Inductive effect - relative reactivity of aldehydes and keto, Chemistry

Assignment Help:

Inductive effect - Relative reactivity of aldehydes and ketones

The comparative re-activities of aldehydes and ketones in nucleophilic addition reactions might be attributed to the amount of positive charge on the carbon. As a higher positive charge seems a higher reactivity. Determine if the positive charge is detached throughout the molecule, the carbonyl compound turns out to be much more stable and its reactivity decreases. Here now, alkyl set is an electron releasing group (+I inductive effect). Hence, electron releasing energy of two alkyl groups in ketones is much more than that of one alkyl set in aldehyde. Since a product, the electron deficiency of carbon atom in the carbonyl group is satisfied much more in ketones as compared to in aldehydes. Hence, the replaced positive charge on carbon in case of ketones discourages the attack of nucleophiles. Therefore ketones are minimum reactive as compared to aldehydes. Formaldehyde correlated to no alkyl sets is the most reactive of the aldehydes and ketones. So, the order of reactivity is:

399_Inductive effect.png


Related Discussions:- Inductive effect - relative reactivity of aldehydes and keto

Chemical reactivity of alkynes - hydrocarbon, Chemical reactivity of alkyne...

Chemical reactivity of alkynes - Hydrocarbon C Ξ C is less reactive as compared to the carbon-carbon double bond in the direction of electrophilic addition reaction. This is re

Palatable inorganic acids other than phosphoric acids, Are there any other ...

Are there any other palatable inorganic acids other than phosphoric acid? I need it because I on a research for finding food replacing plants ---- us becoming autotrophs. I am on t

Hydrogen isotopes, chemical properties of protium,deuterium and tritium..

chemical properties of protium,deuterium and tritium..

In semiconductors why we use only pentavalent or trivalent?, Penta valent ...

Penta valent element has one electron more than 4 electrons which could be used for conduction while the trivalent elements has 1 electron less , this can also be seen as a hole

Metallurgy, Ask question #Minimum 1000! words accepted#

Ask question #Minimum 1000! words accepted#

Illustrate structure of the water molecule, Q. Illustrate Structure of the ...

Q. Illustrate Structure of the Water Molecule? Ans. A water molecule is composed of two hydrogen atoms and one oxygen atom covalently bonded together. The following anim

Difference between thermoplastic and thermosetting polymers, Difference bet...

Difference between thermoplastic and thermosetting polymers Thermoplastic polymers Thermosetting polymers (1) Thermoplastic polymers

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd