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In an electrochemical cell a redox reaction perform in two halves. Electrons are liberated by the oxidation half reaction at one electrode and go through an electrical circuit to another electrode where they are used for the reduction. The cell potential E is the potential difference between the two electrodes have to balance the thermodynamic tendency for reaction, so that the cell is in equilibrium and no electrical current flows. E is related to the molar Gibbs free energy change in the overall reaction according to
where n the number of moles of electrons passed per mole of reaction and F is the Faraday constant (9.6485×104 C mol-1).
Indicate whether the following thermal reactions are allowed concerted reactions by the Woodward-Hoffmann criteria. Classify the reaction according to type. On the basis of
The electronic configuration of a dipositive metal M 2+ is 2, 8, 14 and its atomic weight is 56 a.m.u. The number of neutrons in its nuclei would be: (1) 30 (2)32
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Uses of Nitro alkanes or Nitroparaffins (1) Nitro alkanes are used as solvents for polar substances such as cellulose acetate, synthetic rubber etc. (2) Nitro alkanes are us
(a) Describe how you would carry out a series of experiments to determine the molar conductivities (Λ m ) of an electrolyte at various concentrations, starting with the measurement
Ammonia is a gas for which reliable analytical methods are available to explain concentration in other gases. To measure ?ow in a 15 inch schedule 40 natural gas pipeline, pure am
An isostere is: (1) NO -2 and O 3 (2) No -2 and PO 3- 4 (3) CO 2, N 2 O, NO - 3 (4)Clo - 4 and OCN - Ans: NO -2
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