Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

Prefixes, why we consider methyl using prefixes?

why we consider methyl using prefixes?

Chemistry of carbon, what is the cycle of caban dioxide and how it flow

what is the cycle of caban dioxide and how it flow

#polrography, application of polarogrophy in deatails

application of polarogrophy in deatails

Replacement of metals from salts, Q. How to Replace Metals from their Salts...

Q. How to Replace Metals from their Salts: Ans. If zinc is added to a solution of copper (II) sulfate, it dissolves. A reddish-brown deposit of metallic copper appears,

Project, need an idea for chemistry project

need an idea for chemistry project

Orbital angular momentum of an electron in 2s -orbital, The orbital angular...

The orbital angular momentum of an electron in 2s -orbital is: (1) 1/2 h/ 2Π                              (2) h/ 2Π (3) √2 h/ 2 Π                      (4) Zero Ans

Entropy and second and third law of thermodynamics, ENTROPY Entropy is ...

ENTROPY Entropy is a thermodynamic property of a system. It is denoted as S and like as the enthalpy and internal energy, it is a state function. In thermodynamic expression, e

Paints, #question. what are paints

#question. what are paints

Demonstrate the existence of ferromagnetic domains, Explain experimental ev...

Explain experimental evidence to demonstrate the existence of ferromagnetic domains. Temperature increases, thermal motion, or entropy, competes with ferromagnetic tendency for

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd