Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Halides, The elements of this group form a number of compounds with halogen...

The elements of this group form a number of compounds with halogens. The halogen compounds of S. Se, Te and Po are called as halides. For oxygen, only the fluoro compounds

Organic chemistry, advantages and disadvantages of westron

advantages and disadvantages of westron

Liquefaction of gases, Assainment of liquefaction of gases in degr...

Assainment of liquefaction of gases in degree 2 nd sem

Describe water and heavy water, Q. Describe Water and Heavy Water? Wate...

Q. Describe Water and Heavy Water? Water, H 2 O, the simple hydride of oxygen is a unique compound. It has extraordinarily high melting and boiling points compared to the other

HYDROGEN, #questionWHY LANE''S PROCESS IS ALSO KNOWN AS VIVIFICATION PROCES...

#questionWHY LANE''S PROCESS IS ALSO KNOWN AS VIVIFICATION PROCESS?..

#thermochemistr, can all the total heat content available betotally convert...

can all the total heat content available betotally converted to work done?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd