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In an electrochemical cell a redox reaction perform in two halves. Electrons are liberated by the oxidation half reaction at one electrode and go through an electrical circuit to another electrode where they are used for the reduction. The cell potential E is the potential difference between the two electrodes have to balance the thermodynamic tendency for reaction, so that the cell is in equilibrium and no electrical current flows. E is related to the molar Gibbs free energy change in the overall reaction according to
where n the number of moles of electrons passed per mole of reaction and F is the Faraday constant (9.6485×104 C mol-1).
Reverse Hyperconjugation : The method of hyperconjugation is as well observed in the system given below, In such type of system the effect operates in the opposite direc
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Structure of benzene - Kekule structure It has a special structure, which is even though unsaturated even then it usually behave as a saturated compound. (i) Kekule's struct
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