Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Why vitamine c is not stored in our body ?, There are two type of vitamine...

There are two type of vitamines 1.water soluble 2.fat soluble water soluble vitamines are B complex and C vitamines vitamine c is soluble in water so dissolve in water and ca

Define the term "rice bran", Rice bran Rice bran contains primarily ins...

Rice bran Rice bran contains primarily insoluble fiber (cellulose) and soluble fiber (hemicellulose). Insoluble fiber adds bulk to the gastrointestinal (GI) track in humans cau

Applications of coordnation complexes in medicines, what are medicinal appl...

what are medicinal applications of coordination complexes

Technique error affect the reported activation energy, 1. The temperature o...

1. The temperature of the warm water bath is recorded too high. How will this technique error affect the reported activation energy for the reaction - too high or too low? explain

Law , explain law of equivalence..

explain law of equivalence..

Effect of substituents on acidity - inductive effect, Effect of Substituen...

Effect of Substituents on Acidity: The complete effect of a substituent on acidity of substituted benzoic acids is because of two factors. (i) Inductive effect: If the subs

Beer lambartslambart''s law, Plz tell me the units of absorptivity if it ha...

Plz tell me the units of absorptivity if it has any units

EDTA titration, What is the principle of EDTA titration method

What is the principle of EDTA titration method

No molecule acts as a passitive and negative ligand. why?, Molecule in itse...

Molecule in itself is electrically stable so it cant act as ligand So that it can acts as the negative and pasitive ligand.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd