Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Mahendra, transition elements form coloured compound. Why?

transition elements form coloured compound. Why?

Hardness of water, (a) What is hardness of water? What do you understand ...

(a) What is hardness of water? What do you understand by temporary and permanent hardness?                                                            OR Explain tempora

Fehlings test, what is fehlings test and its reagent?

what is fehlings test and its reagent?

What do you understand by marine biodiversity, Question : (i) What do ...

Question : (i) What do you understand by marine biodiversity? (ii) Give full nomenclature (common and scientific names) for species from marine fauna and species from mari

Caculate the molar mass of the solute, A solution is made by dissolving30 g...

A solution is made by dissolving30 g of a non-volatile solute in 90 g of water. It has a vapour pressure of 2.8 kPa at 298 K. At 298 K, vapour pressure of pure water is 3.64 kPa

WESTRON, explain industrial manufacturing process of westron and explain th...

explain industrial manufacturing process of westron and explain the advantages and disadvantages of westron

What are the physical properties of nitric acid, Q. What are the Physical P...

Q. What are the Physical Properties of Nitric Acid? Ans. Nitric acid (HNO 3 ) may be prepared by heating sodium nitrate with sulfuric acid: NaNO 3 + H 2 SO 4 --> HNO

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd