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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
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The ionization energy of hydrogen atom is -13.6eV. The energy required to excite the electron in a hydrogen atom from the ground state to the first excited state is (Avogadro's co
Q. Extraction of Aluminium? Aluminium cannot be extirpated economically from the silicate minerals. Therefore bauxite is the most important ore for the extraction of alumimum,
Q. Determine the Uniqueness of Carbon? Ans. Carbon forms a very large number of compounds--over 4,000,000. This is far more than the number of compounds of all other eleme
Q. Crystal Field Splitting in Octahedral Complexes? Let us consider an octahedral complex, ML6, where M is a metal ion and L stands for a ligand. The total charge on the comple
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The emf of the cell Cd/CdSO4(0.0093M)//CdSO4/Cd is 0.086V at 25°C find the value of X solution
The total number of valence electrons in 4.2 gm N - 3 of ion is ( N A is the Avogadro's number): (1) 1.6N A (2) 3.2N A
what is magnetic moment
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