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Q. Explain about Coordination Isomerism?
Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position between the cation and the anion. This will result in the formation of coordination isomers. Let us consider one such series:
[Co (en) 3][Cr(C2O4)3] Co(en)2 (C2O4)] [ Cr(en) (C2O4) 2]
[Cr(en)2(C2O4] [Co(en) (C2O4)2] [ Cr(en)3 (C2O4) 2]
It is possible to have the same metal ion present in both cationic and anionic species as shown by the following example:
[Cr (en)3[Cr(C204)3 and [Cr(en)2 (C204)I [Cr(en) (C2O4)2]
Note that in the above example both the oxidation state of the metal ion and its coordination number is same in the cation and anion. Let us consider yet another example where the above condition may be different:
[PII (NH3)4] [Ptiv Cl6 ]and [Ptiv(NH3)4 Cl2] [PtIICl4]
why is ethanol used as an solvent in substitution reactions? ethanol is used as an solvent because it is soluble in water and also it is more reacive.... Ethanol is used u
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What is the effective nuclear charge of 2s for Fe?
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A liquid stream containing half n-hexane and half n-pentane at 80°C and 5 atm is fed at a rate of 100 mol/hr to a flash evaporator operating at pressure (P) and 65°C. The decrease
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