Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

What is electrode potential?, When a strip of metal (M) is brought in conta...

When a strip of metal (M) is brought in contact with the solution containing its own ions (Mn+), then either of the following three possible processes can take place:      The meta

Safety in the laboratory, Laboratory safety During your observation of che...

Laboratory safety During your observation of chemistry you will conduct experiments in the laboratory. When working in the lab you are accountable for the safety of yourself and o

What are the physical properties of nitric acid, Q. What are the Physical P...

Q. What are the Physical Properties of Nitric Acid? Ans. Nitric acid (HNO 3 ) may be prepared by heating sodium nitrate with sulfuric acid: NaNO 3 + H 2 SO 4 --> HNO

Naming a type of isomerism and how it arises?, For">http://imageshack.us/ph...

For">http://imageshack.us/photo/my-images/213/chemistyr.png/ For these structures? I''m not sure how to answer it.

Beer lambartslambart''s law, Plz tell me the units of absorptivity if it ha...

Plz tell me the units of absorptivity if it has any units

Photochemistry, How to prepare my seminar paper ?

How to prepare my seminar paper ?

Illustrate properties of protons and neutrons, Q. Illustrate Properties of ...

Q. Illustrate Properties of Protons and Neutrons? Ans. We now know that following fundamental properties of protons and neutrons: 1. The proton has a charge of +1, which

What are the physical properties of halogens, Q. What are the Physical Prop...

Q. What are the Physical Properties of Halogens? Ans. The halogens exist as  diatomic  molecules held together by a single bond. Reactivity becomes less as you move down

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd