Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Atoms, what is the gram atomic mass of hydrogen and oxygen?

what is the gram atomic mass of hydrogen and oxygen?

Radioanalytical methods, Radioanalytical methods: Radioanalytical meth...

Radioanalytical methods: Radioanalytical methods using radiotracers and activation analysis are more sensitive and specific because of ease of detection of nuclear radiation.

Chemical properties of ethers, Chemical Properties of Ethers Ethers are...

Chemical Properties of Ethers Ethers are fairly stable compounds. These are not simply reacted along with alkalies, dilute mineral acids, active metals, oxidising agents within

Preparation of cyclohexanol from cyclohexene, 1)why hydroboration leads to ...

1)why hydroboration leads to anti-markovnikov addition of hydrogen whereas most electrophilic additions to alkenes result in Markovnikov addition. 2) draw the full mechanism and id

Enthalpy change, Question: Does the number of steps in a reaction process a...

Question: Does the number of steps in a reaction process affect the enthalpy change of the overall reaction? Hypothesis: To compare experimental data to functionality of He

What is the mechanism of e1cb?, E1cb means elimination, unimolecular, of th...

E1cb means elimination, unimolecular, of the conjugate base. This type elimination proceeds through the carbanion mechanism. An carbon compound, acting as an acid, is attacked by

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd