Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

What is calcinations process, Q. What is Calcinations process? This is ...

Q. What is Calcinations process? This is fie method of heating the concentrated ore in a limited supply of air to a high temperature but under the fusion temperature. In calcin

Explain in detail about the thermal oxidation, Explain in detail about the ...

Explain in detail about the thermal oxidation The following reactions take place during thermal oxidation: During oxidation, Si - SiO 2 interface moves into silicon. A

Soaps, why do soap not work in hard water ?

why do soap not work in hard water ?

Energy of electron of hydrogen atom in second bohr orbit, Energy of electro...

Energy of electron of hydrogen atom in second Bohr orbit is: (1)-5.44x10 -19 j                (2)- 5.44x10 -19 kj               (3)-5.44x10 -19 cal

Redox Titration, What is the reliablitiy of redox titrations?

What is the reliablitiy of redox titrations?

Analytical chemistry, explain the notion of environmental analytical chemis...

explain the notion of environmental analytical chemistry

Tie line, tie line explain in with the help of phase rule

tie line explain in with the help of phase rule

Homwork, what is the volume in cubic of a brain that is 4.77-10 to the -3 p...

what is the volume in cubic of a brain that is 4.77-10 to the -3 power.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd