Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

Find the molecular formula for a compound, 1. A compound whose empirical fo...

1. A compound whose empirical formula is CH 3 has a molar mass of 30 g/mol. What is its molecular formula? (3 points) 2. Find the molecular formula for each of the following co

Retinaladehyde, the uses,preparation,and the reaction

the uses,preparation,and the reaction

Iupac nameing, Sir any method to learn the arrangement of functional group ...

Sir any method to learn the arrangement of functional group in poly functional compound ????

Can we vary the pressure while phases remain in equilibrium, Can we vary th...

Can we vary the pressure while phases remain in equilibrium? Consider a system containing only NH 4 Cl(s), NH 3 (g), and HCl(g). Assume that the equilibrium NH 4 Cl(s) ↔ NH

For ns orbital, For ns  orbital, the magnetic quantum number has value: ...

For ns  orbital, the magnetic quantum number has value: (1) 2             (2) 4        (3) - 1               (4) 0 Ans:0

S block , reason behind the diganol relationship of lithium and magnishim

reason behind the diganol relationship of lithium and magnishim

Insulating vessel having negligible heat capacity, 2 Kg of ice at -20 degre...

2 Kg of ice at -20 degree C is diverse with 5Kg of water 20 degree C in an insulating vessel having negligible heat capacity. Measure the final mass of water remaining in the con

PH and PKA., a solid weak acid i weighed, dissolved in water and diluted to...

a solid weak acid i weighed, dissolved in water and diluted to exactly 50ml. 25ml of the solution is taken out and is tittrated to a natural endpoin with .10M NaOH. The titrated po

Applications of hybridisation - size of the hybrid orbitals, Applications o...

Applications of hybridisation - Size of the hybrid orbitals As s- orbitals are closer to the nucleus than p- orbitals, it is reasonable to suppose that greater the s character

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd