Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Find an expression for galvanic cell, Q. The state of a galvanic cell witho...

Q. The state of a galvanic cell without liquid junction, when its temperature and pressure are uniform, can be fully described by values of the variables T, p, and . Find an expre

Conductometric titration, how to write a good lab report on conductometri t...

how to write a good lab report on conductometri titration?

Evolution of the modern atomic model, Q. Evolution of the Modern Atomic Mod...

Q. Evolution of the Modern Atomic Model? Ans: The atomic models of Dalton, Thomson, Rutherford, and Bohr eventually evolved into the current-day Quantum Mechanical model of the

D block elements, what is the general electronic configuration of d block e...

what is the general electronic configuration of d block element

Bohr''s principle the relation between principle quantum no, According to B...

According to Bohr's principle, the relation between principle quantum number and radius of orbit is: (1) r ∞ n    (2) r ∞ n 2       (3) ∞1/n  (4) r∞ 1/ n 2 Ans:  r

Simple distillation, n-propyl acetate (bp 102 C) evaporates rapidly when ex...

n-propyl acetate (bp 102 C) evaporates rapidly when exposed to air, but water(bp 100C)does not. Explain why

Uses of acetic anhydride - carboxylic acids, Uses of Acetic anhydride (...

Uses of Acetic anhydride (a) Acetic anhydride is used as an acetylating agent. (b) Acetic anhydride is used for the detection and estimation of hydroxyl and amino group.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd