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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
All the elements of Group 13 form trioxides also known as sesquioxides of the formula, M 2 O 3 . Thallium forms stable Tl 2 0 also. The basic character of oxides increases down th
information of boron element
Stereochemical arrangement has an issue whenever an atom is bonded to two or more others. Thus triatomic substance AB2 can be bent or linear. It is observed that when a central ato
project&objectives
An element X with the electronic configuration 1s 2 , 2s 2 , 2p 6 , 3s 2 , would be expected to form the chloride with the formula: (1) XCl 3 (2) Xcl 2 (3) XCl
Anomalous behavior of Fe
Q. Estimation of synthetic food colours in foods? Food colours in various products need to be isolated, identified and then quantitatively measured for their limits. Estimatio
What is the use of bhc
Steam supply for experiments in heat A tin with a press-on lid may be used to make a steam can. Punch two holes in the lid and solder by them one long and one short pip
You are given the following data taken in several runs in a mixed flow reactor: where - r A is the measured rate of disappearance of component A, and C A is the concen
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