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Q. Explain about coordination compound?
These compounds are usually formed by the donation of pair of electrons to the central metal ion by the group of ions or molecules. The bond so formed is called a coordinate bond and hence the name coordination compound. However, such a simple donor-acceptor bond approach does not seem to apply to all types of coordination compounds. In the following discussion we shall not only restrict ourselves to those complexes where the central atom or ion is a metal or more specifically a transition metal, but also exclude a class of compounds known as double salts, addition products and organometallic compounds. It will be useful to briefly define these compounds to avoid any future confusion. Double salts, as you know, are compounds such as alums where two salts crystallise together as one solid but when dissolved in water they dissociate into their constituent ions. For example, a compound like potash alum, K2Al2 (SO4)42.4H20 or KAI(S04)2.12H20, when dissolved in water dissociates to give K+, Al3+. SO2-4 ions. A complex shows different properties from the original constituents and generally does not dissociate into component ions. In case of addition products, two apparently stable compounds such as NH3 and BF3 when brought together result in the formation of a compound called addition product or simply adduct with the formulation NH3. BF3. The formation of such a compound is no doubt due to donation of a pair of electrons from nitrogen atom of NH3 molecule to the boron atom 6f BF3; but we cannot assign the role of a central atom to any particular atom on the resultant molecule. Organometallic compounds are those compounds where the central metal atom or ion is directly attached to at least one carbon atom of a molecule. A complex compound could be neutral, cationic or anionic depending upon the total charge carried by the complex species.
The tris(monothiocarbamato)iron(III)complex shown to the right undergoes conversion from low to high spin state with an increase in temperature. This can be monitored by measurin
Q. Illustrate the structure of Alkanes? Ans. Alkanes have the general formula C n H 2n+2 . This means that for every n atoms of carbon, there are 2n + 2 atoms of hydrogen.
why do transition metals form complex salts
What steps should be taken to minimize the risk of spoilage and wastage of the harvested produce during packing and transportation? What factors need to be considered while t
The quantity of heat liberated of absorbed when one mole of compound is formed in its standard state from its elements in their standard state is known as standard heat of formatio
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Initially 5 mol of an ideal gas with Cv,m=12.5 J K^-1 mol^-1 are at a volume of 5 dm^3 and a temperature of 300K. If the gas is heated to 373 K and the volume changed to 10 dm^3, w
what rules and principles are violated in the following electronic configuration: 1s22s3
what is electronic displacements?
Conclusion for chemicals used in medicines
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