Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Borax bead test - chemical analysis, Borax bead test : The transparent ...

Borax bead test : The transparent glassy bead while heated along with inorganic salt and the colour produced gives some idea of cation present in it. Table:

Types of interferences, Types of interferences: The various kinds of i...

Types of interferences: The various kinds of interferences encountered in analysis through flame photometry are: Spectral interferences Ionisation interferences

Recrystallization, what is the relationship between the rate of cooling and...

what is the relationship between the rate of cooling and the size of crystals?

Melting point - physical charterstics of monocarboxylic acid, Melting point...

Melting point - physical charterstics of monocarboxylic acids (a) The melting points of carboxylic acids do not change smoothly from one member to other member. (b) The melt

F block, electronic configuration of lanthanides

electronic configuration of lanthanides

What are the disadvantages of cold working, What are the Disadvantages of c...

What are the Disadvantages of cold working (i) Higher forces are required for deformation. (ii) Heavier and more powerful equipment is required. (iii) May produce undesir

Radioactivity, what is the principal of radiometric titration

what is the principal of radiometric titration

Metamerism - type of isomerism, Metamerism - Type of Isomerism This typ...

Metamerism - Type of Isomerism This type of isomerism is due to the difference in the nature of alkyl groups attached to the polyvalent atoms or functional set. Metamers always

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd