Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Determine the impurities in the sample of oil, Q. Determine the impurities ...

Q. Determine the impurities in the sample of oil? After conducting this activity, you will be able to: • determine impurities such as total dirt and organic dirt in the giv

Antifertility drugs - chemistry in action, Antifertility drugs: These a...

Antifertility drugs: These are the chemical substances employed to manage the pregnancy. These are as well known as oral contraceptives. The fundamental plan of anti fertility

Why vitamine c is not stored in our body ?, There are two type of vitamine...

There are two type of vitamines 1.water soluble 2.fat soluble water soluble vitamines are B complex and C vitamines vitamine c is soluble in water so dissolve in water and ca

Find out the temperature of ellingham diagrams, Q. Find out the temperature...

Q. Find out the temperature of Ellingham diagrams? Ellingham diagrams are very useful for finding out the temperature at which appreciable reaction occurs. The lower the ΔG 0

Hybridation, hybridisation of o in boric acid

hybridisation of o in boric acid

CALORIMETRY, when a 0.800g sample of CaCl2 is dissolved in 9.85g of water i...

when a 0.800g sample of CaCl2 is dissolved in 9.85g of water in a microscale calorimeter the temperature of the solution rose from 23.4 degrees celcius to 35.8 degrees celcius.calc

Show the rate of decrease in atomic radius, Q. Show the rate of decrease in...

Q. Show the rate of decrease in atomic radius? The rate of decrease in atomic radius along the lanthanide series and also along the actinide series is even less than that in th

Explain generation of the electrophile, Generation of the electrophile : Th...

Generation of the electrophile : The electrophile is the carbocation produced by protonation of the alcohol  oxygen and loss of water.

.plastic, what gases are released when the plastic is burnet

what gases are released when the plastic is burnet

Fractose does not have an aldehydic group, Although fractose does not have ...

Although fractose does not have an aldehydic group, it reacts with Fehling solution Explain why? Ans)  Fructose is a ketone first we cnvert it into aldehyde by reacting fructse

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd