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1. (a) Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and optical isomers of each other. Explain.
(b) What other type of isomerism might one envisage arising from the reaction given in (a)? 2. The aquated Cr2+ ion is sky blue in colour. If you were to obtain its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb? Explain your reasoning. 3. (a) Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well.
(b) Identify which spin state is preferred based solely on the CFSE's. (c) Explain why though there is a preference for one over the other both cases are still possible.
Physical properties of Tri-halides (i) Tri-halides is a sweet smelling colourless liquid. (ii) Tri-halides is heavy liquid. The density of it is 1.485. It boils at 61°C.
Q. Explain about Thiosulphuric Acid? Thiosulphuric acid, H 2 S 2 0 3 , has never been isolated but its salts are well known which contain the thiosulphate ion, S 2 O 2- 3 . Th
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octahedral splitting of electrons is expressed in terms of 10Dq.what would be the splitting for a d^3 high spin octahedral coordination compound?
It is a phenomenon in which compounds have same moleculer formula but different structural formula due to which they posses different physical and chemical properties.
CLARK'S METHOD OR SOAP TITRATION METHOD: This method depends upon the fact that when soluble soap is added to hard water, constituent of hard water. Ca, Mg and other heavy metals
Ninhydrin test- test of proteins Ninhydrin test : This test is specified by all proteins. While a protein is boiled along with a dilute solution of ninhydrin, a violet colour i
complete assignment for half life determination
Define Electric Potentials in the Cell? The electric potential - at a point in space is de?ned as the change in the electrical potential energy of an in?nitesimal test charge w
Give chemical reaction in support of each of the following statements: (i) The +1 oxidation state gets stabilised progressively from Ga to TI in Group (ii) All the bonds PCl5
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