Already have an account? Get multiple benefits of using own account!
Login in your account..!
Remember me
Don't have an account? Create your account in less than a minutes,
Forgot password? how can I recover my password now!
Enter right registered email to receive password!
Ion mobility:
Ion mobility is related to molar conductivity by the equations:
which allows the mobilities, u+ and u- of the cation and anion to be determined from molar conductivity measurements at and away from infinite dilution. z+ and z- are the formal charges of the cation and anion respectively, so z+F and |z-F| are the magnitudes of the charges on a mole of cations and anions. The mobility is always positive (+) and is a measure of the terminal migration speed of an ion per unit applied electric field. This limiting speed is accelerating due to the field is exactly balanced by the viscous drag of the ions moving through the solution which for a spherical ions lead to the equations:
where e is the charge on the electron (-), so ze is the charge on the ions, η is the viscosity, a constant for any solvents which determines how easy it is for the ion to part the solvent molecule and move through solution and a is the hydrodynamic radius of the solvated ion.
H+/OH- mobility:
Hydroxide and Protons ions have anomalously high ionic molar conductivities and mobilities in comparison to all ions, and in particular for their size. That is as a result of the mechanism by which they move through solution, called the Grotthus mechanism (Fig. 1).
Fig. 1. The Grotthus mechanism for (a) H+; (b) OH- ion motion in water. The arrows indicate the concerted proton movement when the field is applied.
The assignment is basically concerned with the writing of a number of functions which can implement the density theory described above. These functions will then be called by a pro
Chemical methods - Purification of organic compounds Besides these physical methods, few chemical methods have as well been utilized to separate a mixture of organic compounds.
Titration introductions,Objective,Literature,Method ,Discussion ,Conclusion and References.
The number of unpaired electrons in a chromic ion Cr 3+ (atomic number = 24) is: (1) 6 (2) 4 (3) 3 (4) 1 Ans: 3
Explain experimental evidence to demonstrate the existence of ferromagnetic domains. Temperature increases, thermal motion, or entropy, competes with ferromagnetic tendency for
between nitrobenzene and phenol which is more reactive towards chlorine and why? Upon reaction with chlorine what products can be formed from the two reactions.
Initially 5 mol of an ideal gas with Cv,m=12.5 J K^-1 mol^-1 are at a volume of 5 dm^3 and a temperature of 300K. If the gas is heated to 373 K and the volume changed to 10 dm^3, w
Why cyclo propane is more stable than cyclohexane
Which among the following species have the same number of electrons in its outermost as well as penultimate shell: (1) Mg 2+ (2) O 2-
(a) Given the values below, Determine the concentration of benzoyl peroxide needed to prepare polystyrene with a number average molar mass of 400,000 by bulk free radical polymeris
Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!
whatsapp: +91-977-207-8620
Phone: +91-977-207-8620
Email: [email protected]
All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd