Determine the crystal field stabilization energy, Chemistry

Assignment Help:

1. (a)  Reacting Pt2+ with two equivalents of each of the ligands NO2- and en, it is possible to prepare several complexes that could be described as both geometric and  optical isomers of each other.  Explain.

       (b)  What other type of isomerism might one envisage arising from the reaction given in (a)?
 
2.  The aquated Cr2+  ion is sky blue in colour.   If you were to obtain  its UV-VIS spectrum, in what wavelength range will you expect this complex to absorb?   Explain your reasoning. 
 
3.  (a)  Determine the crystal field stabilization energy (CFSE) for the high and low spin complexes of an octahedral Co2+ metal complex. Make sure to include with your answer the energy for electron pairing as well. 

       (b)  Identify which spin state is preferred based solely on the CFSE's.   
       (c)  Explain why though there is a preference for one over the other both cases are still possible.


Related Discussions:- Determine the crystal field stabilization energy

Procedure regarding purchase of laboratory related items, INTRODUCTION : I...

INTRODUCTION : In this exercise you will learn various steps and procedures adopted while purchasing lab-related items. This exercise will acquaint you with practices of preparing

Carbonyls, how to find the structure of Mn2(CO)10

how to find the structure of Mn2(CO)10

Valence electrons, what are valence electrons? and how do you write them?

what are valence electrons? and how do you write them?

The electron density between 1s and 2s orbital is, The electron density be...

The electron density between 1s and  2s orbital is : (1) High (2) Low (3) Zero (4)None of these Ans:Zero

Explain tempering, Tempering is a heat treatment method for metals and all...

Tempering is a heat treatment method for metals and alloys. In steels, tempering is completed to "toughen" the metal by transforming brittle marten site into bainite or a combinat

Show the hydrides of boron and aluminium, Q. Show  the Hydrides of Boron an...

Q. Show  the Hydrides of Boron and Aluminium? Boron forms a series of volatile hydrides which resemble in some respects, e.g., volatility and covalent nature, the hydrides of c

Orgenic, libermann nitroso reaction

libermann nitroso reaction

Correct ground state electronic configuration chromium atom, The correct gr...

The correct ground state electronic configuration of chromium atom is: (1) [Ar] 3d 5 4s 1                (2)[Ar]3d 4 4s 2      (3) [AR]3d 6 4s 0                (4

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd