Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

What are natural or synthetic food colours?, Q. What are natural or synthet...

Q. What are natural or synthetic food colours? Food in raw state has a natural colour, which is associated with the characteristics of that food. In the processing, preservatio

Nacl is dissolved in water the sodium ion, When  Nacl  is dissolved in wat...

When  Nacl  is dissolved in water the sodium ion becomes: (1) Oxidized                                       (2) Reduced   (3) Hydrolysed           (4) Hydr

The electron deficient compound, Which one is the electron deficient compou...

Which one is the electron deficient compound: (1) ICl                                                   (2)  NH 3                      (3)  BCl 3

Dna nucleotides - biomolecules, DNA nucleotides Adenine ...

DNA nucleotides Adenine + Deoxy ribose sugar + Phosphate → Adenosine phosphate Guanine

Laboratory apparatus in inorganic chemistry, what are the laboratory appara...

what are the laboratory apparatuses used in inorganic chemistry ?

Alkyl substituents on the double bond, Alkyl substituents on the double bon...

Alkyl substituents on the double bond 2,3-Dimethyl-2-butene has four alkyl substituents on the double bond. This alkene is more stable than 2,3-dimethyl-1-butene and 2-ethyl-1-

Periodic table and periodicity of properties, alkali metals belong to s-blo...

alkali metals belong to s-block in the periodic table.why?

EDTA titration, What is the principle of EDTA titration method

What is the principle of EDTA titration method

Electrolytic reduction of magnesium chloride, Electrolytic reduction of mag...

Electrolytic reduction of magnesium chloride Iron cell 2. Magnesium 3. Graphite anode 4. Porcelain hood 5. Iron cathode 6. Coal gas 7. Chlorine 8. Coal gas 9. Molten ele

How much heat is liberated?, How many KCal of heat are liberated when 48.0 ...

How many KCal of heat are liberated when 48.0 grams of iron are burned to form Fe2O3 at standard state conditions? (Change of Hf^0 of Fe2O3 is -197 kCal/Mole )

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd