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(a) Explain in terms of ionic equilibria why the aqueous solution of a salt derived from a weak acid and a strong base (e.g. sodium phenolate) has a pH greater than 7.
(b) By considering the equilibrium constant (Ka) of a weak acid, and the effect on Ka when a salt of that acid is added to the solution, derive the Henderson-Hasselbalch equation for buffer solution pH.
(c) Explain why the Henderson-Hasselbalch equation sometimes features a term written as + log10 gA- where gA- represents the activity coefficient of the common anion, and hence describe the effect of increasing the concentration of both the acid and salt in the buffer formulation on buffer performance.
(d) An aqueous buffer solution is formulated containing 0.010 mol dm-3 sodium phenolate to which phenol is added. Given that the pKa of phenol is 9.98, calculate the concentration of phenol required to produce a pH of exactly 9.65 (you may assume that gA- = 1).
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If the atomic weight of an element is 23 times that of the lightest element and it has 11 protons, then it contains : (1)11 protons, 23 neutrons, 11 electrons (2)11 protons,
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If 0.5 mol of BaCl 2 is mixed with 0.20 mol of Na 3 PO 4 , the maximum amount of Ba 3 (PO4) 2 that can be formed is 3 BaCl 2 + 2 Na3PO 4 = Ba 3 (PO4) 2 + 6NaCl Here cle
Beginning in the early nineteenth century, scientists developed models to explain the structure of the atom. As more information was discovered about the nature of the subatomic pa
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Depression in freezing point - Physical methods for Non-volatile substances Mol. Mass = (1000 K f * w) /W* ΔT Where, K f stands for Molal depression constant of the solve
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