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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
give a brief explaination of magnetic separation is. ?
Q. Show the Halides of Aluminium? All the four trihalides of aluminium, i.e. AIF 3 , AICI 3 ,, AlBr 3 , and AlI 3 , are known. AIF 3 , is made by treating Al 2 0 3 with HF ga
Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a primary alkyl halide and undergo SN2 rapidly.
principle of EDTA method
chemistry and mechanism of action
Tautomerism - Type of Isomerism (i) The type of isomerism in which a substance exist in two readily interconvertible different structures leading to dynamic equilibrium is know
Explain rules of pericyclic The pericyclic selection rules say absolutely nothing about the position of equilibrium in every case. These rules refer to rates of reactions, not
Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.
Explain the Phase Diagrams - Ternary Systems? A ternary system is one with three components. We can independently vary the temperature, the pressure, and two independent compos
conclusion for the project
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