Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Simple distillation, n-propyl acetate evaporates rapidly when exposed to ai...

n-propyl acetate evaporates rapidly when exposed to air,but water does not.Explain

Uses of benzene - hydrocarbon, Uses of Benzene - Hydrocarbon (1) In dry...

Uses of Benzene - Hydrocarbon (1) In dry cleaning (2) As a motor fuel when mixed with petrol. (3) As a solvent. (4) In the manufacture of gammexane (As insecticide).

Physical chemisty, Calculate the ratio of d number of molecules in two ener...

Calculate the ratio of d number of molecules in two energy levels at 27''c given E2=9.75x10"-13erg/mol E1=6.95X10"-13erg/mol g1=2 g2=3

One-dimensional box of length l, For a particle confined to a one-dimension...

For a particle confined to a one-dimensional box of length L, determine the probability that the particle is in the central third of the box (the middle section when the box is div

TLC, Mesh size of silica gel for prep tlc

Mesh size of silica gel for prep tlc

Prefixes, why we consider methyl using prefixes?

why we consider methyl using prefixes?

Noble gas, please help me to do assignment about noble gas.

please help me to do assignment about noble gas.

Help please!, Methane (CH4), or natural gas, is commonly used all over the ...

Methane (CH4), or natural gas, is commonly used all over the world as a source of energy and fuel. Many homes in the United States combust methane to generate heat for hot water he

107, assignement

assignement

Obtain by product - contain neither sulfur nor oxygen atom, A student attem...

A student attempting to sulfonate styrene (vinyl benzene) obtains a by product that contains neither sulfur nor oxygen atoms. Efforts to nitrate styrene yield identical results. Of

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd