Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Periodic table, lithium and beryllium markedly differ from other members of...

lithium and beryllium markedly differ from other members of their respective groups.

Lab report, how to write a lab report

how to write a lab report

Illustrate Chemical nomenclature, Q. Illustrate Chemical nomenclature? ...

Q. Illustrate Chemical nomenclature? Ans. Chemical nomenclature is the system of names that chemists use to identify compounds precisely. The systematic method of naming c

Conductivity, List three factor that affect conductivity

List three factor that affect conductivity

IUPAC Naming, Could you please provide me the priority order of polyfunctio...

Could you please provide me the priority order of polyfunctional prefixes

Determine discharge coefficient, The determination of k is not a strait for...

The determination of k is not a strait forward exercise. Model it from first principles using Bernoulli's equation would produce a square root relationship and would probably have

Determine mass of an electron, Q. Determine mass of an electron? Ans. ...

Q. Determine mass of an electron? Ans. Three years later after J.J Thomson discovered the electron, the American scientist Robert Millikan used an oil drop experiment to accu

Bondletgth of nitroalkanes, In nitromethane N-O bondlength is 1.21A° while...

In nitromethane N-O bondlength is 1.21A° while normal N-O bondlength is 1.36 A° and for N=O it is 1.18A°..Explain why

S block., prperties of s block elements?

prperties of s block elements?

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd