User Account

All Pages

free radical polymerisation, Chemistry

Assignment Help:
#ques(a) Given the values below, calculate the concentration of benzoyl peroxide required to prepare polystyrene with a number average molar mass of 400,000 by bulk free radical polymerisation at 60°C, assuming all termination is by combination.

f = 0.6

kd=2×10-6 s-1

kp= 341 M-1 s-1

kt=4×107 M-1s-1

density of styrene = 880 kg m-3.

(b) Calculate the initial radical concentration and initial rate of polymerisation for this reaction.

(c) Given the values below for the activation energies of benzoyl peroxide dissociation, styrene propagation, and styrene termination, and assuming all other parameters remain constant calculate the number average molar mass, initial radical concentration, and initial rate of polymerisation if the reaction is run at 66°C rather than 60°C.

EA dissociation = 115 kJ mol-1

EA propagation = 34 kJ mol -1

EA termination = 10 kJ mol-1tion..

Related Discussions:- free radical polymerisation

Find the concentration of hydrogen ions, An aqueous solution has a hydroxyl...

An aqueous solution has a hydroxyl concentration of 1.75 x 10^-7mol/L. Find the concentration of hydrogen ions in this solution.

Types of organic reaction., Ask question #Minimum 250 words accepted#

Ask question #Minimum 250 words accepted#

Preparation of iodoform, how will you test for the presence of the halogen ...

how will you test for the presence of the halogen in iodoform

Electrochemical cells, I have this chemistry assignment. It basically says,...

I have this chemistry assignment. It basically says, "study and make a report on any two types of electrochemical cells". What do I do? I have no idea so please, I need some help.

Uses of esters - carboxylic acids, Uses of Esters (a) Esters are used a...

Uses of Esters (a) Esters are used as a solvent for oils, fats, cellulose, resins etc. (b) Esters are used in making artificial flavours and essences. (c) Esters are used

Mechanism of stille reaction, show me mechanism of stille reactin

show me mechanism of stille reactin

Organic chemistry, why staggerd conformor is more stable than eclipsed conf...

why staggerd conformor is more stable than eclipsed conformer

Uses of glucose - biomolecules, Uses of Glucose (a) Glucose is used in ...

Uses of Glucose (a) Glucose is used in the conservation of fruits and making of jams and jellies. (b) Glucose is used in the preparation of confectionary and as a sweetening

Isolation and purification of metals, Q. Isolation and purification of meta...

Q. Isolation and purification of metals? metals as a group of elements have acquired a unique importance in the modern world. However, nature' does not generally offer us metal

Periodic table, d block elements boiling point

d block elements boiling point

Write Your Message!

Captcha
Order Assignment

Featured Services

Order Now

Popular Subjects

Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

Submit Assignment

Academics

Major Subjects

Majors

Get In Touch

whatsapp: +1-415-670-9521

Phone: +1-415-670-9521

Email: [email protected]

TERMS & POLICIES

HELP & SUPPORT

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd