Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Melting points of s block, give the melting temperature values of group 2 e...

give the melting temperature values of group 2 elements

Solution, what is abnormal molecular mass

what is abnormal molecular mass

What parts of molecular forces are expected the species, What parts of mole...

What parts of molecular forces are expected to exist between the species in any three of the following pairs constituting mixtures? (a) He and N2 (b) Cl2 and NO- 3 (c) NH

Cordination compounds, i want some 25 exampels of nomenculature of complex...

i want some 25 exampels of nomenculature of complex coordination compounds

Atomic spectroscopy, Atomic spectroscopy: Atomic spectroscopy is the o...

Atomic spectroscopy: Atomic spectroscopy is the oldest instrumental method of elemental analysis. The origin of these methods dates back to the times of Bunsen and Kirchhoff i

Inner Transition Elements, Why are they (Lanthanides and Actinides) called ...

Why are they (Lanthanides and Actinides) called Inner Transition Elements?

Anomalous behaviour of boron, Just like lithium and beryllium in Groups Lan...

Just like lithium and beryllium in Groups Land 2, boron also shows anomalous behaviour. In general, the boron chemistry resembles that of silicon (occupying a diagonal position in

Alpha-particle scattering experiment proved that atom, Rutherford's α parti...

Rutherford's α particle scattering experiment proved that atom has: (1) Electrons (2 )Neutron (3) Nucleus    (4 )Orbitals Ans: Nucleus

Uses of urea or carbamide - carboxylic acids, Uses of Urea or Carbamide - C...

Uses of Urea or Carbamide - Carboxylic Acids (a) Urea is used mainly as a nitrogen fertilizer. It has 46.4% nitrogen. (b) Urea is used in the manufacture of formaldehyde-ure

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd