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In an electrochemical cell a redox reaction perform in two halves. Electrons are liberated by the oxidation half reaction at one electrode and go through an electrical circuit to another electrode where they are used for the reduction. The cell potential E is the potential difference between the two electrodes have to balance the thermodynamic tendency for reaction, so that the cell is in equilibrium and no electrical current flows. E is related to the molar Gibbs free energy change in the overall reaction according to
where n the number of moles of electrons passed per mole of reaction and F is the Faraday constant (9.6485×104 C mol-1).
(a) Assign a reason for each of the following statements: (i) Alkylamines are stronger bases than arylamines. (ii) Acetonitrile Is preferred as solvent for carrying out sever
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Which set of quantum numbers for an electron of an atom is not possible: (1) n=1 l=0, m=-0, s= +1/2 (2) n=1, l=1, m=-1, s= +1/2 (3) n=1, l=0, m=0, s= -1/2 (4) n=
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Which one of the following is not the characteristic of Planck's quantum theory of radiation: (1)The energy is not absorbed or emitted in whole number or multiple of quantum
1. A laboratory animal exercised on a treadmill that was connected to a weight with a mass of 250. g through a pulley. The work done by the animal raised the weight through 1.32 m.
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Various methods are employed to calculate the rate constant. The method to be adopted and the proper selection depend on the experimental condition and nature of reactants and pr
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