Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Solute standard state based on mole fraction, Q. For a solution process in ...

Q. For a solution process in which species B is transferred from a gas phase to a liquid solution, find the relation between Δ sol G 0 (solute standard state based on mole fracti

Inorganic, the diagnal relationship in periodic table

the diagnal relationship in periodic table

The maximum number of electrons, The maximum number of electrons present in...

The maximum number of electrons present in an orbit l= 3 , is: (1) 6        (2) 8       (3) 10       (4) 14 Ans: 14

Surface tension, Why liquids rise in the cappilary tube ? Explain.

Why liquids rise in the cappilary tube ? Explain.

#title.chemistiry of f-block elements., #question.all questions under lanth...

#question.all questions under lanthanides and actinides.

Laws of chemical combination, how many grams of silicon are present in 35 g...

how many grams of silicon are present in 35 grams of silicon?

Conjugate-base anion of diethyl malonate, Conjugate-base anion of diethyl m...

Conjugate-base anion of diethyl malonate The conjugate-base anion of diethyl malonate would be formed with sodium ethoxide, but it would not react with bromobenzene due to the

Cycloalkanes, Why cyclo propane is more stable than cyclohexane

Why cyclo propane is more stable than cyclohexane

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd