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Q. Explain about Molecular orbital theory?
Molecular orbital theory is a completely different approach. It starts with identifying the metal orbitals and the ligand orbitals (hybridised) which have the correct symmetry and energies for combination to yield molecular orbitals. The total electrons from the ligands and metal ion are placed into these molecular orbitals and the bond order, which is a measure of the covalency. is determined. Once the energy sequence of molecular orbitals in a complex is known. The properties of the complex can be all explained. It does not start with any assumption regarding the type of bond involved in the complex; rather it comes out as a natural consequence of the theory. Further, it IS much more comprehensive yet the theory has not become very popular. The reason for this is that the quantum mechanical calculations involved are too tedious and many a time cannot be solved. We shall not go into the details of this theory but would like to emphasise that this is the best and comprehensive approach; in all those cases where precise calculations have been possible, the results are in almost 'perfect agreement with the experimental observations.
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An electron has kinetic energy 2.8 x 10 -23 J . de-Broglie wavelength will be nearly: (me: 9.1 x 10 -31 kg) (1) 9.28x 10 -4 m (2) 9.28 x10 -7 m
what is allyl componund
what is flame coloration?
Calculation of Number of Atoms per Unit Cell of HCP (n): One half of the each of the 2 base centre atoms (2x1/2), one six of the every of the 12 corner atoms (12x1/6) and all
The charge of an electron is -1.6 x10 -19 C. The value of free charge on Li + ion will be: (1) 3.6x 10 -19 c (2) 1x 10 -19 c (3) 1.6 x 10 -19
WHAT are the properties of group13 elements?
The lengths of the C-C bonds in isobutene The lengths of the C-C bonds in isobutene have no significance; two are longer merely to accommodate the rest of the structure. Rememb
Which of the following sets of quantum number is not possible: (1) n=3, l=+2, m=0,and s = +1/2 (2) n=3, l=0, m=0,and s = -1/2 (3) n=3, l=0, m=-1,and s = +1/2
Hexagonal Close Packed (HCP) Structure:- The cell of HCP system has 12 corner atoms, one at each corner of the hexagon with two base centered atoms, one at the top face of the
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