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Explain rules of pericyclic
The pericyclic selection rules say absolutely nothing about the position of equilibrium in every case. These rules refer to rates of reactions, not to equilibrium constants. Other considerations must be used to decide on the position of equilibrium. The point of the problem is for you to use what you have learned about the relative energies of molecules; the molecule of lower energy is favored in each equilibrium.
(b) The left side of the equation is favored at equilibrium because the double bonds have more alkyl branches. (Alkyl substitution stabilizes a double bond.)
(d) The right side of the equation is favored at equilibrium because single product is aromatic and thus particularly stable, and the other product is volatile (ethylene is a gas)
Coordination number and geometry Binary compounds are ones with two different elements present. 'Simple' crystal structures can be classed as ones in which each atom (or
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how is the regulation of citrate synthase?
What is meant by linear combination of atomic orbitals? State bonding and antibonding molecular orbitals based on bomo-nuclear dihydrogen molecule.
Radius of the first Bohr's orbit of hydrogen atom is: (1)1.06 Å (2) 0.222 Å (3) 0.28 Å (4)0.53A Ans: 0.53 Å
Physical properties of Acyl Halides 1. As much lower acyl chloride are mobile, colourless liquid while the higher members are coloured solids. 2. Acyl chloride has very pun
The standard EMF of Pt/H2(g)/HCl(aq)//AgCl(aq)/Ag has been experimentally determined from 0-90?C to yield the following; E?/V =0.23659 – 4.856 * 10-4t(?C) – 3.4205 * 10-4t2(?C) +
Gold has a molar mass of 197g/mol. How many atoms are in the sample?Please give me procedure also. Ans) molecular wieght of gold is 197 g 1mole/g of molecule is occupies the
Uses of Cellulose - biomolecules (i) Cellulose is used as such in the manufacture of cloth (cotton), canvas and gunny bags (jute) and paper (wood, bamboo, straw, etc.) (ii)
Indicate the nature of bonding in CCl 4 and CaH 2 : (1) Covalent in Ccl 4 and electrovalent in Cah 2 (2) Electrovalent in both CCl and CaH 2 (3) Covalent in bot
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