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In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.
the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.
The abstraction of a hydrogen atom The H-CN bond is stronger than the O-H bond, the abstraction of a hydrogen atom from HCN by the tert-butoxy radical is endothermic by 528 - 4
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Q. Uses of Aluminium? Aluminium exhibits useful properties of low density, high thermal and electrical conductivity, and good corrosion resistance with non-toxic nature of the
Write a program called tarc that performs much of the cf operation of tar .The command arguments look like: If there are no ar guments, tarc reports an error and e xits. If ther
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Discuss the ion exchange process of water softening. Give an account of the variety of mechanisms of Lubrication. Write notes on bulk and solution polymerization techniques.
The order of a reaction is occasionally changed by conditions. Consider a chemical reaction between two substances where one reactant is there in large excess. During the hydrolysi
Examples
Polymerization The tendency of many molecules to aggregate and form dimmers (e.g. Al2Cl6 2), extended polymeric, or larger oligomers structures can be regarded as a donor-accep
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