How tetrahedral complex splitting takes place?, Chemistry

Assignment Help:

The tetrahedral arrangement of four ligands surrounding the metal ion may be visualized. It is clear that in tetrahedral field, none of the orbitals point exactly towards the ligands and therefore, the splitting of energy will be less that in octahedral field. The tree d-orbitals dxyand dyz and dzx are pointing close to the direction in which the ligands are approaching while the two orbitals  244_Untitled.png  and  942_Untitled.png  are lying in between the ligands. Therefore, the energies of the three orbitals will be raised while the energies of the two orbitals will be lowered. Thus, in the presence of octahedral field, the degeneracy of five d-orbitals splitting as:
    
The two orbitals,  244_Untitled.png  and  942_Untitled.png  becomes stable and their energies are lowered. These are designated as 'e' orbitals.
    
The three orbitals, dxy, dyz and dzx become unstable and their energies are raised. These are designated as 't2' orbitals. 

The magnitude of crystal field splitting is the difference between e and t2 orbitals and is designated as Δt, (the subscript indicating tetrahedral complexes). It is also measured in terms of Dq and Δt, = 10 Dq. If we compare the magnitude of crystal field splitting in octahedral and tetrahedral complexes (having same metal ion, ligands and metal ion-ligand distances), it has been observed that the crystal field splitting in octahedral complexes t) is considerably less than in octahedral complexes 0). It has been found to be Δt = 4/9 Δ0.

There are two main reasons for the smaller value of crystal field splitting in tetrahedral than in octahedral complexes.
    
In tetrahedral complexes there are four ligands while there are six ligands in octahedral complexes. Therefore, lesser ligands produce less crystal field splitting. The crystal field splitting in tetrahedral field is about two third of the octahedral field.
    
In tetrahedral field, none of the orbitals is pointing directly towards the ligands and, therefore, splitting is less.

Since the magnitude of crystal field splitting in tetrahedral field is quite small and is always less the pairing energy, therefore, the pairing of electrons will never be energetically favourable. Thus; all the tetrahedral complexes are high spin complexes. No tetrahedral complex with low spin has been found to exist. 

 

 

 


Related Discussions:- How tetrahedral complex splitting takes place?

Purification and nomenclature of organic compound, Modern Meaning of Organi...

Modern Meaning of Organic Chemistry Organic chemistry is a chemistry of hydrocarbons and their derivatives where covalently bonded carbon is a necessary constituent. Berzelius

Rusting of iron, How rusting of iron is envisaged as setting up of an elect...

How rusting of iron is envisaged as setting up of an electrochemical cell? Solution) Rusting of Iron is due to corossion. Rust is an Fe 2 O 3 .xH 2 O Theory of Rusting :

Sulphur, why does the sulphur has three different valency

why does the sulphur has three different valency

Calculate standard state enthalpy of the substance, Q. Calculate standard s...

Q. Calculate standard state enthalpy of the substance? Ans. To determine ΔH o f for calcium carbonate, calcium and carbon are burned in a calorimeter. Noti

Illustrate relative amounts of two co-existing phases, Illustrate that...

Illustrate that  for  correct  mass  balance,  relative  amounts  of  two  co-existing  phases  or microconstituents must be given by lever principle. Ans:   Using  lever  rule

Describe the scope of emission spectrometric methods, Problem 1: Descri...

Problem 1: Describe TDM and mention its clinical significance in clinical practice. Definition of TDM Show the importance of TDM and its clinical significance in clini

Oxidation no., how to count two oxidation no. of Cl in Ca(OCl)Cl?

how to count two oxidation no. of Cl in Ca(OCl)Cl?

Biochemistry.., why dietry iodine is important in thyroid functioning

why dietry iodine is important in thyroid functioning

Physical properties of monohydric alcohols, Physical properties of monohydr...

Physical properties of monohydric alcohols (a) Character - Monohydric Alcohols are neutral component. These comprise no effect on litmus paper. This is analytical investigation

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd