Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Bi, what is hi

what is hi

Organic chemistry, what is the structural formula of Hexane-1,6-dioic acid

what is the structural formula of Hexane-1,6-dioic acid

Method for detection of elements - oxygen, Method for Detection of Elements...

Method for Detection of Elements - Oxygen There is no any type of satisfactory qualitative method for the detection of oxygen. Though, its presence can be inferred indirectly.

Titration, how is back titration graphs drawn

how is back titration graphs drawn

S block elements in the modern periodic table, How many gaseous elements ar...

How many gaseous elements are there in the s block of modern periodic table? What are they??

Salt, what is the name of the precipitate and the formulae of the precipita...

what is the name of the precipitate and the formulae of the precipitate of NH3 (aq) and Pb(NO3)2 (aq)

How can we obtain boron, Q. How can we obtain Boron? Boron is- obtained...

Q. How can we obtain Boron? Boron is- obtained by the red-action of B 2 O 3 with magnesium or sodium B 2 0 3 is first prepared by strongly katingH 3 B0 3 which is obtained b

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd