Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Ion mobility:
Ion mobility is related to molar conductivity by the equations:
which allows the mobilities, u+ and u- of the cation and anion to be determined from molar conductivity measurements at and away from infinite dilution. z+ and z- are the formal charges of the cation and anion respectively, so z+F and |z-F| are the magnitudes of the charges on a mole of cations and anions. The mobility is always positive (+) and is a measure of the terminal migration speed of an ion per unit applied electric field. This limiting speed is accelerating due to the field is exactly balanced by the viscous drag of the ions moving through the solution which for a spherical ions lead to the equations:
where e is the charge on the electron (-), so ze is the charge on the ions, η is the viscosity, a constant for any solvents which determines how easy it is for the ion to part the solvent molecule and move through solution and a is the hydrodynamic radius of the solvated ion.
H+/OH- mobility:
Hydroxide and Protons ions have anomalously high ionic molar conductivities and mobilities in comparison to all ions, and in particular for their size. That is as a result of the mechanism by which they move through solution, called the Grotthus mechanism (Fig. 1).
Fig. 1. The Grotthus mechanism for (a) H+; (b) OH- ion motion in water. The arrows indicate the concerted proton movement when the field is applied.
chemical bonding
(a) Describe how you would carry out a series of experiments to determine the molar conductivities (Λ m ) of an electrolyte at various concentrations, starting with the measurement
what are the limitations of third law of thermodynamics. what is thermodynamics third law.
Define the process of Metallization - fabrication processes It's the process of providing electrical connections between different parts of the circuit. Aluminium is common
classification of lubricants
How much NaCl is needed to prepare a 0.5 solution of 5 Ltires?
The orbital angular momentum of an electron in 2s -orbital is: (1) 1/2 h/ 2Π (2) h/ 2Π (3) √2 h/ 2 Π (4) Zero Ans
difference between scales and sludge
Unlike components of the 3 d series, 4 d and 5 d elements have little simple aqueous cationic chemistry. The main exceptions are La3+ and Y3+, and Ag+, which builds some soluble
Chloroform
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd