Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Show the techniques of preservation, Q. Show the techniques of preservation...

Q. Show the techniques of preservation? The various methods can be used for preservation of foods. Some of the common methods employed to preserve foods are summarized herew

Sum of its enthalpy, What is basically Gibb''s free energy change? Ans) Th...

What is basically Gibb''s free energy change? Ans) The energy associated with a chemical reaction that can be used to do work.  The free energy of a system is the sum of its entha

Explain the shelf life, Normal 0 false false false EN-U...

Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4

The electron deficient compound, Which one is the electron deficient compou...

Which one is the electron deficient compound: (1) ICl                                                   (2)  NH 3                      (3)  BCl 3

The maximum number of electrons, The maximum number of electrons accommodat...

The maximum number of electrons accommodated in 5f  orbitals are: (1) 5             (2) 10         (3) 14             (4) 18 Ans:  14

Edta, #questionQ1. 0.28gm of CaCO3 was dissolved in HCl and the solution wa...

#questionQ1. 0.28gm of CaCO3 was dissolved in HCl and the solution was made to one litre with distilled water. 100 ml of the above solution required 28 ml of EDTA solution on titra

Orgenic, libermann nitroso reaction

libermann nitroso reaction

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd