Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Electronic configuration and position in periodic table, Q. Electronic Conf...

Q. Electronic Configuration and Position in Periodic Table? The outstanding feature of the actinide and lanthanide elements is the great similarity in chemical and physical pro

Molar conductivity, Molar conductivity: The rate of charge transfer is ...

Molar conductivity: The rate of charge transfer is proportional to the number of ions in the solution between the plates, which itself will vary with the concentration, c, of

General anesthetics - drugs and medicines, General Anesthetics: Genera...

General Anesthetics: General Anesthetics depress the central nervous system to like an extent that all sensitivity to pain or feeling is gone, that is they make unconsciousnes

Packing fraction, Why +ve P.F. gives nuclear instability where as -ve PF gi...

Why +ve P.F. gives nuclear instability where as -ve PF gives nuclear stability ?explain .

Concentration of the enzyme, The concentration of the product in the equili...

The concentration of the product in the equilibrium is enhancing with increasing concentration of the substrate.      ?     ? The concentration of the product in the equilibrium

Atomic number, A transition metal X   has a configuration [Ar] 3d 4    in i...

A transition metal X   has a configuration [Ar] 3d 4    in its +3 oxidation state. Its atomic number is: (1) 25      (2) 26      (3) 22     (4) 19 Ans: 25

The model of trans-bicyclo decane, The model of trans-bicyclo decane T...

The model of trans-bicyclo decane The model of trans-bicyclo[5.3.0]decane is easier to build. The larger is a ring, the easier it is to compress the dihedral angle of the tran

Explain about smelting process, Q. Explain about Smelting process? The ...

Q. Explain about Smelting process? The roasted ore, which is generally an oxide, is strongly heated with a suitable reducing agent as result of which the metal is acquired in a

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd