Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Acid refractory : application and examples, what are the acid refractory an...

what are the acid refractory and its application and examples?

Define equilibrium state, The chemical reaction at one time the rate of for...

The chemical reaction at one time the rate of forward and backward reaction becomes equal that state is known as Equilibrium state.

Abnormal molecular mass, what is meant by abnormal molecular mass of solute...

what is meant by abnormal molecular mass of solute ? discuss the factors which bring abnormality in the experimentally determined molecular masses of solutes using colligative prop

Define the term wheat bran, Wheat bran   The useful role of wheat bran ...

Wheat bran   The useful role of wheat bran in promoting regularity in colonic function and preventing constipation is generally accepted. In addition, growing research has focu

What do you understand by replication by dna, (a) Write chemical equations ...

(a) Write chemical equations for the reactions of glucose with (i) Acetic anhydride and (ii) ammoniacal silver nitrate solution. (b) Draw simple Fischer projections of D-g

Solubility of ionic substances-thermodynamics, Thermodynamics Consider ...

Thermodynamics Consider an ionic solid that dissolves in water according to the equation: The equilibrium constant for the reaction, is defined as the solubilit

Redox reactions as a change in oxidation number, Q. How to change in Oxidat...

Q. How to change in Oxidation Number in Redox Reactions? Ans. In reduction-oxidation, or redox, reactions, atoms undergo changes in their oxidation numbers. Consider th

The outlet temperature, You are interested in modelling a 10 m  surge tank ...

You are interested in modelling a 10 m  surge tank which holds the products exiting a plug flow reactor, as shown below. One of the purposes of the tank is to heat the reactor prod

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd