Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Tetracyclines - drugs and medicines, Tetracyclines: The tetracyclines ...

Tetracyclines: The tetracyclines consist of hydronapht-hacene skeleton like the characteristic structural unit. The structures of tetracycline are specified as follows,

Describe about temperature scales, Q. Describe about temperature scales? ...

Q. Describe about temperature scales? The temperature of an entity explains how hot or cold the object is relative to other objects. Scientists utilize two temperature scales-t

Explain about coordination isomerism, Q. Explain about Coordination Isomeri...

Q. Explain about Coordination Isomerism? Coordination Isomerism: If the complex is a salt having both cation and anion as complex ions then the ligands can exchange position

The effect of temperature on the enzyme betaglucosid, What is the rate of r...

What is the rate of reaction at the optimum temperature? (the starting concentration of the protein was 2 mg/ml, the Extinction coefficient (e) of the chromogenic product is A515 =

D block elements , explain why Cu2+ ion is not stable in aqueous solution?

explain why Cu2+ ion is not stable in aqueous solution?

Standard temperature and pressure, Q.Waht are Standard Temperature and Pres...

Q.Waht are Standard Temperature and Pressure? Ans. The agreed set of conditions for comparison of gas volumes is called  standard temperature and pressure  (abbreviated

Electronic configuration of c is, Electronic configuration of C  is: (...

Electronic configuration of C  is: (1) 1s 2 , 2s 2 , 2p 2 ,                               (2) 1s 2 , 2s 2 , 2p 3 (3) 1s 2 , 2s 2 ,            (4) 1s 2 , 2s 2 , 2p 6

Buffers , does adding hcl to acetic acid and sodium acetate = more acid con...

does adding hcl to acetic acid and sodium acetate = more acid consumption r spodium consupmtion?>

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd