Explain about hydrogen sulphide, Chemistry

Assignment Help:

Q. Explain about Hydrogen Sulphide?

Hydrogen sulphide is the only thermodynamically stable sulphane. It is a foul smelling and poisonous gas.

H2S is prepared in the laboratory by treating FeS with dilute HCI in Kipp's apparatus. In aqueous solution H, S is a weak acid. At 293 K, it dissociates as shown below: 

740_Hydrogen Sulphide.png

You must have used H2S in qualitative identification and separation of cations. This separation is based on selective precipitation of the sulphides in acidic and alkaline medium:  In the acidic medium, the ionisation of H2S which is a weak acid, is further suppressed and the solubility product of sulphides of relatively less soluble cations of Group 11, namely.  Pb2+, Hg2+, Bi3+, Cu2+ , Cd2+ . As3+, Sb3+, Sn+2 is exceeded:

1988_Hydrogen Sulphide1.png

In Group IV, in the presence of ammonia, a higher concentration of S2- ions is obtained leading to the precipitation of the more soluble sulphides of Zn, Mn, Ni and Co.

73_Hydrogen Sulphide2.png


Related Discussions:- Explain about hydrogen sulphide

Compton effect, What are the significance of compton effect

What are the significance of compton effect

Where is tin obtained, Where is tin obtained? Ans) Tin is obtained in se...

Where is tin obtained? Ans) Tin is obtained in several places tin is found mainly in the ore cassiterite, which is originate in Malaysia, Bolivia, Thailand, and Nigeria.

Properties of nitrophenols, Properties of Nitrophenols:  O-Nitrophenol ...

Properties of Nitrophenols:  O-Nitrophenol is a yellow in colour crystalline compound, whereas m- and p-isomers are colourless crystalline compounds. Isomer             orth

Solutions, how can you prepare 20%(v:v),150ml ethanol solution

how can you prepare 20%(v:v),150ml ethanol solution

What is piezoelectricity, What is piezoelectricity Piezoelectricity pr...

What is piezoelectricity Piezoelectricity provides us a means of converting electrical energy to presume new geometric positions and mechanical dimensions of the substance are

One of the following compound is ionic, Which one of the following compound...

Which one of the following compound is ionic: (1) KCl                             (2) CH 4               (3) Diamond              (4) H 2 Ans: KCl

Nomenclature of simple aromatic compounds, Nomenclature of simple aromatic ...

Nomenclature of simple aromatic compounds Aromatic compounds are those that consist of one or more benzene rings in them. An aromatic substance has two major types: (1) Nucl

The number of 2p electrons having spin quantum numbers, The number of 2p  ...

The number of 2p  electrons having spin quantum numbers= -1/2   are: (1) 6        (2) 0        (3) 2        (4) 3 Ans: 3

Show the nomenclature compounds, Q. Show the Nomenclature compounds? In...

Q. Show the Nomenclature compounds? In the earlier days naming of complexes was based on the colour of the complex. For example: Compound                              Colou

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd