Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Dunstan''s test, what are the equacyions of Dunstan''s test ???

what are the equacyions of Dunstan''s test ???

#title.introduction to organic and inorganic chemistry, #question:although ...

#question:although CO is well known,why doesn''t SiO exist under normal conditions?

Write a feature of metallic solid from an ionic solid, Write a feature whic...

Write a feature which will distinguish a metallic solid from an ionic solid. a) Explain 'order of a reaction'. b) What is an emulsion?

Methods of characterization, Introduction Methods of characterization a...

Introduction Methods of characterization aim to calculate the products of a reaction. The level of detail expected depends on the circumstances, and calculates the range of met

Packing of atoms, how can i make an assignment on this topic?

how can i make an assignment on this topic?

How to find equivalents, I put an unknown solid acid into a base solution. ...

I put an unknown solid acid into a base solution. How do I find the equivalents of base consumed?

Explain product optimization, Product Optimization Sensory analysis du...

Product Optimization Sensory analysis during this phase of product development is critical and includes extensive evaluation with many kinds of tests, each playing a specific

Michelle, What volumne of 10.83 M HNO3 is required to prepare 683 mL of a 1...

What volumne of 10.83 M HNO3 is required to prepare 683 mL of a 1.9 M HNO3 solution? Answer in units of mL

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd