Determine the crystal field stabilization energy, Chemistry

Assignment Help:

1. (a)  Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and  optical isomers of each other.  Explain.

       (b)  What other type of isomerism might one envisage arising from the reaction given in (a)?
 
2.  The aquated Cr2+  ion is sky blue in colour.   If you were to obtain  its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb?   Explain your reasoning. 
 
3.  (a)  Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well. 

       (b)  Identify which spin state is preferred based solely on the CFSE's.   
       (c)  Explain why though there is a preference for one over the other both cases are still possible.


Related Discussions:- Determine the crystal field stabilization energy

Find the resulting moisture content, Question: a) Briefly compare the w...

Question: a) Briefly compare the windrow method v/s the aerated static pile composting b) Explain, with the help of a diagram, the role of aeration in turned windrow compos

Number of unpaired electron, Number of unpaired electrons in  Mn 4+ is: ...

Number of unpaired electrons in  Mn 4+ is: (1) 3        (2) 5         (3) 6       (4) 4 Ans: 3

Explain the systems at high pressure - phase diagram, Explain the Systems a...

Explain the Systems at high pressure - Phase Diagram? Binary phase diagrams begin to look different when the pressure is greater than the critical pressure of either of the pur

Assignment, fatty acid distribution in trihydric alcohol for triacylglycero...

fatty acid distribution in trihydric alcohol for triacylglycerol formation

Vitamins - biomolecules, Vitamins - Biomolecules Additionally to air, w...

Vitamins - Biomolecules Additionally to air, water, proteins, carbohydrates, fats and mineral salts, specific organic substances needed for regulating some of the body procedur

Uses of benzoic acid - carboxylic acids, Uses of Benzoic Acid - carboxylic ...

Uses of Benzoic Acid - carboxylic acids (i) Benzoic acid is used in medicine in the form of its salts particularly as urinary antiseptic. (ii) Benzoic acid is used as sodium

Determine the final pressure and steam condenses, A 15 m 3 tank contains s...

A 15 m 3 tank contains steam at 10 bar and 300 o C. The system is then cooled until the temperature reaches 150 o C . Some of the steam condenses. a) How much heat was transf

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd