Henderson-hasselbalch equation, Chemistry

Assignment Help:

(a) Explain in terms of ionic equilibria why the aqueous solution of a salt derived from a weak acid and a strong base (e.g. sodium phenolate) has a pH greater than 7.

(b) By considering the equilibrium constant (Ka) of a weak acid, and the effect on Ka when a salt of that acid is added to the solution, derive the Henderson-Hasselbalch equation for buffer solution pH.

(c) Explain why the Henderson-Hasselbalch equation sometimes features a term written as + log10 gA- where gA- represents the activity coefficient of the common anion, and hence describe the effect of increasing the concentration of both the acid and salt in the buffer formulation on buffer performance.

(d) An aqueous buffer solution is formulated containing 0.010 mol dm-3 sodium phenolate to which phenol is added. Given that the pKa of phenol is 9.98, calculate the concentration of phenol required to produce a pH of exactly 9.65 (you may assume that gA- = 1).


Related Discussions:- Henderson-hasselbalch equation

Mark-houwink model, The table below gives intrinsic viscosity values determ...

The table below gives intrinsic viscosity values determined by viscometry and weight- average molar mass values determined under the same conditions by static light scattering.

Acids, Choose the best definition of temperature

Choose the best definition of temperature

Aromatic nitro compounds - electrophilic substitution, Chemical Properties ...

Chemical Properties of Aromatic Nitro Compounds - Electrophilic substitution Because - NO 2 group is deactivating and m-directing, electrophilic substitution (halogenation, ni

What is eutectic point??, 1. Of, relating to, or formed at the lowest possi...

1. Of, relating to, or formed at the lowest possible temperature of solidification for any mixture of specified constituents. Used especially of an alloy whose melting point is low

Show the properties of lithium aluminium hydride, Q. Show the properties of...

Q. Show the properties of Lithium Aluminium Hydride? Lithium aluminium hydride is much more useful than aluminium hydride. It is prepared in the laboratory by the action of LiH

Hydrogen-spectrum, Energy difference is maximum between which of the consec...

Energy difference is maximum between which of the consecutive energy levels in an atom? Ans) According to the line spectrum of hydrogen maximum energy is there between FIRST AND

Explain the term production, Production Sensory analysis does not stop...

Production Sensory analysis does not stop after the  product has been developed and is being produced routinely. However, it is critical that products continue to be analyzed

Help!, How do you know if a property is extensive or intensive?

How do you know if a property is extensive or intensive?

Normality, I don''t understand the concept of normality and gram equivalent...

I don''t understand the concept of normality and gram equivalent

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd