Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Thermodynamics, work is not a state function. Explain

work is not a state function. Explain

Methods of characterization, Introduction Methods of characterization a...

Introduction Methods of characterization aim to calculate the products of a reaction. The level of detail expected depends on the circumstances, and calculates the range of met

Organic chemistry, how to do nomenclature in organic chemistry

how to do nomenclature in organic chemistry

STOCHIOMETARY, Ask quCOPPER REACT REACT WITH OXYGEN TO FORM TWO OXIDES X AN...

Ask quCOPPER REACT REACT WITH OXYGEN TO FORM TWO OXIDES X AND Y ON ANALYSIS 1.535g OF X YIELDED 1.365 OF COPPER AND 1.450 OF Y YIELDED 1.160g OF COPPER 1 DETERMIN THE CHEMICAL FOR

Solid state and quantum chemistry, What are laws of crystallography? How do...

What are laws of crystallography? How does it help in study of crystal structure?

Which carbonate mineral reacts with cool dilute hydrochloric, Which carbona...

Which carbonate mineral reacts readily with cool dilute hydrochloric acid to produce visible bubbles of carbon dioxide gas? Many carbonate minerals.

Explain about radioactive dating, Q. What do you know about Radioactive Dat...

Q. What do you know about Radioactive Dating? Ans. Half-life measurements of radioactive elements in rocks and fossils can be used to determine the age of the specimen. On

Fats and oils, what are the composition of fats and oils?

what are the composition of fats and oils?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd