Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

N factor, how to calculate the n factor for redox reaction involving comple...

how to calculate the n factor for redox reaction involving complex scenarios and more than two exchanges..

Determined intrinsic viscosity, The table below gives intrinsic viscosity v...

The table below gives intrinsic viscosity values determined by viscometry and weight- average molar mass values determined under the same conditions by static light scattering

Substances like platinum and palladium, Normal 0 false false ...

Normal 0 false false false EN-IN X-NONE X-NONE MicrosoftInternetExplorer4

Crude and dietary fibre, Q. Crude and Dietary Fibre? Crude fibre is the...

Q. Crude and Dietary Fibre? Crude fibre is the organic residue which remains after the food sample has been treated with boiling dilute sulphuric acid, boiling dilute sodiu

Applications of atomic fluorescence spectrometry, Applications of atomic fl...

Applications of atomic fluorescence spectrometry: In common AFS is used to determine the concentration stages of elements in samples (elemental analysis). For favorable elemen

Illustrate si system, Q. Describe SI System and Standards Ans: Wh...

Q. Describe SI System and Standards Ans: What units you will you use science class? Long ago people decided that the "foot" must be standardized so that when I measure

Preparation of hot souffle?, Q. Preparation of hot souffle ? i) Melt 1...

Q. Preparation of hot souffle ? i) Melt 12 g butter in a saucepan. Add 12 g flour and stir cook for 1-2 minutes. ii) Gradually add ¼ cup of scalded milk stirring continuou

Chemical properties, chemical properties with reactions of alkali metals

chemical properties with reactions of alkali metals

Discuss the various annealing processes, Explain objectives of annealing? D...

Explain objectives of annealing? Discuss the various annealing processes? Is spheroidising different from annealing? Illustrate. A  slow  cooling  rate  from  eutectoid  tempe

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd