explain the capacitance of spherical capacitor when the inner surface is earthed

Specific heats of gases, Specific heat of a gas is numerically equivalent t...

Specific heat of a gas is numerically equivalent to the amount of heat essential to raise the temperature of unit mass of gas by 1 0 C. In order to raise the temperature of unit ma

Batteries used in the torch lights, Can the batteries used in the torch lig...

Can the batteries used in the torch lights be recharged after their discharge? Give reason? Ans) No,because the NH4Cl corrods the zn containger gradually.so with out anode redox

Determination of packing fraction of diamond, Determination of packing frac...

Determination of packing fraction of diamond  The co-ordination number of an atom in diamond structure is 4 as can be seen from the unit cell of diamond and is loosely packed.

Explain passive network, Passive network:- It can be described as a net...

Passive network:- It can be described as a network, which contains no source of e.m.f. in it.

Optical rotation, expression of optical rotation based on his assumptions

expression of optical rotation based on his assumptions

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd