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ELECTROCHEMISTRY AND ION CONCENTRATION
Activity dependence of cell voltage:
Measurement of galvanic cell potentials away from the standard state provides a convenient method for measuring ion activity and activity coefficient. As ion concentration is varied in a half-cell to vary ion activity. Equilibrium position of the half cell reduction reaction changes and that causes a change in the half-cell potential. The relationship between the activity and half-cell potential is given by the Nernst equation:
for the general half-cell reduction reaction:
aA+bB+ne-→cC+dD
Cells at equilibrium:
When a cell is at equilibrium, Ecell=0 (the 'flat battery' condition) and Q=K, the equilibrium constant for the reaction (see Topic C1). This gives the expression: which allows calculation of equilibrium constants (see Topic C1) for cell reactions from calculated or measured values.
which allows calculation of equilibrium constants for cell reactions from calculated or measured values.
how hyperconjugation accued in branched molecules?
Chemical properties of Cycloalkanes Cycloalkanes behave both such as alkenes and alkanes in their chemical properties. All cycloalkanes go through substitution reaction with ha
what reactions take place
Q. Show various methods of blanching for the vegetables? To carry out various methods of blanching for the given vegetables. • carry out various methods of blanching, and
proper definition plz
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Initially 5 mol of an ideal gas with Cv,m=12.5 J K^-1 mol^-1 are at a volume of 5 dm^3 and a temperature of 300K. If the gas is heated to 373 K and the volume changed to 10 dm^3, w
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