Equilibria, Chemistry

Assignment Help:

Equilibria

Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for every of these systems.

Conditions of equilibrium

For the general reaction:

aA+bB→cC+dD

The change in Gibbs free energy, ΔG (see Topic B6) for the reaction at a temperature, T, is given by:

728_gibbs energy.png 

 

Where Q is the reaction quotient,

The free energy change of both the reverse and the forward reaction is equal. This is when ΔGback=ΔG=0. In this case, the rate constants for the forward and back reactions, kf and kb, and the activities of reactants and products are such that both forward and reverse reactions are occurring at an equal rate and the reaction is at equilibrium.

 

1263_gibbs energy1.png


Related Discussions:- Equilibria

Electrochemistry, Explain about Debye huckel onsager equation of conductivi...

Explain about Debye huckel onsager equation of conductivity and its validity?

Acidity, which is more acidic among o-methoxy benzoic acid and m-methoxy be...

which is more acidic among o-methoxy benzoic acid and m-methoxy benzoic acid Ans) o-methoxy benzoic acid is more acidic than m-metoxy benzoic acid.

Physical properties - alkenes, Physical Properties - Alkenes (i) Alkene...

Physical Properties - Alkenes (i) Alkenes are odourless and colourless. (ii) Alkenes are soluble in organic solvents and insoluble in water. (iii) Physical state of Alken

Acetic acid or ethanoic acid, Acetic Acid or Ethanoic Acid Acetic acid ...

Acetic Acid or Ethanoic Acid Acetic acid is the oldest termed as fatty acid. It is the major constituent of vinegar and therefore its name (Latin acetum = vinegar)

#space lattice, #space lattice, unit cell, calculation of particles per uni...

#space lattice, unit cell, calculation of particles per unit cell, laws of crystallography, symmetry elements in crystals, derivation of braggs equation#

Reversible and irreversible cells for asssignment, REVERSIBLE CELLS AND IRR...

REVERSIBLE CELLS AND IRREVERSIBLE CELLS DEFINITION, TYPES, CLASSIFICATION, REACTION AND DIFFERENCES

General and physical characteristic of proteins, General and physical chara...

General and physical characteristic of proteins (a) Most of them apart from chromoproteins are colourless, tasteless, and odourless. Several are amorphous but few are crystalli

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd