Explain about coordination compound, Chemistry

Assignment Help:

Q. Explain about coordination compound?

These compounds are usually formed by the donation of pair of electrons to the central metal ion by the group of ions or molecules. The bond so formed is called a coordinate bond and hence the name coordination compound. However, such a simple donor-acceptor bond approach does not seem to apply to all types of coordination compounds. In the following discussion we shall not only restrict ourselves to those complexes where the central atom or ion is a metal or more specifically a transition metal, but also exclude a class of compounds known as double salts, addition products and organometallic compounds. It will be useful to briefly define these compounds to avoid any future confusion. Double salts, as you know, are compounds such as alums where two salts crystallise together as one solid but when dissolved in water they dissociate into their constituent ions. For example, a compound like potash alum, K2Al2 (SO4)42.4H20 or KAI(S04)2.12H20, when dissolved in water dissociates to give K+, Al3+. SO2-4 ions. A complex shows different properties from the original constituents and generally does not dissociate into component ions. In case of addition products, two apparently stable compounds such as NH3 and BF3 when brought together result in the formation of a compound called addition product or simply adduct with the formulation NH3. BF3. The formation of such a compound is no doubt due to donation of a pair of electrons from nitrogen atom of NH3 molecule to the boron atom 6f BF3; but we cannot assign the role of a central atom to any particular atom on the resultant molecule. Organometallic compounds are those compounds where the central metal atom or ion is directly attached to at least one carbon atom of a molecule. A complex compound could be neutral, cationic or anionic depending upon the total charge carried by the complex species.


Related Discussions:- Explain about coordination compound

TGA, principle and application

principle and application

Electron configurations, what is the unabbreviated electron configuration o...

what is the unabbreviated electron configuration of lanthanum

Hard and soft behaviour , For cations build from metals in early groups in ...

For cations build from metals in early groups in the periodic table the complexing strength with halide ions follows the sequence     whereas with many post-transitio

Show anomalous behaviour of oxygen, Q. Show Anomalous Behaviour of Oxygen? ...

Q. Show Anomalous Behaviour of Oxygen? Oxygen differs considerably from the rest of the family members. Small size, very high electronegativity and non-availability of d-orbita

P-nitrobenzenediazonium ion, P-nitrobenzenediazonium ion The p-nitroben...

P-nitrobenzenediazonium ion The p-nitrobenzenediazonium ion, which is formed in the diazotization reaction, acts as the electrophile in an electrophilic aromatic substitution a

Units of hardness and their relationship, Q.   Write short note on units of...

Q.   Write short note on units of hardness and their relationship. Sol. Units of hardness and their relationship. (1)         Parts Per million (ppm): It is defined as t

Hybridization, how find out the correct answer in multiple choice question ...

how find out the correct answer in multiple choice question regarding to complex molecule structure

Carbon, in which state carbon exist

in which state carbon exist

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd