Explain about coordination compound, Chemistry

Assignment Help:

Q. Explain about coordination compound?

These compounds are usually formed by the donation of pair of electrons to the central metal ion by the group of ions or molecules. The bond so formed is called a coordinate bond and hence the name coordination compound. However, such a simple donor-acceptor bond approach does not seem to apply to all types of coordination compounds. In the following discussion we shall not only restrict ourselves to those complexes where the central atom or ion is a metal or more specifically a transition metal, but also exclude a class of compounds known as double salts, addition products and organometallic compounds. It will be useful to briefly define these compounds to avoid any future confusion. Double salts, as you know, are compounds such as alums where two salts crystallise together as one solid but when dissolved in water they dissociate into their constituent ions. For example, a compound like potash alum, K2Al2 (SO4)42.4H20 or KAI(S04)2.12H20, when dissolved in water dissociates to give K+, Al3+. SO2-4 ions. A complex shows different properties from the original constituents and generally does not dissociate into component ions. In case of addition products, two apparently stable compounds such as NH3 and BF3 when brought together result in the formation of a compound called addition product or simply adduct with the formulation NH3. BF3. The formation of such a compound is no doubt due to donation of a pair of electrons from nitrogen atom of NH3 molecule to the boron atom 6f BF3; but we cannot assign the role of a central atom to any particular atom on the resultant molecule. Organometallic compounds are those compounds where the central metal atom or ion is directly attached to at least one carbon atom of a molecule. A complex compound could be neutral, cationic or anionic depending upon the total charge carried by the complex species.


Related Discussions:- Explain about coordination compound

Transport number, how to calculate transport number by moving boundary meth...

how to calculate transport number by moving boundary method

Alcohols, Preparation of dihydric alcohols

Preparation of dihydric alcohols

Find the number of intensive variables, Find the number of intensive variab...

Find the number of intensive variables? Consider the lime-kiln process CaCO 3 (s) → CaO (s) + CO 2 (g) Find the number of intensive variables that can be varied independen

In bohr''s model, In Bohr's model, atomic radius of the first orbit is γ th...

In Bohr's model, atomic radius of the first orbit is γ the radius of the 3rd orbit, is: (1) γ/ 3 (2)γ (3) 3γ (4) 9γ Ans:  9γ

Show anomalous behaviour of oxygen, Q. Show Anomalous Behaviour of Oxygen? ...

Q. Show Anomalous Behaviour of Oxygen? Oxygen differs considerably from the rest of the family members. Small size, very high electronegativity and non-availability of d-orbita

, calculate the ratio of the fundamental frequency of HI and D

calculate the ratio of the fundamental frequency of HI and DI

Mechanism.., give the mechanism of additin of HCN to acetaldehyde?????

give the mechanism of additin of HCN to acetaldehyde?????

Equivalent weights, molecular weight of orthophosphoric acid is M.Its equi...

molecular weight of orthophosphoric acid is M.Its equivalent weight

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd