Equilibria, Chemistry

Assignment Help:

Equilibria

Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for every of these systems.

Conditions of equilibrium

For the general reaction:

aA+bB→cC+dD

The change in Gibbs free energy, ΔG (see Topic B6) for the reaction at a temperature, T, is given by:

728_gibbs energy.png 

 

Where Q is the reaction quotient,

The free energy change of both the reverse and the forward reaction is equal. This is when ΔGback=ΔG=0. In this case, the rate constants for the forward and back reactions, kf and kb, and the activities of reactants and products are such that both forward and reverse reactions are occurring at an equal rate and the reaction is at equilibrium.

 

1263_gibbs energy1.png


Related Discussions:- Equilibria

Inorganic chemistry, Why is that Li is the only element in group 1A that re...

Why is that Li is the only element in group 1A that reacts with dinitrogen to a nitride

Higher fatty acids - carboxylic acids, Higher fatty acids - Carboxylic acid...

Higher fatty acids - Carboxylic acids Stearic, Palmitic, and oleic acids are found in natural fats and oils like glyceryl esters. Higher fatty acids derived their names from

IUPAC Naming, Could you please provide me the priority order of polyfunctio...

Could you please provide me the priority order of polyfunctional prefixes

P-orbitals of an atom in presence of magnetic, p-orbitals of an atom in pre...

p-orbitals of an atom in presence of magnetic field are: (1)  Two fold degenerate (2) Non degenerate (3) Three fold degenerate (4) None of these Ans: Non degenerate

Rayon., what is rayon?what are the things made of it?

what is rayon?what are the things made of it?

Show experimental observations of werners theory, Q. Show Experimental obse...

Q. Show Experimental observations of werners theory? Werner showed that his postulates are consistent with experimental observations. He made use of basically three kinds of ex

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd