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Q. Describe Coordinated octahedral complexes?
Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd, Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2
type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In the latter (mer-). one set of these ligands art arranged around an edge of the octahedron whereas the other set occupies the opposite edge as shown in Fig.(b).
The nucleus of the element 21 E 45 contains: (1) 45 protons and 21 neutrons (2) 21 protons and 24 neutrons (3) 21 protons and 45 neutrons (4) 24 protons and 21 n
graphical representation &mathematical treatment
The chemical reaction at one time the rate of forward and backward reaction becomes equal that state is known as Equilibrium state.
No. of valence orbitals- No of Hybrid orbitals.Apply the formula for no. of hybrid orbitals.If it exceeds 4 then the answer is 0.
Anomalous behaviour of carbon and silicon
the standard EMF of cell Pt/H2
What happens when complex compounds consist of legand?
glutamic acid standard estimation protocol
it is impossibe to synthesise orgnic compounds in the lab since life force is essential for their formation -theory is known as
an elementary idea of crystal field theory
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