Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Neutrons than protons at high mass numbers because, Nuclei tend to have mor...

Nuclei tend to have more neutrons than protons at high mass numbers because: (1) Neutrons are neutral particles   (2) Neutrons have more mass than protons   (3) More neut

Reactivity, why HOH is not harmful to our body but Phenol is?

why HOH is not harmful to our body but Phenol is?

Resonance for the methyl group at room temperature, Resonance for the methy...

Resonance for the methyl group at room temperature The resonance for the methyl group at room temperature is a singlet. When the temperature is lowered, the resonance of this m

Production of nitrogen, Q. How to produce Nitrogen on Industrial Level? ...

Q. How to produce Nitrogen on Industrial Level? Ans. Nitrogen is produced by the fractional distillation of liquid air. Air is cooled to liquefy it. The liquid is then all

Organic- ammine, can we reduce r-cn to primary ammines using fe/hcl

can we reduce r-cn to primary ammines using fe/hcl

Selecting and numbering the principal chain, Selecting and Numbering the ...

Selecting and Numbering the principal chain Selecting the principal chain : choose the longest continuous chain of carbon atoms consisting of the principal functional

Solution, What will be the mole fraction of 98% pure H2SO4 in 1 liter solut...

What will be the mole fraction of 98% pure H2SO4 in 1 liter solution which has density 1.85gm/ml at ntp?

Illustrate resonance structures, Illustrate resonance structures that defin...

Illustrate resonance structures that define the electronic structure of benzene. Illustrate the structures of all conceivable disubstituted benzene isomers bearing two

What do you mean by solids non-fat, Q. What do you mean by Solids Non-Fat? ...

Q. What do you mean by Solids Non-Fat? Solid non-fat is an important criterion of milk selection for further processing. Milk solids non-fat would include the nitrogenous subst

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd