Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

Atomic structure, the value of charge on the oil droplets experimentally ob...

the value of charge on the oil droplets experimentally observed were -1.6*10-19 and -4*10-19coulomb. the value of the electronic charge,indicated by these results is

Write the structural formula of 3-phenylprop-2-enal, (a) Write the structur...

(a) Write the structural formula of 3-phenylprop-2-enal. (b) Write one chemical equation each to illustrate the following reactions: (i) Aldol condensation (ii) Cannizzaro

All the bonds pcl5 are not equivalent, Give chemical reaction in support of...

Give chemical reaction in support of each of the following statements: (i) The +1 oxidation state gets stabilised progressively from Ga to TI in Group (ii) All the bonds PCl5

Industrial chemistry: bulk inorganic chemicals, INDUSTRIAL CHEMISTRY: BULK ...

INDUSTRIAL CHEMISTRY: BULK INORGANIC CHEMICALS It shows a selection of the major inorganic chemicals that are defined in annual quantities of many millions of tones. Substances

Nitrenes, tell me the methods of preparation of nitrenes?

tell me the methods of preparation of nitrenes?

Nonstoichiometry, Whereas a pure molecular species has a definite stoichiom...

Whereas a pure molecular species has a definite stoichiometry, this is not often true for solids. Defects in crystals will include vacancies (atoms missing from their expected site

Lab questions, 1. List possible manipulation errors that might contribute t...

1. List possible manipulation errors that might contribute to the following errors in results: 1) obtaining a significantly larger amount of NaCl than was present in the original

Special topics in analytical chem, using a diagram explain how a fluorescen...

using a diagram explain how a fluorescence detector optical bench works

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd