Explain about stereoisomerism, Chemistry

Assignment Help:

Q. Explain about Stereoisomerism?

Stereoisomers have the same bonds but the arrangement of atoms in space is different.  Stereoisomerism can be divided into two kinds: geometrical and optical.

Geometrical isomerism occurs when ligands can assume different positions around rigid bond\ with the metal ion. For example the compound Pt(NH3)2Cl2 has a square  plana  structure   the two possible arrangements are shown in Fig.

In the cis-isomer the two ammonia molecules are next (cis) or adjacent to each other whereas in the trans-isomer the two ammonia molecules are across (Trans) to each other.

586_Explain about Stereoisomerism.png

This type of isomerism is not possible for complexes with coordination number 2 (linear molecule). 3 (trigonal planar)  and 4 (tetrahedral geometry).


Related Discussions:- Explain about stereoisomerism

Explain bonding molecular orbital, Explain bonding molecular orbital Th...

Explain bonding molecular orbital The bonding molecular orbital is derived by the constructive "side-to-side" overlap of peaks with peaks and troughs with troughs. The antibond

Electrochemistry, consider the reaction: Mg(s) +2H _Mg(aq)+H2(g).Calculate...

consider the reaction: Mg(s) +2H _Mg(aq)+H2(g).Calculate the standard electrode potential.

Describe the mechanism of ferromagnetism, Describe the mechanism of ferroma...

Describe the mechanism of ferromagnetism Ferromagnetism is the basic mechanism by which certain materials (like iron) form permanent magnets or/and exhibit strong interactions

Reaction, Preparation of alkene

Preparation of alkene

Illustrate uses of f-block element, Q. Illustrate Uses of f-block element? ...

Q. Illustrate Uses of f-block element? Lanthanides and many of their complexes have received wide industrial applications. For example, europium derivatives are used as phospho

Write a feature of metallic solid from an ionic solid, Write a feature whic...

Write a feature which will distinguish a metallic solid from an ionic solid. a) Explain 'order of a reaction'. b) What is an emulsion?

Back-titration, 1 gram of pure sodium carbonate is dissolved in water and t...

1 gram of pure sodium carbonate is dissolved in water and the solution is made up to 50 ml of this solution 50 ml of 0.1 N HCl is added whose volume is 50 ml and the mixture furthe

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd