Equilibria, Chemistry

Assignment Help:

Equilibria

Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for every of these systems.

Conditions of equilibrium

For the general reaction:

aA+bB→cC+dD

The change in Gibbs free energy, ΔG (see Topic B6) for the reaction at a temperature, T, is given by:

728_gibbs energy.png 

 

Where Q is the reaction quotient,

The free energy change of both the reverse and the forward reaction is equal. This is when ΔGback=ΔG=0. In this case, the rate constants for the forward and back reactions, kf and kb, and the activities of reactants and products are such that both forward and reverse reactions are occurring at an equal rate and the reaction is at equilibrium.

 

1263_gibbs energy1.png


Related Discussions:- Equilibria

Show the extraction of oxygen, Q. Show the Extraction of Oxygen? Oxygen...

Q. Show the Extraction of Oxygen? Oxygen is separated from air on a large scale by the fractional distillation of liquid air. It is obtained as a by-product along with hydrogen

Density of natural waters, Certain basic properties of lakes and oceans are...

Certain basic properties of lakes and oceans are important to understanding how they "work". One of these is the density of the water, and its changes. Dense (or heavier) water wan

Ionic bonds, ionic bonds are usually formed by combination of elements with...

ionic bonds are usually formed by combination of elements with

Mention the stages in product life cycle, Q. Mention the stages in product ...

Q. Mention the stages in product life cycle, at which sensory evaluation is used? Initial screening, product optimization, scale up and production are the stages in product lif

Calorimetry, 240 g of water at 20 degree C are mixed with a sample of iron ...

240 g of water at 20 degree C are mixed with a sample of iron at 500 degree C. The final temperature of the system is 42 degree C. Find the mass of the iron sample

The electronic configuration, Which of the following pairs of species has s...

Which of the following pairs of species has same electronic configuration: (1) Zn 2   and Ni 2+                              (2) Co +3  and  Ni 4    (3)  Co 2+   and Ni

Explain about heterogeneous mixture, Q. Explain about heterogeneous mixture...

Q. Explain about heterogeneous mixture? A heterogeneous mixture is one that isn't blended smoothly throughout. Illustrations of heterogeneous mixtures include smoky air and m

Classification of proteins - conjugated proteins, Classification of protein...

Classification of proteins - Conjugated proteins The molecules of conjugated proteins are made up of simple proteins and non protein material. The non-protein material is known

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd