Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Periodic table, Alkali metals belong to S-block ? why?

Alkali metals belong to S-block ? why?

Project, Preparation of saturated calomel electrode and determination of st...

Preparation of saturated calomel electrode and determination of standard potentials of electrodes such as Cu 1 Cu, Zn 1 Zn, etc. Comparison of the potential values with values from

Separation techniques, what technique can be used to improve water quality ...

what technique can be used to improve water quality ?

How to calculate rate constant of first order reaction, find the rate const...

find the rate constant of first order reaction if 75% of reaction is completed in 6.03 sec

Colloidal system, How many types of colloidal system? and which are they?

How many types of colloidal system? and which are they?

Degree of unsaturation procedure, what is the procedure on how to get degre...

what is the procedure on how to get degree of unsaturation in a fruit

Hyperconjugative effect - organic chemistry, Hyperconjugative effect Wh...

Hyperconjugative effect While a H-C bond is attached to an unsaturated system like double bond or a benzene ring, the sigma (σ) electrons of the H-C bond interact or enter into

Balancing equations, What methods can I use to understand balancing equatio...

What methods can I use to understand balancing equations?

Solubility Product Constant , The known metal ion solution used contains 0....

The known metal ion solution used contains 0.10 M of each of the six metal ions (i.e. 0.10 M Ag+ and 0.10M Pb2+). An equal volume of 3 M HCl and the known solution are mixed. What

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd