Electrochemistry and ion concentration, Chemistry

Assignment Help:

ELECTROCHEMISTRY AND ION CONCENTRATION

Activity dependence of cell voltage:

Measurement of galvanic cell potentials away from the standard state provides a convenient method for measuring ion activity and activity coefficient. As ion concentration is varied in a half-cell to vary ion activity. Equilibrium position of the half cell reduction reaction changes and that causes a change in the half-cell potential. The relationship between the activity and half-cell potential is given by the Nernst equation:

890_electrochemistry.png

for the general half-cell reduction reaction:

 aA+bB+ne-→cC+dD

Cells at equilibrium:

When a cell is at equilibrium, Ecell=0 (the 'flat battery' condition) and Q=K, the equilibrium constant for the reaction (see Topic C1). This gives the expression: which allows calculation of equilibrium constants (see Topic C1) for cell reactions from calculated or measured values.

 

199_electrochemistry1.png

which allows calculation of equilibrium constants for cell reactions from calculated or measured 1046_electrochemistry2.png values.


Related Discussions:- Electrochemistry and ion concentration

Determine the equilibrium constant, Q. Determine the equilibrium constant? ...

Q. Determine the equilibrium constant? At 298 K, the molar conductivities at infinite dilution of NH 4 Cl, NaOH and NaCl are 129.8,217.4 and 108.9 ohm -1 cm 2 mol -1 respect

Seperation of actinide element, how trans uranium elements are seperated by...

how trans uranium elements are seperated by solvent extraction

Advantages of icp-aes method, Advantages of ICP-AES method: The wide a...

Advantages of ICP-AES method: The wide applicability of ICP-AES in the quantitative analysis of various materials can be attributed to the following advantages. Rapid a

A cyclic ester, The lactone, a cyclic ester, can form an enolate ion, and t...

The lactone, a cyclic ester, can form an enolate ion, and this ion is alkylated by methyl iodide.

What is carcinogenic substance?, A carcinogen is any substance,  radiation ...

A carcinogen is any substance,  radiation or radionuclidethat is an agent directly involved in causing cancer. This may be due to the ability to break the genome or to the disrupti

Hello, determination the degree of hydrolysis and hydrolysis constant of sa...

determination the degree of hydrolysis and hydrolysis constant of salt by conductometric method

Explain the shelf life, Normal 0 false false false EN-U...

Normal 0 false false false EN-US X-NONE X-NONE MicrosoftInternetExplorer4

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd