Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Citric Acid, What are some chemical properties of citric acid?

What are some chemical properties of citric acid?

Azimuthal quantum number defines, Azimuthal quantum number defines: (1)...

Azimuthal quantum number defines: (1) e/m ratio of electron (2) Spin of electron (3) Angular momentum of electron (4) Magnetic momentum of electron Ans:  Angular mo

Carbon and its compounds, Carbon And its Compounds Carbon is a typical ...

Carbon And its Compounds Carbon is a typical non-metal present in earth's crust to the extent of 0,02% by mass. All living organisms contain carbon and hydrogen as their ess

Sets of quantum numbers is correct for an electron, Which of the following ...

Which of the following sets of quantum numbers is correct for an electron in 4f orbital: (1) n-=4, l=3. m+1, s= +1/2              (2) n-=4, l=4. m-4, s= -1/2

Analytical chemistry, purification of ammonium chloride using set up

purification of ammonium chloride using set up

#title.Honey ., Ask Dear Sir Greetings Please be informed that I am an expe...

Ask Dear Sir Greetings Please be informed that I am an expert in Beekeeping at my Univ. We are intending to open new Dept. under the name under Honey Bee Dept. Consequently, we ne

Chemical equation, why is it useful to use moles to measure chemical quanti...

why is it useful to use moles to measure chemical quantities

How tert-butylamine is prepared, Tert-butylamine Tert-butylamine cannot...

Tert-butylamine Tert-butylamine cannot be prepared by the Gabriel synthesis because it would require that the nitrogen of phthalimide be alkylated with tert-butyl bromide in an

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd