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Q. Explain about Coordination Isomerism?
Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position between the cation and the anion. This will result in the formation of coordination isomers. Let us consider one such series:
[Co (en) 3][Cr(C2O4)3] Co(en)2 (C2O4)] [ Cr(en) (C2O4) 2]
[Cr(en)2(C2O4] [Co(en) (C2O4)2] [ Cr(en)3 (C2O4) 2]
It is possible to have the same metal ion present in both cationic and anionic species as shown by the following example:
[Cr (en)3[Cr(C204)3 and [Cr(en)2 (C204)I [Cr(en) (C2O4)2]
Note that in the above example both the oxidation state of the metal ion and its coordination number is same in the cation and anion. Let us consider yet another example where the above condition may be different:
[PII (NH3)4] [Ptiv Cl6 ]and [Ptiv(NH3)4 Cl2] [PtIICl4]
An element has the electronic configuration 1s 2 , 2s 2, 2p 6 , 3s 2 , 3p 2 . Its valency electrons are: (1) 6 (2) 2 (3) 3 (4)4 Ans: 4
As the electron move away from the nucleus,its potential energy
Which of the following represents the electronic configuration of an element with atomic number 17: (1) 1s 2, 2s 2 , 2p 6 , 3s 1, 3p 6 (2) 1s 2 , 2s 2 , 2p
locallized and delocalized bond
conclusion of the topic?
what would be the structure of SiS2 edge sharing linking polyhedra?
how it works, give me some examples
Give the example of inductomeric effect.
Electronic configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 5 4s 1 represents: (1) Ground state (2) Excited state (3) Anionic state (4) All of these Ans: Ground
Q. Complexation Behaviour of Group 13? As compared to the elements of Groups 1 and 2, elements of Group 13 show a greater tendency of complex formation. Because of lack of d-or
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