Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Objective of elements of group 16, Q. Objective of elements of group 16? ...

Q. Objective of elements of group 16? You should be able to: • describe the occurrence, extraction and uses of the elements of Group 16, • describe the allotropic forms o

Regenerated by heating, Desiccants (drying agents) can often be regenerated...

Desiccants (drying agents) can often be regenerated by heating.  A desiccant that is commonly regenerated is CaSO 4 ?2H 2 O:

Why we use boron, Q. Why we use Boron? Boron is used to increase the ha...

Q. Why we use Boron? Boron is used to increase the hardness of steels. Crystalline boron is used in transistors. Boron is a good neutron absorber and is used as shields and con

Determine the calories, The Calorie, used to express food heat values, is s...

The Calorie, used to express food heat values, is similar as a kilocalorie of heat energy . If you eat a chocolate bar from the United States with 600 Calories of food energy, how

Explain limiting radius., The ratio among the radius of cation and the radi...

The ratio among the radius of cation and the radius of anion is known as Limiting radius.

Carbon and its compounds, Carbon And its Compounds Carbon is a typical ...

Carbon And its Compounds Carbon is a typical non-metal present in earth's crust to the extent of 0,02% by mass. All living organisms contain carbon and hydrogen as their ess

In heisenberg''s uncertainty equation, In Heisenberg's uncertainty equation...

In Heisenberg's uncertainty equation Δ x ×Δ p ≥ h/ 4 Π  ;   stands for: (1) Uncertainty in energy    (2) Uncertainty in velocity (3) Uncertainty in momentum (4) Uncert

Explain four applications of adsorption, a. How can a colloidal solution an...

a. How can a colloidal solution and true solution of the similar colour be distinguished from each other? b. Give four applications of adsorption

Radicals, trivalent acid and basic radicals

trivalent acid and basic radicals

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd