Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

What is the dipole moment of chloro-octane, What is the dipole moment of ch...

What is the dipole moment of chloro-octane? Ans) There are many forms of the molecule "chloro-octane." This is due to the chlorine atom can be attached to the octane chain in va

Mechanism of Methanol, What are the different mechanism to produce methanol...

What are the different mechanism to produce methanol(CH3OH)?

Explain the following, Lithium and beryllium markedly differ from other mem...

Lithium and beryllium markedly differ from other members of their respective groups? Read more: http://wiki.answers.com/Q/Lithium_and_beryllium_markedly_differ_from_other_members

Transition elements, Why transition elements form interstitial compound

Why transition elements form interstitial compound

Organic, Few methods preparation of cyacloalken

Few methods preparation of cyacloalken

Catalysis, #question:- What are the theories of catalysis?

#question:- What are the theories of catalysis?

Illustrate classification of matter, Q. Illustrate Classification of Matter...

Q. Illustrate Classification of Matter? Pure Substances In order to understand what a pure substance is, you must think of it on an atomic level. Elements and compounds

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd