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Q. Describe Coordinated octahedral complexes?
Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd, Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2
type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In the latter (mer-). one set of these ligands art arranged around an edge of the octahedron whereas the other set occupies the opposite edge as shown in Fig.(b).
Rice bran Rice bran contains primarily insoluble fiber (cellulose) and soluble fiber (hemicellulose). Insoluble fiber adds bulk to the gastrointestinal (GI) track in humans cau
Synthesis of phenothrine
Conformation energy profile for butane Conformation energy profile for butane C2-C3 bond rotation
Be's 4th electron will have four quantum numbers: n l m s (1) 1 0 0 +1/2 (2) 1 1 +1 +1/2
EXPLAIN ALLOTROPHY?
What is the net flux of the uniform electric field of Exercise 1.15 through a cube of side 20 cm oriented so that its faces are parallel to the coordinate planes?
Test of proteins - Xanthoproteic test Xanthoproteic test : A few proteins give yellow colour along with concentrated nitric acid (formation of yellow stains on fingers when wor
Electronic configuration of deuterium atom is: (1) 1s 1 (2) 2s 2 (3) 2s 1 (4) 1s 2 Ans: 1s 1
Q. Describe Peroxomonosulphuric Acid? It is also known as permonosulphuric acid. It is obtained by the action of chlorosulphuric acid on cold anhydrous hydrogen peroxide :
Pb(NO)3 + Na3Po4 --> NaNo3 + PbPO4
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