How tetrahedral complex splitting takes place?, Chemistry

Assignment Help:

The tetrahedral arrangement of four ligands surrounding the metal ion may be visualized. It is clear that in tetrahedral field, none of the orbitals point exactly towards the ligands and therefore, the splitting of energy will be less that in octahedral field. The tree d-orbitals dxyand dyz and dzx are pointing close to the direction in which the ligands are approaching while the two orbitals  244_Untitled.png  and  942_Untitled.png  are lying in between the ligands. Therefore, the energies of the three orbitals will be raised while the energies of the two orbitals will be lowered. Thus, in the presence of octahedral field, the degeneracy of five d-orbitals splitting as:
    
The two orbitals,  244_Untitled.png  and  942_Untitled.png  becomes stable and their energies are lowered. These are designated as 'e' orbitals.
    
The three orbitals, dxy, dyz and dzx become unstable and their energies are raised. These are designated as 't2' orbitals. 

The magnitude of crystal field splitting is the difference between e and t2 orbitals and is designated as Δt, (the subscript indicating tetrahedral complexes). It is also measured in terms of Dq and Δt, = 10 Dq. If we compare the magnitude of crystal field splitting in octahedral and tetrahedral complexes (having same metal ion, ligands and metal ion-ligand distances), it has been observed that the crystal field splitting in octahedral complexes t) is considerably less than in octahedral complexes 0). It has been found to be Δt = 4/9 Δ0.

There are two main reasons for the smaller value of crystal field splitting in tetrahedral than in octahedral complexes.
    
In tetrahedral complexes there are four ligands while there are six ligands in octahedral complexes. Therefore, lesser ligands produce less crystal field splitting. The crystal field splitting in tetrahedral field is about two third of the octahedral field.
    
In tetrahedral field, none of the orbitals is pointing directly towards the ligands and, therefore, splitting is less.

Since the magnitude of crystal field splitting in tetrahedral field is quite small and is always less the pairing energy, therefore, the pairing of electrons will never be energetically favourable. Thus; all the tetrahedral complexes are high spin complexes. No tetrahedral complex with low spin has been found to exist. 

 

 

 


Related Discussions:- How tetrahedral complex splitting takes place?

Iupac system of nomenclature of complex compounds, IUPAC system of nomencla...

IUPAC system of nomenclature of complex compounds The naming of any organic compound relies on the name of normal parent hydrocarbon from that it has been derived. IUPAC system

Compare pot furnace and tank furnace, Q.   Compare pot furnace and tank fur...

Q.   Compare pot furnace and tank furnace used in manufacture of glass. Ans. S.NO. Pot furnace Tank furnace 1. Used f

Nuclophilic substitution, solution A is made by dissolving sodium acetate i...

solution A is made by dissolving sodium acetate in methanol. so

The energy of covalent o-h, Bond energy of covalent O-H  bond in water is: ...

Bond energy of covalent O-H  bond in water is: (1) Greater than bond energy of H bond (2) Equal to bond energy of H bond (3) Less than bond energy of H bond (4) None o

Halogen containing compounds, Halogen Containing Compounds Compounds th...

Halogen Containing Compounds Compounds that are derived from hydrocarbons by the replacement of one or more than one hydrogen atoms by the corresponding number of halogen atoms

Calculate heat transfer, Q. Determine the heat transfer? Ans. Let's say...

Q. Determine the heat transfer? Ans. Let's say a blacksmith tosses a hot horse shoe into a bucket of water. The horseshoe will get cooler while the water gets hotter. Ideally

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd