Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

write a shortnote on electrorefining of copper? , Electro refining of Copp...

Electro refining of Copper • Electrolyte - Aqueous copper sulphate solution (acidified) • Cathode - Pure copper metal (thin rod) • Anode - Impure copper metal (thick block) • Disso

Gases, a small 0.600ml bubble forms at the bottom of a lake where the tempe...

a small 0.600ml bubble forms at the bottom of a lake where the temperature is 4.0 degrees Celsius and the pressure is 2.40 atm. What volume will the bubble occupy near the surface

P block, diamond is covalent.yet it has high melting point.why?

diamond is covalent.yet it has high melting point.why?

Test of proteins - biuret test, Test of proteins - Biuret test (i) Biur...

Test of proteins - Biuret test (i) Biuret test : By adding a dilute solution of copper sulphate to alkaline solution of protein, a violet colour is made. This test is because o

Matter, Q.give characterstics of matter?

Q.give characterstics of matter?

0 order, radioactive decay order

radioactive decay order

Show redox reactions as electron transfer, Q. Show Redox Reactions as Elect...

Q. Show Redox Reactions as Electron Transfer? Ans. Oxidation is a process where electrons are lost, and reduction is a process where electrons are gained. For example,

Electrogravimetry, what are some instruments used in electrogravimetry?

what are some instruments used in electrogravimetry?

Synthesis of freon and freon synthesis, explain the synthesis of freon and ...

explain the synthesis of freon and westron i need only the synthesis of those coompound

Explain carbocation, Explain Carbocation The mechanism is a sequence of...

Explain Carbocation The mechanism is a sequence of two Brønsted acid-base reactions. In the first (step a), the double bond is protonated to give a tertiary carbocation; in the

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd