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Q. Explain about coordination compound?
These compounds are usually formed by the donation of pair of electrons to the central metal ion by the group of ions or molecules. The bond so formed is called a coordinate bond and hence the name coordination compound. However, such a simple donor-acceptor bond approach does not seem to apply to all types of coordination compounds. In the following discussion we shall not only restrict ourselves to those complexes where the central atom or ion is a metal or more specifically a transition metal, but also exclude a class of compounds known as double salts, addition products and organometallic compounds. It will be useful to briefly define these compounds to avoid any future confusion. Double salts, as you know, are compounds such as alums where two salts crystallise together as one solid but when dissolved in water they dissociate into their constituent ions. For example, a compound like potash alum, K2Al2 (SO4)42.4H20 or KAI(S04)2.12H20, when dissolved in water dissociates to give K+, Al3+. SO2-4 ions. A complex shows different properties from the original constituents and generally does not dissociate into component ions. In case of addition products, two apparently stable compounds such as NH3 and BF3 when brought together result in the formation of a compound called addition product or simply adduct with the formulation NH3. BF3. The formation of such a compound is no doubt due to donation of a pair of electrons from nitrogen atom of NH3 molecule to the boron atom 6f BF3; but we cannot assign the role of a central atom to any particular atom on the resultant molecule. Organometallic compounds are those compounds where the central metal atom or ion is directly attached to at least one carbon atom of a molecule. A complex compound could be neutral, cationic or anionic depending upon the total charge carried by the complex species.
Photon absorption for IR spectroscopy Absorption spectroscopy refers to spectroscopic methods which measure the absorption of radiation, as a function of frequency or waveleng
can you help me with understanding chemistry?
The reaction A ? B + C is known to be zero order in A and to have a rate constant of 5.0 x 10-2 mol/L·s at 25 oC. An experiment was run at 25 oC where [A]0 = 1.0 x 10-3 M. a)
Alkyl nitrites and nitro alkanes In two tautomeric types Nitrous acid found. Corresponding to these two forms, nitrous acid provides two types of derivatives, that is n
Covalent Bond Purely electrostatic attractions between ions are nondirectional, but with increasing covalent character the directional properties of valence orbitals become more
dry air near sea level has the following composition by volume N2=78.08 percent,O2=20.94 percent. Calculate the partial pressure of each gas if atmospheric pressure is 1.00 atm
The interatomic distances in H 2 and Cl 2 molecules are 74 and 198 pm respectively. The bond length of HCl is : (1) 272 pm (2) 1
The chemical reaction at one time the rate of forward and backward reaction becomes equal that state is known as Equilibrium state.
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a metal forms 2 oxides. the higher oxide has 80% metal. 0.72g of lower oxide gave 0.8g of higher oxide when oxidised. show that law of multiple proportion is valid?
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