Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Water pressure is the same in all directions, Water pressure is the same in...

Water pressure is the same in all directions Punch holes around the base of a tall tin can with a nail. Wrap the holes as above with a strip of tape. Fill the can with water an

Stoichiometry, How do i calculate the number of grams of CO that can react ...

How do i calculate the number of grams of CO that can react with .150kg of Fe2O3?

Condensation reaction of carbonyl compounds, Condensation reaction of carbo...

Condensation reaction of carbonyl compounds Nucleophilic addition reaction of compounds comprising carbonyl group along with those compounds that have at least one acidic hydro

Thermodynamics, what are macroscopic properties ?

what are macroscopic properties ?

Ionic compounds do not have, Ionic compounds do not have: (1) Hard and ...

Ionic compounds do not have: (1) Hard and brittle nature (2) High melting and boiling point (3) Directional properties (4) Soluble in polar solvents Ans:  Direction

Freezing Point Depression, A solution is prepared with 3.85g of a non-ionic...

A solution is prepared with 3.85g of a non-ionic unknown compound in 100.0g cyclohexane. The solution had a freezing point of 4.18 degrees Celsius. What is the molar mass of the un

DIENES, PREPARATIONS OF DIENES

PREPARATIONS OF DIENES

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd