Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Determine the final pressure and steam condenses, A 15 m 3 tank contains s...

A 15 m 3 tank contains steam at 10 bar and 300 o C. The system is then cooled until the temperature reaches 150 o C . Some of the steam condenses. a) How much heat was transf

Evaluate percentage fat content in milk, Q. Evaluate percentage Fat Content...

Q. Evaluate percentage Fat Content in Milk? The fat content in milk can be determined through various procedures as: Direct determination of fat by extraction with ether - A

Describe conformation energy profile -ethane, Describe Conformation energy ...

Describe Conformation energy profile -Ethane   Conformation energy profile for ethane

The number of orbitals in the fourth principal quantum no., The number of o...

The number of orbitals in the fourth principal quantum number will be: (1) 4               (2) 8        (3) 12               (4) 16 Ans: 16

Nucleophilic addition reactions, Nucleophilic addition reactions: While...

Nucleophilic addition reactions: While the addition reaction takes place on account of the initial attack of nucleophile, the reaction is known as a nucleophilic addition react

Aromatic nitro compounds, why are aromatic nitro compounds pale yellow in c...

why are aromatic nitro compounds pale yellow in colour

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd