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(a) Describe how you would carry out a series of experiments to determine the molar conductivities (Λm) of an electrolyte at various concentrations, starting with the measurement of conductance. Explain clearly how you would calibrate the apparatus to obtain the cell constant, and how you would use this value in your calculations.
(b) Explain briefly how you would plot the data obtained from the experiments in part (a) graphically to find the value of the limiting molar conductivity (Λm0) of:
(i) a strong electrolyte;
(ii) a weak electrolyte.
(c) The molar conductivity of aqueous potassium perchlorate at 298K has been measured at selected concentrations:
c /mol dm-3
0.0005
0.0050
0.0200
0.0500
0.1000
Λm /S m2 mol-1
0.0139
0.0134
0.0128
0.0122
0.0115
(i) By means of a suitable graph, estimate the limiting molar conductivity (Λm0) of aqueous potassium perchlorate.
(ii) If the limiting molar ionic conductivity (λ-) of the perchlorate ion is 6.85 x 10-3 S m2 mol-1, calculate that of the potassium ion (λ+).
tests for mixture of acid radicals
calculate the voltage of the cell mg/mg+//cd2+/cd at 250c.when[cd2+]=7*10-11 M,[mg2+]=1.0M and standerd electrode potential=1.97V.
what is chemistry
Molten sodium chloride conducts electricity due to the presence of: (1) Free electrons (2) Free ions (3) Free molecules (4) Atoms of sodium and chlorine Ans: Free
Physical properties of Glucose 1. Glucose is a colourless crystalline solid, melts at 146° C. 2. Glucose is readily soluble in water. 3. From aqueous solution,Glucose se
i) Electrophillic substitution in case of aromatic amines takes place more readily than benzene. ii) Nitro compounds have higher boiling points than hydrocarbons having almost s
in ecm some have positive eo values
hitorff method
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process of metellergy
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