Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Why nh4+ ion doesnot form complexes? , Explain ,Why NH 4 + ion doesnot fo...

Explain ,Why NH 4 + ion doesnot form complexes? solution) NH 4 + Ion does not act as ligand because nitrogen atom has no lone pair of electrons which it can donate to metal a

Chemical Equilibrium, why is the reaction mixture does not have 50% reactan...

why is the reaction mixture does not have 50% reactants and 50% products?

Hubles Test, Explain in brief hubles test for any test splution

Explain in brief hubles test for any test splution

What is the major diffrence btw cast cast iron and pig iron?, Pig iron is c...

Pig iron is cast iron with a very high carbon content: 4% by weight or more. Cast iron has at least 2% carbon by weight. Less than that, and it''s steel. Cast iron and pig iron are

Effect of addition of ingredients on egg foam stability, Q. Effect of addit...

Q. Effect of addition of ingredients on egg foam stability? The addition of other ingredients also influences stability. Sometimes salt is added to an egg white foam for flavou

Branched chain polymers - classification of polymers, Branched chain polym...

Branched chain polymers -  Classification of polymers These are polymers where the monomers are connected to make long chains with side chains or branches of dissimilar sizes.

Show the colorimetric analysis, Q. Show the Colorimetric analysis? Colo...

Q. Show the Colorimetric analysis? Colorimetric analysis depends on the variation of the colour with the change in concentration of the compound. Usually, absorption of light i

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd