Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Boiler troubles and their consequences, Q. What are boiler troubles? Discus...

Q. What are boiler troubles? Discuss their consequences? Sol. Boiler feed water (water for steam making): water is very important engineering material which is mainly used fo

Eqivalent weight of an element, what is n-factor and what is the formula fo...

what is n-factor and what is the formula for calculating it

What happens if lattice energy increases, a) The Strength of ionic bond ...

a) The Strength of ionic bond b)  Stability of the Ionic compound c)  Ease of formation of the Ionic bond enhances

Mesomeric effect, what are the differences between positive and negative me...

what are the differences between positive and negative mesomeric effect

Moles to grams, determine the no of atom in 4.5g of k

determine the no of atom in 4.5g of k

Describe about halide minerals, Q. Describe about Halide Minerals? High...

Q. Describe about Halide Minerals? Highly electropositive alkali and alkaline earth metals tend to form halide salts, which being soluble in water are washed away into the ocea

Dunstan''s test, what are the equacyions of Dunstan''s test ???

what are the equacyions of Dunstan''s test ???

The properties of buffers, while gibing the ph and the volume intial and fi...

while gibing the ph and the volume intial and final how do we calculate the number of moles

ELECTROCHEMISTRY, AT 25 DEGREES CELCIUS,THE MOLAR IONIC CONDUCTIVITIES OF C...

AT 25 DEGREES CELCIUS,THE MOLAR IONIC CONDUCTIVITIES OF CALCIUM IONS,MAGNESIUM IONS AND ZINC IONS 3.87,5.01 AND 7.35 MILISECONDS SQUARE METRE PER MOLE RESPECTIVELY.CALCULATE THEIR

Electrons in atom having quantum value 4, What is the maximum number of ele...

What is the maximum number of electrons which can be accommodated in an atom in which the highest principal quantum number value is 4: (1) 10        (2) 18      (3) 32

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd