Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Ion mobility:
Ion mobility is related to molar conductivity by the equations:
which allows the mobilities, u+ and u- of the cation and anion to be determined from molar conductivity measurements at and away from infinite dilution. z+ and z- are the formal charges of the cation and anion respectively, so z+F and |z-F| are the magnitudes of the charges on a mole of cations and anions. The mobility is always positive (+) and is a measure of the terminal migration speed of an ion per unit applied electric field. This limiting speed is accelerating due to the field is exactly balanced by the viscous drag of the ions moving through the solution which for a spherical ions lead to the equations:
where e is the charge on the electron (-), so ze is the charge on the ions, η is the viscosity, a constant for any solvents which determines how easy it is for the ion to part the solvent molecule and move through solution and a is the hydrodynamic radius of the solvated ion.
H+/OH- mobility:
Hydroxide and Protons ions have anomalously high ionic molar conductivities and mobilities in comparison to all ions, and in particular for their size. That is as a result of the mechanism by which they move through solution, called the Grotthus mechanism (Fig. 1).
Fig. 1. The Grotthus mechanism for (a) H+; (b) OH- ion motion in water. The arrows indicate the concerted proton movement when the field is applied.
Show by means of equations and reagents, how the following conversion would be achieved? Propyne to butanoic acid
Give the example of inductomeric effect.
Physical properties of Ethers - Boiling points and Solubility (a) Boiling points: Boiling points of ethers are very much lower as compared to those of isomeric alcohols, althou
Q. Illustrate the structure of Alkanes? Ans. Alkanes have the general formula C n H 2n+2 . This means that for every n atoms of carbon, there are 2n + 2 atoms of hydrogen.
when H+ is removed from any compound it forms conjugate acid. the addition of H+ ion gives conjugate base.
what are the assumpions made in valence bond theory
Explain stereochemistry a) The stereochemistry is E. The Br has higher priority on one carbon stereocenter, but it has lower priority on the other. b) The stereochemistry is
In the transition of Zn atoms to Zn ++ ions there is a decrease in the: (1) Number of valency electrons (2) Atomic weight (3) Atomic number (4) Equivalent weight A
complete assignment for half life determination
Tests of phenol - Hydrocarbon (a) Aqueous solution of phenol gives a violet colouration with a drop of ferric chloride. (b) Aqueous solution of phenol gives a white precipit
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +1-415-670-9521
Phone: +1-415-670-9521
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd