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Q. Explain about Coordination Isomerism?
Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position between the cation and the anion. This will result in the formation of coordination isomers. Let us consider one such series:
[Co (en) 3][Cr(C2O4)3] Co(en)2 (C2O4)] [ Cr(en) (C2O4) 2]
[Cr(en)2(C2O4] [Co(en) (C2O4)2] [ Cr(en)3 (C2O4) 2]
It is possible to have the same metal ion present in both cationic and anionic species as shown by the following example:
[Cr (en)3[Cr(C204)3 and [Cr(en)2 (C204)I [Cr(en) (C2O4)2]
Note that in the above example both the oxidation state of the metal ion and its coordination number is same in the cation and anion. Let us consider yet another example where the above condition may be different:
[PII (NH3)4] [Ptiv Cl6 ]and [Ptiv(NH3)4 Cl2] [PtIICl4]
Dihydric alcohols - Hydrocarbon These are compound consisting of two hydroxyl sets. These are dihydroxy components of alkanes. Their common formula is A n H 2n+2 O 2 . The very
Q. Show properties of the Borax? Salts of boric acids are known as borates. As said earlier, hydrated borates occur naturally, e.g., borax, Na 2 B 6 0 11 . 5H 2 0, kernite, Na
Write the reactions and the conditions involved in the conversion of: a. Propene to 1-Propanol b. Phenol to Salicyclic acid
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how to solve radial equation using the laguerre polynomial
Compounds with similar molecular formula but different properties are known as Isomers and the phenomenon is known as Isomerism.
Name the principal ore of tin or lead. Describe the different steps (along with equationsfor the reactions) involved in the extraction of the metal from the ore named. Name
the decomposition of nh3 on a platinum surface is a zero order reaction. what are the rates of production of n2 and h2 if k+2.5*10-4 mol-1 lsec-1?
Number of unpaired electrons in 1s 2 2s 2 2p 3 is: (1) 2 (2) 0 (3) 3 (4) 1 Ans: 3
give examples
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