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For a reversible process involving ideal gases in a closed system, show that
ΔS = Cv ln(T2/T1) for a constant volume process
ΔS = Cp ln(T2/T1) for a constant pressure process
ΔS = R ln(V2/V1) = R ln(P1/P2) for an isothermal process
b. Determine the change in entropy when 2 kg of a gas at 277 K is heated in a closed, rigid container to a temperature of 368 K. Take the specific heat at constant volume to be 1.42 KJ/Kg.K
c. Calculate the entropy change when 1 kmol of an ideal gas at 300 K and 10 bar expands to a pressure of 1 bar if the temperature stays constant.
d. What is the change in entropy when 1 kmol of an ideal gas at 335 K and 10 bar is expanded irreversibly to 300 K and 1 bar? C = 29.3 KJ/(kmol K)
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The quantity of heat liberated of absorbed when one mole of compound is formed in its standard state from its elements in their standard state is known as standard heat of formatio
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