Equilibria, Chemistry

Assignment Help:

Equilibria

Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for every of these systems.

Conditions of equilibrium

For the general reaction:

aA+bB→cC+dD

The change in Gibbs free energy, ΔG (see Topic B6) for the reaction at a temperature, T, is given by:

728_gibbs energy.png 

 

Where Q is the reaction quotient,

The free energy change of both the reverse and the forward reaction is equal. This is when ΔGback=ΔG=0. In this case, the rate constants for the forward and back reactions, kf and kb, and the activities of reactants and products are such that both forward and reverse reactions are occurring at an equal rate and the reaction is at equilibrium.

 

1263_gibbs energy1.png


Related Discussions:- Equilibria

D-bock elements, color formation of d-block elements

color formation of d-block elements

Analytical chemistry, describe the steps involved in a sampling operation o...

describe the steps involved in a sampling operation of a chemical sample

Explain the process of threshing, Threshing The process of threshing se...

Threshing The process of threshing separates the kernels from the stalks or panicles on which they grow. Threshing may take place in the field, or at the homestead or village;

Non-benzenoid aromatics and heterocyclic compounds, Non-benzenoid aromatics...

Non-benzenoid aromatics and Heterocyclic compounds There are aromatic compounds that have structural units which are not same from benzenoid type and are termed as Non-benzeno

IInorganic chemistry, Why magnesium does not impart any colour to Bunsen fl...

Why magnesium does not impart any colour to Bunsen flame while calcium does

Equilibria, Equilibria Equilibrium can also exist in between the same s...

Equilibria Equilibrium can also exist in between the same species in two different forms e.g. liquid and solid, liquid and gas. An equilibrium constant may also be produced for

oxides and oxyacids of sulphur and nitrogen, Environmental pollution cause...

Environmental pollution caused by oxides and oxyacids f nitrogen and sulphur

Principle of atomic fluorescence spectrometry, Principle of atomic fluoresc...

Principle of atomic fluorescence spectrometry: In AFS, the analyte is converted within gaseous atoms in the ground state using a appropriate atomization technique. These are t

Polymer, how vulcanisation does changes the chareter of natural rubber

how vulcanisation does changes the chareter of natural rubber

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd