Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Show electron dot diagrams for covalent bonds, Q. Show Electron Dot Diagram...

Q. Show Electron Dot Diagrams for Covalent Bonds? Ans. Electron dot diagrams for covalent bonds In covalent bonds, atoms share electrons in such a manner that each atom

Basic organic chemistry, can you locate ortho,meta para positions on a benz...

can you locate ortho,meta para positions on a benzene ring

Why vitamine c is not stored in our body ?, There are two type of vitamine...

There are two type of vitamines 1.water soluble 2.fat soluble water soluble vitamines are B complex and C vitamines vitamine c is soluble in water so dissolve in water and ca

S block elements, Why lithium and beryllium markedly differ from other memb...

Why lithium and beryllium markedly differ from other members of their respective groups?

Quantitative Analysis, A hydrocarbon z with molecular mass 78 on combustion...

A hydrocarbon z with molecular mass 78 on combustion gave 3.384g of carbon (IV) oxide and 0.693g of water. Determine the molecular formula of Z and draw its structure. [H=1, C=12,

Acid base titration, the given solution contains 2.5g of laundry soap disso...

the given solution contains 2.5g of laundry soap dissolved per 250 cubic cm.determine the amount of free alkali in 350 cubic cm.

The following is least soluble, Which of the following is least soluble: ...

Which of the following is least soluble: (1) BeF 2                                              (2)  NaBr                  (3)  CaF 2                              (4

Lubrcants, Respected Mam/Sir Please tell me the detailed inforamtion about ...

Respected Mam/Sir Please tell me the detailed inforamtion about lubricant in metal rubbing

Halides of boron and aluminium, Q. Halides of Boron and Aluminium? All ...

Q. Halides of Boron and Aluminium? All the elements of Group 13 form binary halides. All the four trihalides of each element are known, with one exception. The compound Tl13 is

The wavelength associated with its motion, A cricket ball of 0.5 kg  is mov...

A cricket ball of 0.5 kg  is moving with a velocity of  100 m/ sec . The wavelength associated with its motion is: (1) 1/ 100cm                        (2) 6.6 x10 -34 m

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd