Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Determien the least ionic, Which of the following is least ionic: (1) C...

Which of the following is least ionic: (1) C 2 , H 5 Cl                                       (2)  KCl                     (3)  BaCl 2               (4)  C 6 H 5 +

Explain the major modes of food deterioration, Major modes of food deterior...

Major modes of food deterioration During storage and distribution, foods are exposed to a wide range of environmental conditions. Environmental factors such as temperature, hum

How can we obtain pure alumina, Q. How can we obtain Pure alumina? Pure...

Q. How can we obtain Pure alumina? Pure alumina is obtained from bauxite ore. Powdered bauxite mineral is heated in a concentrated solution of sodium hydroxide under pressure w

Define colligative properties of a dilute solution, Define Colligative Prop...

Define Colligative Properties of A Dilute Solution? The colligative properties of a solution are usually considered to be: 1. Freezing-point depression: the decrease in the

Molar conductivity, What do you understand by molar conductivity at infinit...

What do you understand by molar conductivity at infinite dilution

Mole M&M problem, 200.0 M&Ms mass out at 175 grams. How many tons of M&Ms a...

200.0 M&Ms mass out at 175 grams. How many tons of M&Ms are there in one mole?

Acetaldehyde, what could be the distillate present in acetaldehyde after pr...

what could be the distillate present in acetaldehyde after preparation in lab

Credit cards, Credit Cards Credit cards are offered by banks, as well ...

Credit Cards Credit cards are offered by banks, as well as other institutions such as credit unions. There are numerous credit cards currently available in the market, each wi

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd