Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Comparison of alkyl cyanides and alkyl isocyanides, Test Ethyl c...

Test Ethyl cyanide Ethyl isocyanide Smell Strong but pleasant Extremely unpleasant Dipole moment

A completely filled d -orbital, A completely filled d -orbital ( d 10 ): ...

A completely filled d -orbital ( d 10 ): (1) Spherically symmetrical (2) Has octahedral symmetry (3) Has tetrahedral symmetry (4) Depends on the atom Ans: Spherical

Illustrate boyles law, Q. Explain Boyles law with volume and pressure graph...

Q. Explain Boyles law with volume and pressure graph? Ans. Boyle's law demonstrates the relationship between the volume (V) and pressure (P) of a gas. This law shows that th

Vulcanization of rubber - polymer, Vulcanization of rubber The procedur...

Vulcanization of rubber The procedure of heating natural rubber with sulphur to enhance its properties is known as vulcanization. Vulcanization was illustrated by Charles Goody

Acyclic or open-chain compounds, Acyclic or open-chain compounds Organi...

Acyclic or open-chain compounds Organic compounds where all types of the carbon atoms are associated to one another to form open chains (straight or branched) are known as acyc

Explain the extraction of sulphur, Q. Explain Extraction of Sulphur? Th...

Q. Explain Extraction of Sulphur? The most important method for the extraction of sulphur from native deposits is the frasc process developed by Herman frach in 1891. It consis

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd