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Q. Explain about Molecular orbital theory?
Molecular orbital theory is a completely different approach. It starts with identifying the metal orbitals and the ligand orbitals (hybridised) which have the correct symmetry and energies for combination to yield molecular orbitals. The total electrons from the ligands and metal ion are placed into these molecular orbitals and the bond order, which is a measure of the covalency. is determined. Once the energy sequence of molecular orbitals in a complex is known. The properties of the complex can be all explained. It does not start with any assumption regarding the type of bond involved in the complex; rather it comes out as a natural consequence of the theory. Further, it IS much more comprehensive yet the theory has not become very popular. The reason for this is that the quantum mechanical calculations involved are too tedious and many a time cannot be solved. We shall not go into the details of this theory but would like to emphasise that this is the best and comprehensive approach; in all those cases where precise calculations have been possible, the results are in almost 'perfect agreement with the experimental observations.
Complex: A very general definition of complex is, 'A compound that results from the combination of a central atom or ion and a group of atoms/ions/molecules surrounding it'. As
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1. A laboratory animal exercised on a treadmill that was connected to a weight with a mass of 250. g through a pulley. The work done by the animal raised the weight through 1.32 m.
Calculate how the internal energy stored in one O-H bond of H20 Consider the following chemical reaction H20(g)-->2H(g) + O(g) at 298.15 K and 1.00 Bar fH* [H(g)]=218.0 kJ/mole fH*
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Bond order is the number of chemical bonds between a pair of atoms. For example, in diatomic nitrogen N≡N the bond order is 3, while in acetylene H-C≡C-H the bond order between the
what is the defination of interstitial?
Explain The compound decarboxylates The compound decarboxylates; it is a disubstituted malonic acid in which the two a substituents are connected within a ring. The net effect
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what groups comprise each block of elements(s,p.d and f blocks)in the periodic table
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