Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Hell volhard-zelinsky reaction - carboxylic acids, Hell Volhard-zelinsky re...

Hell Volhard-zelinsky reaction In presence of Red P and diffused light or Hell Volhard-zelinsky reaction Carboxylic acid comprising an α-hydrogen react with Cl 2 or Br 2 i

Organic chemistry, When Ethanoic acid is mixed with methanol what is the en...

When Ethanoic acid is mixed with methanol what is the end product?

What are trioxides, Q. What are Trioxides? The selenium and tellurium t...

Q. What are Trioxides? The selenium and tellurium trioxides are not stable, SO 2 , is the only important trioxide in the group. Its preparation has been described above. Sul

#titlespontaneous and non spontaneous reactions, give me assigment of spont...

give me assigment of spontaneous and non spontaneous reactions

Organic, formula of acetic acid

formula of acetic acid

Identify the formula and melting point of hydrate, Identify the formula and...

Identify the formula and melting point of hydrate? Iron (III) chloride forms various solid hydrates, all of which melt congruently. Table lists the temperatures t of aqueous so

Principal quantum number of an atom represents, Principal quantum number of...

Principal quantum number of an atom represents : (1) Size of the orbital (2) Spin angular momentum (3) Orbital angular momentum (4) Space orientation of the orbital

How many electrons are in benzene, There are thirty (30) electrons in benze...

There are thirty (30) electrons in benzene. This contains 24 carbon electrons and 6 hydrogen electrons. There are 12 electrons shared among C and H, and 18 among C and C. (6 electr

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd