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In an electrochemical cell a redox reaction perform in two halves. Electrons are liberated by the oxidation half reaction at one electrode and go through an electrical circuit to another electrode where they are used for the reduction. The cell potential E is the potential difference between the two electrodes have to balance the thermodynamic tendency for reaction, so that the cell is in equilibrium and no electrical current flows. E is related to the molar Gibbs free energy change in the overall reaction according to
where n the number of moles of electrons passed per mole of reaction and F is the Faraday constant (9.6485×104 C mol-1).
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WITH THE HELP OF A GRAPH, STATE THE DEVIATION OF MOLAR CONDUCTIVITY OF STRONG AGAINST WEEK ELECTROLYTE.
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Q. The state of a galvanic cell without liquid junction, when its temperature and pressure are uniform, can be fully described by values of the variables T, p, and . Find an expre
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Vacancies A vacancy is a lattice position that is vacant due to the atom is missing. It is formed when the solid is formed. Vacancies are simply empty atom site.
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