Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

Explain the electrode reactions and the cell reaction, Explain the Electrod...

Explain the Electrode reactions and the cell reaction? A cell diagram, with its designation of the left and right electrodes, allows us to write reaction equations for the cell

Why is zinc not extracted from zinc oxide?, Why is Zinc not extracted from ...

Why is Zinc not extracted from ZInc oxide throgh reduction with CO?? Ans) Reducing agent should have more negative ΔG value. In case of zinc oxide ,Zn has more negative ΔG value t

The electrons in different shells, Which of the following explains the sequ...

Which of the following explains the sequence of filling the electrons in different shells: (1)  Hund's rule (2) Octet rule (3) Aufbau principle (4) All of these Ans

Mathematical method of expressing the concentrations of solu, how many gram...

how many grams of salt must be added to 500 gram of water in preparation of 12% saline solution

Briefly explain about alloys, Q. Briefly explain about Alloys? Ans. ...

Q. Briefly explain about Alloys? Ans. Pure metals are malleable. Metals that are harder, stronger and less malleable are sometimes required. These characteristics may be a

S block elements in the modern periodic table, How many gaseous elements ar...

How many gaseous elements are there in the s block of modern periodic table? What are they??

Uses of aluminium, Q. Uses of Aluminium? Aluminium exhibits useful prop...

Q. Uses of Aluminium? Aluminium exhibits useful properties of low density, high thermal and electrical conductivity, and good corrosion resistance with non-toxic nature of the

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd