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Q. Explain about Molecular orbital theory?
Molecular orbital theory is a completely different approach. It starts with identifying the metal orbitals and the ligand orbitals (hybridised) which have the correct symmetry and energies for combination to yield molecular orbitals. The total electrons from the ligands and metal ion are placed into these molecular orbitals and the bond order, which is a measure of the covalency. is determined. Once the energy sequence of molecular orbitals in a complex is known. The properties of the complex can be all explained. It does not start with any assumption regarding the type of bond involved in the complex; rather it comes out as a natural consequence of the theory. Further, it IS much more comprehensive yet the theory has not become very popular. The reason for this is that the quantum mechanical calculations involved are too tedious and many a time cannot be solved. We shall not go into the details of this theory but would like to emphasise that this is the best and comprehensive approach; in all those cases where precise calculations have been possible, the results are in almost 'perfect agreement with the experimental observations.
Explain stereochemistry a) The stereochemistry is E. The Br has higher priority on one carbon stereocenter, but it has lower priority on the other. b) The stereochemistry is
why dipole moment of CH3CL is more than CH3F
2. A mixture is prepared by adding 25.0 mL of 0.185 M Na3PO4 to 34.0 mL of 0.140 M Ca(NO3)2. (a) What mass of Ca3(PO4)2 will be formed? (b) What will be the concentrations of eac
Q. What are the Chemical Properties of Halogens? Ans. he halogens have 7 valence electrons in their outermost shell. Note that 7 is one electron short of the octet.
Q. Illustrate Born-Haber cycle? Boron is always covalent and does not form,B 3+ ions, because' the energy required to remove three electrons is very high. Many simple compo
how did atoms appear
The azimuthal quantum number is related to: (1) Size (2) Shape (3) Orientation (4) Spin Ans: Shape
Physical properties of Tri-halides (i) Tri-halides is a sweet smelling colourless liquid. (ii) Tri-halides is heavy liquid. The density of it is 1.485. It boils at 61°C.
NITROGEN Nitrogen is the great strength of the triple bond makes N2 thermodynamically and kinetically stable but moderately electronegative element. The atom can form three sing
Artificial process for manufacture of Petrol or gasoline (a) Cracking, (b) Synthesis
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