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Q. Explain about Coordination Isomerism?
Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position between the cation and the anion. This will result in the formation of coordination isomers. Let us consider one such series:
[Co (en) 3][Cr(C2O4)3] Co(en)2 (C2O4)] [ Cr(en) (C2O4) 2]
[Cr(en)2(C2O4] [Co(en) (C2O4)2] [ Cr(en)3 (C2O4) 2]
It is possible to have the same metal ion present in both cationic and anionic species as shown by the following example:
[Cr (en)3[Cr(C204)3 and [Cr(en)2 (C204)I [Cr(en) (C2O4)2]
Note that in the above example both the oxidation state of the metal ion and its coordination number is same in the cation and anion. Let us consider yet another example where the above condition may be different:
[PII (NH3)4] [Ptiv Cl6 ]and [Ptiv(NH3)4 Cl2] [PtIICl4]
why they are called noble gases
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Low grade oxide, sulphide and carbonate ores of copper are treated with dilute sulphuric acid in the existence of oxygen: CuO+ H 2 SO 4 ------------------> CuSO 4 + H 2 O CuC
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Calculate the pressures required to achieve a density of 220 g dm -3 , 330 g dm -3 , and 440 g dm -3 at temperatures of 305 K and 350 K. Properties, like the solvent powe
How scale and sludge formed in boilers explain in kannKan
(CH3)2CHOH
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