Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

What is the excitation power that has been used, What is the excitation pow...

What is the excitation power that has been used? The absorption cross section is a significant parameter for the calculation of the expected fluorescence signal from a single m

Alkane, Ask question pls tell me the reaction of ethane and chlorine#Minimu...

Ask question pls tell me the reaction of ethane and chlorine#Minimum 100 words accepted#

Alcohols, Preparation of dihydric alcohols

Preparation of dihydric alcohols

Determine the final pressure and steam condenses, A 15 m 3 tank contains s...

A 15 m 3 tank contains steam at 10 bar and 300 o C. The system is then cooled until the temperature reaches 150 o C . Some of the steam condenses. a) How much heat was transf

Atoms, What would be the benefit of knowing where the electrons are at any ...

What would be the benefit of knowing where the electrons are at any time?

Homweoek help, Determine the rate constant from the concentration-time depe...

Determine the rate constant from the concentration-time dependence: Time (s) [Reactant](M) 0.0 0.0451 2.0 0.0421 5.0 0.0376 9.0 0.0316 15 0.0226 Use SI units, that is, seconds fo

Calculate the ideal rm ratio for cation-anion, Calculate the ideal rM/rX ra...

Calculate the ideal rM/rX ratio for cation-anion and anion-anion contacts of an octahedral arrangement of anions around a cation as show in one plane in the figure below.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd