Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

What is electrode potential?, When a strip of metal (M) is brought in conta...

When a strip of metal (M) is brought in contact with the solution containing its own ions (Mn+), then either of the following three possible processes can take place:      The meta

Relating Careers to Chemistry, What impact does Chemistry have on linguisti...

What impact does Chemistry have on linguistic anthropology?

Give the total order and the partial orders of the reaction, Chemical Kinet...

Chemical Kinetics of the Peroxodisulfate Ion The peroxodisulfate  ion is one of the strongest oxidants that are  called, although the oxidation reaction is relatively slo

Estimate the enthalpy of fusion of sulphuric acid, In the industrial produc...

In the industrial production of sulphuric acid, SO 3 is carefully reacted with water: SO 3 + H 2 O → H 2 SO 4 any excess SO 3 giving rise to what is called oleum, a solut

Properties of ethyl alcohol, Properties of ethyl alcohol Physical prope...

Properties of ethyl alcohol Physical properties It is a colorless liquid with a characteristic alcoholic smell. Its boiling point is 351K It is neutral towards litmus

Define food spoilage, Q. Define Food spoilage? Food spoilage is a major...

Q. Define Food spoilage? Food spoilage is a major concern of all people. Spoilage by growth of bacteria, yeasts and moulds limits the time that the food can be stored and still

Silicides, preparation of silicides

preparation of silicides

Conformation energy profile for cyclohexane ring flip, Conformation energy ...

Conformation energy profile for cyclohexane ring flip   cyclohexane ring flip

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd