Henderson-hasselbalch equation, Chemistry

Assignment Help:

(a) Explain in terms of ionic equilibria why the aqueous solution of a salt derived from a weak acid and a strong base (e.g. sodium phenolate) has a pH greater than 7.

(b) By considering the equilibrium constant (Ka) of a weak acid, and the effect on Ka when a salt of that acid is added to the solution, derive the Henderson-Hasselbalch equation for buffer solution pH.

(c) Explain why the Henderson-Hasselbalch equation sometimes features a term written as + log10 gA- where gA- represents the activity coefficient of the common anion, and hence describe the effect of increasing the concentration of both the acid and salt in the buffer formulation on buffer performance.

(d) An aqueous buffer solution is formulated containing 0.010 mol dm-3 sodium phenolate to which phenol is added. Given that the pKa of phenol is 9.98, calculate the concentration of phenol required to produce a pH of exactly 9.65 (you may assume that gA- = 1).


Related Discussions:- Henderson-hasselbalch equation

S block, Anomalous behaviour of boron

Anomalous behaviour of boron

Atomic structure, the most probable radius for finding the electron in he+

the most probable radius for finding the electron in he+

Explain important properties of energy, Q. Explain important properties of ...

Q. Explain important properties of energy? Properties of Energy There are two important laws that explain the important properties of energy: Conservation of Energy (

Define bond angle, The angle among the lines joining the nuclei of the bond...

The angle among the lines joining the nuclei of the bonded atom with a central atom is known as bond angle.

How to find which compound is acid or basic?, We can find a compound  is  a...

We can find a compound  is  acid or base by using litmus test. Acides turnes red litmus to blue colour, in case of base it turnes blue  litmus to red.(or) According to arrhenius

Potentiometry, principle and application of potentiometry in biochemistry

principle and application of potentiometry in biochemistry

Assignment beginning, Is this a excellent beginning for my assignment Most...

Is this a excellent beginning for my assignment Most Australians who own a pool, have saltwater pools, which are basically pools where the water have salt (NaCl) dissolved into th

Sodium atom the number of electrons, For sodium atom the number of electron...

For sodium atom the number of electrons with m=0 will be: (1) 2        (2) 27      (3) 9          (4) 8 Ans: 7

Physical properties of group16, Q. Physical Properties of group16? Simi...

Q. Physical Properties of group16? Similar to the groups discussed earlier. The metallic character in Group 16, increases with increasing atomic number. Oxygen and sulphur are

Tests for acetone - indigo test and iodoform test, Tests for acetone - Indi...

Tests for acetone - Indigo test and Iodoform test (a) Indigo test: When a small amount of orthonitrobenzaldehyde is added to approximately 2 ml. of acetone and it is diluted al

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd