Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Acetanilide in water, Acetanilide in water Water can accept a hydrogen ...

Acetanilide in water Water can accept a hydrogen bond from the hydrogen of the N-H bond, and can donate a hydrogen bond to the oxygen of the CAO bond as well as to the nitrogen

Show the reduction process on mixing acetone and chloroform, On mixing acet...

On mixing acetone and chloroform, a reduction in total volume occurs. What kind of deviations from ideal behavior for solutions is given in this case and why?

Azo dyes, what is the classification, applications and structures of azo dy...

what is the classification, applications and structures of azo dyes? how can they be removed from textile and other industrial effluents by semi-interpenetrating networks ?

Thermogravimatic analysis, what is thermogavimatic analysis and their instu...

what is thermogavimatic analysis and their instumental

Which species contain unpaired electron, Which species contain unpaired ele...

Which species contain unpaired electron? BaO 2 here oxidation number of Ba is +1 Ba(+) has 1 electron in its outermost shell so its unpaired in KO 2 . .oxd state of K is +

What do you mean by milk foams, Q. What do you mean by Milk Foams? The ...

Q. What do you mean by Milk Foams? The proteins and water in milk are extended into thin films by agitation. These thin films enclose small air bubbles to make foam in which t

Consumption of marine oils results in, Q. Consumption of marine oils result...

Q. Consumption of marine oils results in: Consumption of marine oils result in decrease in plasma lipids by reduced synthesis of fatty acids and low density lipoproteins.

Zoology, Classify phylum protozoa upto classes giving characters and suitab...

Classify phylum protozoa upto classes giving characters and suitable examples.

Solid state, Copper crystallizes into a FCC structure and the unit cell has...

Copper crystallizes into a FCC structure and the unit cell has length of edge 3.61 x10-8 cm. Calculate the density of copper if the molar mass of Cu is 63.5 g

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd