Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Show the basic definitions of coordination compounds, Q. Show the Basic Def...

Q. Show the Basic Definitions of coordination compounds? Some of the terms which we use in connection with coordination compounds carry specific meaning and thus form a kind of

Homolysis bond fission or homolytic, Homolysis bond fission or Homolytic ...

Homolysis bond fission or Homolytic (i) In homolysis bond, the covalent bond is broken in such a way that every resulting species gets its own electron. This is apt to the crea

Inorganic chemistry, which is having more atomic size alkali metals or alka...

which is having more atomic size alkali metals or alkaline earth metals#Minimum

Compressibility factor is unity at boyle''s temperature, Yes....because at ...

Yes....because at boyles law....ideal gas equation is used and z=1 for PV=nRT

Determine the purpose of quenching, Determine the purpose of Quenching ...

Determine the purpose of Quenching Quenching is most generally used to harden steel by introducing martensite, in which case steel should be rapidly cooled through its eutect

P-orbitals of an atom in presence of magnetic, p-orbitals of an atom in pre...

p-orbitals of an atom in presence of magnetic field are: (1)  Two fold degenerate (2) Non degenerate (3) Three fold degenerate (4) None of these Ans: Non degenerate

Preparation of dimethylbutan, Preparation of dimethylbutan: Procedur...

Preparation of dimethylbutan: Procedure: Prepare a mixture of 3,3-dimethylbutan-2-one (trivial name pinacolone; 20.0 g, 0.200 moles), redistilled benzaldehyde (24.0 g,

Preparation of iodoform, how will you test for the presence of the halogen ...

how will you test for the presence of the halogen in iodoform

Why boron is electron-deficient, Why boron is electron-deficient (a) E...

Why boron is electron-deficient (a) Every atom has an octet; thus, this is not an electron-deficient compound. (b) The boron is electron-deficient because it has a sextet o

Qualitative Analysis of Cations, We are asked to design a qualitative analy...

We are asked to design a qualitative analysis scheme that can be used to determine which cations are present in a solution containing only four of the following cations: Pb2+, Ag+,

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd