Equilibrium equation derivation, Chemistry

Assignment Help:
My problem is how should the specific equation be derived using boundary condition. I have the final equation (which is based on Langmuir isotherm) and I know the boundary condition as well so I just need to know how should I reach to the final equation using boundary condition? step by step.
The model is on the assumptions that (i) in a As–HA binary system, sorbent binding sites form complexes represented as SA when arsenic binding occurs and complexes denoted SH when HA is bound and (ii) equilibrium can be expressed as S+A ? SA, where K1 = [SA]/[S][A], S + H ? SH, where K2 =[SH]/[S][H] and A+H ? AH where K3=[AH]/[A][H]. In this model, considering an interactions resulting in SAH complexes, the equilibrium can be expressed as SA+H ? SAH, where K1,2=[SAH]/[SA][H], SH+A ? SHA, where K2,1=[SHA]/[SH][A] and S+AH ? SAH where K3,3=[SAH]/[S][AH]. Then one can assume S+A+H ? SAH and S+H+A ? SHA, where K=K1K1,2 = K2K2,1= K3K3,3. Assuming that the sorption system is in equilibrium (there are no net changes of [SA], [SH] and [SAH] with respect to time), the following can be written: d[SA]/dt = 0 , d[SH]/dt=0 and d[SAH]/dt=0 and [S0]=[S]+[SA]+[SH]+[SAH]
In such case, the model can be presented to the form:
qAs=(qmax Ce [As]{1+(K1/K )Ce [HA] })/({K1+Ce [As]+(K1/K2 ) Ce [HA]+2(K1/K) Ce [As] Ce [HA]})
So I need to know how I should reach to the above final equation using the mentioned assumptions?

Related Discussions:- Equilibrium equation derivation

Which of the following oxides nitrogen is isoelectronic co2, Which of the f...

Which of the following oxides of nitrogen is isoelectronic with CO 2: (1) No 2                 (2) N 2 O    (3) NO                (4)N 2 O 2 Ans:  N 2 O

Why nichrome and not copper is used as heating element, Explain why nichrom...

Explain why nichrome and not copper is used as heating element whereas manganin is used as standard resistance? For heating elements, primary requirements are high melting poin

Chemical in cosmetics, Chemical in cosmetics The phrase cosmetics are t...

Chemical in cosmetics The phrase cosmetics are taken from the Greek word Kosmetikos. The meaning of this is decorating. Beautifying or enhancing complexion of skin. In middle a

Hypothesis on chlorofluorocarbon, Q. Hypothesis on chlorofluorocarbon? ...

Q. Hypothesis on chlorofluorocarbon? A hypothesis is a probable explanation for what has been observed. Based on the explanation of ozone thinning and CFC build-up in the chemi

Predict the order of the reaction, Consider the reaction A → P. The change ...

Consider the reaction A → P. The change in concentration of A with time is shown in the given plot:  (i) Predict the order of the reaction.  (ii) Derive the mathematical expr

Which of the following sets is possible for quantum numbers, Which of the f...

Which of the following sets is possible for quantum numbers : (1) n=4, l=3, m= -2 , s=0  (2) n=4, l=4, m= +2 , s=1/2           (3) n=4, l=3, m= -2 , s=+1/2          (4)

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd