Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Define matrix of the mitochondrion., Write down the complete names and the ...

Write down the complete names and the commonly used abbreviations of the molecules A and B. a) Illustrate the line bond structures of the reactive moieties of these molecules i

Solution, what is abnormal molecular mass

what is abnormal molecular mass

Why sky appears blue in colour, Describe the following observations: a....

Describe the following observations: a. Lyophilic colloid is more stable than Lyophobic colloid. b. Coagulation takes place when sodium chloride solution is added to a collo

S block elements, Write the similarities of lithium with other alkali meta...

Write the similarities of lithium with other alkali metals

Physical properties of group 3 elements, Explain trend in variation of the ...

Explain trend in variation of the atomic size properties from Boron and Thallium

Qualitative analysis, #question.why basic radicals are arranged in differen...

#question.why basic radicals are arranged in different groups.

Chemistry, 4 NH3 + 5 O2 --> 4 NO + 6 H2O How many grams of NO are actually ...

4 NH3 + 5 O2 --> 4 NO + 6 H2O How many grams of NO are actually produced when 60.02 grams of ammonia are allowed to react with 96.00 grams of oxygen? ((This is a limiting reactant

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd