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Q. Explain about Molecular orbital theory?
Molecular orbital theory is a completely different approach. It starts with identifying the metal orbitals and the ligand orbitals (hybridised) which have the correct symmetry and energies for combination to yield molecular orbitals. The total electrons from the ligands and metal ion are placed into these molecular orbitals and the bond order, which is a measure of the covalency. is determined. Once the energy sequence of molecular orbitals in a complex is known. The properties of the complex can be all explained. It does not start with any assumption regarding the type of bond involved in the complex; rather it comes out as a natural consequence of the theory. Further, it IS much more comprehensive yet the theory has not become very popular. The reason for this is that the quantum mechanical calculations involved are too tedious and many a time cannot be solved. We shall not go into the details of this theory but would like to emphasise that this is the best and comprehensive approach; in all those cases where precise calculations have been possible, the results are in almost 'perfect agreement with the experimental observations.
Onion and Garlic Onions (A. cepa), and garlic (A. sativam), have been used in traditional and folk medicine for over 4000 years. Disorders for which both garlic and onions ha
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The energy of a radiation of wavelength 8000 Å is E 1 and energy of a radiation of wavelength 16000 Å is E 2 . What is the relation between these two: (1) E 1 =6E 2
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What is the electronic configuration of Cu 2+ (Z= 29) of least position: (1) [Ar]4s 1 3d 8 (2) [Ar]4s 2 , 3d 10 4p 1 (3) [Ar]4s 1 3d 10
What are the points to be taken into account to compare the enol %? Ans) Different propositional proof system for theorem proving in propositional logic, like sequent calculus,
Complexometric Titrations - Types of titrations A titration, where an dissolved complex is formed at the equivalence point, is termed as complexometric titration. These types
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