Fullerene structure and properties, Physics

Assignment Help:

 

 

FULLERENE: The fullerene is a cage like hollow molecules composed of hexagonal and pentagonal groups of atoms, and especially those formed from carbon, that constitute the third form of carbon after diamond and graphite. However the term has been widened to contain any closed cage structure having more than twenty carbon atoms including completely of three coordinate carbon atoms. A, hollow pure carbon molecule in which the atoms positioned at the vertices of a polyhedron with 12 pentagonal faces and any number (other than one) of hexagonal faces. The fullerene is a just revealed family of carbon allotropes (any two or more forms of the same chemical element) named after the sheet from being planner.

STRUCTURE AND PROPERTIES: - In the fullerene molecule an even number of carbon atoms are arranged over the surface of a closed hollow cage. Each atom is trigonally linked to its three near neighbours by bonds that delineate a polyhedral network, consisting of 12 pentagonal and n hexagons (n may be any number other that one including zero). All 60 atoms in fullerenes 60 are equivalent and lie on the surface distributed with the symmetry of a truncated icosahedrons (an icosahedrons is a polyhedron having 20 faces, but usually a regular icosahedrons is meant, which has faces which are equilateral triangles). The 12 pentagons are isolated and spread symmetrically among 20 linked hexagons. Solid C60 exhibits interesting dynamic behaviour in that at room temperature the individual round molecules in the face centred cubic crystals are rotating isotropic ally (that is freely) at around 108Hz. At around 260k (8.3F) there is a phase transition to a simple cubic lattice accompanied by an abrupt lattice contraction rotation is no longer free, and the individual molecules make rotational jumps between two favoured (relative) orientations configurations, in the lower energy one a double bond lies over a pentagon, and in the other it lies over a hexagon. At 900k (-300 F) the individual molecules stop rotating altogether, freezing into the orientation ally discovered crystal involving a mix of the two configurations.

 

 


Related Discussions:- Fullerene structure and properties

Name the device used for data transmission, Name the device used for data t...

Name the device used for data transmission from single computer to an other Justify the name. Using this device draw the block diagram for data Communication and define it brief

Write about isaac newton, Write a short (approx. one page) review of the co...

Write a short (approx. one page) review of the contribution of one of the following people to the historical development of Physics;   Aristotle Ibn al-Haytham Ga

Advantages and disadvantages of three phase system, Advantages and disadvan...

Advantages and disadvantages of three phase system over single phase System A) In a single phase circuit the power delivered is pulsating. In three phase system the total power

Obt, Obtain expression for an optical path difference for formation of circ...

Obtain expression for an optical path difference for formation of circular fringe in Michelson''s interferometer

Force on rocket repulsion, a jet of engine on a test tube takes in 20kg of ...

a jet of engine on a test tube takes in 20kg of air per second at a velocity of 100m/s and burns 0.8kg of fuel per second.after compression and heating the exhaut gases are ejected

Turning effect of forces, information about parallel forces and its types a...

information about parallel forces and its types and examples

What is the average velocity of the airplane, The position of an airplane a...

The position of an airplane as a function of time is shown in the figure below. a. What is the average velocity of the airplane? b. What is the average speed of the air

Describe construction and working of carbon dioxide laser, Describe the con...

Describe the construction and working of carbon dioxide laser. Construction and Working: The most fundamental form of a CO 2 laser comprise a gas discharge (along with a mi

Elasticity of solids, a metal wire 75.0 cm long and 0.130 cm in diameter st...

a metal wire 75.0 cm long and 0.130 cm in diameter stretches 0.0350 cm when a load of 8.00 kg is hung on its end. find the stress, the strain and the young''s modulud for the mater

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd