Heteronuclear diatomics, Chemistry

Assignment Help:

In a heteronuclear molecule a bond is build between different atoms, and the most important difference from the homonuclear case is that molecular orbitals (MOs) are no longer shared exactly between atoms. As like a molecule where each atom has just one valence atomic orbital (AO): As like would be gas-phase LiH with 2s on Li and 1s on H. When MOs are build using the LCAO approximation.

 

2392_Untitled.png

 

the coefficients c2 and c1 are no longer equal. In LiH the two AOs differ greatly in energy, as H has a bigger ionization energy and higher electronegativity than Li. If is the AO of lower energy (i.e. of higher ionization energy or greater electronegativity;), then the bonding MO has c2>c1.

 


Related Discussions:- Heteronuclear diatomics

Standard solutions and titrations, How are standard solutions and titration...

How are standard solutions and titrations prepared in industry?

Inorganic chemistry, diagonal relationship between boron and silicon

diagonal relationship between boron and silicon

Ethyl chloride reacts with alcoholic potassium hydroxide, Q. Why eliminatio...

Q. Why elimination occurs instead of nucleophilic substitution when ethyl chloride reacts with alcoholic potassium hydroxide? Ans: Ethyl chloride can undergo both nucleophilic sub

Nitrogenous base - composition of nucleic acids, Nitrogenous base: Thes...

Nitrogenous base: These are heterocyclic organic compound that comprise two or more nitrogen atoms in ring skeleton. These are called bases as the lone pairs of electrons on th

Crystal field splitting in tetrahedral field, Q. Crystal Field Splitting in...

Q. Crystal Field Splitting in Tetrahedral Field? A tetrahedron can be viewed as a part of cube where the metal ion occupies the centre of the cube and the four ligands are plac

Differential extraction - purification of organic compounds , Differential ...

Differential extraction - Purification of organic compounds This technique is employed for the separation of an organic compound that solid or liquid from its aqueous soluti

The energy of a photon is calculated, The energy of a photon is calculated ...

The energy of a photon is calculated by: (1) E= hv (2) h= Ev (3) h = E/v (4) E= h/v Ans: E= hv

Chemistry of carbon, what is the cycle of caban dioxide and how it flow

what is the cycle of caban dioxide and how it flow

Organic chemistry, electrophilic substitution reactions and mechanisms

electrophilic substitution reactions and mechanisms

Alkyl nitrites and nitro alkanes, Alkyl nitrites and nitro alkanes In t...

Alkyl nitrites and nitro alkanes In two tautomeric types Nitrous acid found. Corresponding to these two forms, nitrous acid provides two types of derivatives, that is n

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd