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Q. Explain about Stereoisomerism?
Stereoisomers have the same bonds but the arrangement of atoms in space is different. Stereoisomerism can be divided into two kinds: geometrical and optical.
Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square plana structure the two possible arrangements are shown in Fig.
In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.
This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar) and 4 (tetrahedral geometry).
advantages and dis advantages?
Reaction Intermediates Short lived fragments that are known as reaction intermediates result from homolytic and heterolytic bond fission. The significant reaction substances ar
Show by means of equation and reagent butanoic acid is formed from propyne
Q. Show Crystal Field Splitting in Square Planar Complexes? In a d 1 or d 2 system the electrons will always go in the 'e' set of orbitals with the release of corresponding a
give two reasons why it is necessary to ionize the chromium atoms
Question: Does the number of steps in a reaction process affect the enthalpy change of the overall reaction? Hypothesis: To compare experimental data to functionality of He
Types of interferences - Atomic absorption spectrophotometry: Three types of interferences viz., chemical, spectral and physical interferences are encountered in AAS. These re
Upon treatment of A with benzyl amine in the presence of a weak acidic catalyst, they obtained mainly the undesired amino alcohol C along with some of the desired product D that c
Properties of Detergents - Oils and Fats Detergents are superior cleansing agents due to following properties. (i) These can be employed both in soft and hard waters as the
reaction of cycloalkane??
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