Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

MATTER AND CHEMISTRY FORMULAS, WE ARE WONDERING IF WE GOT THE ANSWER RIGHT ...

WE ARE WONDERING IF WE GOT THE ANSWER RIGHT V=d/M 0.8 G/Ml / 100G =400G

Standard solutions and titrations, How are standard solutions and titration...

How are standard solutions and titrations prepared in industry?

Define functional food, Q. Define functional food? Functional food is a...

Q. Define functional food? Functional food is a food that has a component incorporated into it to give a specific medical or physiological benefit, other than a purely nutritio

Wave, #quesdcsxxdxf tion..

#quesdcsxxdxf tion..

Vsper theory, #quest defination ,description prostulates

#quest defination ,description prostulates

Partition coefficient, what is the effect on the distribution of solute if ...

what is the effect on the distribution of solute if the solvents have mutual miscibility

Oxidizing and reducing agent, ionic equation for potassium dichromate and p...

ionic equation for potassium dichromate and potassium manganate

Explain about coordination isomerism, Q. Explain about Coordination Isomeri...

Q. Explain about Coordination Isomerism? Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position

The ph of an aqueous solution of ba(oh)2, The ph of an aqueous solution of ...

The ph of an aqueous solution of Ba(OH)2 is 10 if the ksp of Ba(OH)2 is 1*10^-9 then the concentration of Ba+2 ions in the aqueous solution is   Ans) [OH(-)] = 10^(-4) 2.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd