Equilibria, Chemistry

Assignment Help:

Equilibria

Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for every of these systems.

Conditions of equilibrium

For the general reaction:

aA+bB→cC+dD

The change in Gibbs free energy, ΔG (see Topic B6) for the reaction at a temperature, T, is given by:

728_gibbs energy.png 

 

Where Q is the reaction quotient,

The free energy change of both the reverse and the forward reaction is equal. This is when ΔGback=ΔG=0. In this case, the rate constants for the forward and back reactions, kf and kb, and the activities of reactants and products are such that both forward and reverse reactions are occurring at an equal rate and the reaction is at equilibrium.

 

1263_gibbs energy1.png


Related Discussions:- Equilibria

Hyperconjugation, I wanna knw what is alpha hydrogen and how to count it

I wanna knw what is alpha hydrogen and how to count it

Why carboxylate salts less reactive than esters, Carboxylate salts Car...

Carboxylate salts Carboxylate salts are less reactive than esters in nucleophilic acyl substitution reactions for two reasons.  First, resonance stabilization of carboxylate s

The bond is formed between similar atoms, Which type of bond is formed betw...

Which type of bond is formed between similar atoms: (1) Ionic    (2) Covalent      (3) Coordinate               (4) Metallic Ans:  Covalent

Molality of asolution, question..in which the molality is used? units of mo...

question..in which the molality is used? units of molality

Types of organic reactions - organic chemistry, Types of organic reactions ...

Types of organic reactions It is suitable to simplify the several reactions of the a variety of classes of organic compound into four types, Substitution reactions,

Salt analysis, chemical reactions that takes place during salt analysis for...

chemical reactions that takes place during salt analysis for class 12

Law of chemical combination, law of chemical combination with aim,introduct...

law of chemical combination with aim,introduction and conclution

The phosphate of a metal has the formula mpo4, The phosphate of a metal has...

The phosphate of a metal has the formula MPO4 .The formula of its nitrate will be: (1) MNO 3                                                   (2)  M 2 (NO 3 ) 2

Need of tar, If you have not used tar before, try this sequence to makeanar...

If you have not used tar before, try this sequence to makeanarchive ofyour llast project: %cd;tar cf llast.tar llast %tar tfv llast.tar The first line m vesyou to your hom

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd