Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

Transference numbers, a hittorf cell fitted with Ag-AgClis filled with HCl ...

a hittorf cell fitted with Ag-AgClis filled with HCl solution that contains 0.0003856g HCl/g water. A current of 2 mA is passed for exactly 3 hours. the solutions are withdrawn, we

Iupac system of nomenclature of complex compounds, IUPAC system of nomencla...

IUPAC system of nomenclature of complex compounds The naming of any organic compound relies on the name of normal parent hydrocarbon from that it has been derived. IUPAC system

Polymers., uses of the polymer bakelite

uses of the polymer bakelite

Determine the gluten content in the of flour, Q. Determine the gluten conte...

Q. Determine the gluten content in the sample of flour? After undertaking this activity, you will be able to: • assess the gluten content the given sample of flour, • c

Uncertainty in the position of an electron is zero, If uncertainty in the p...

If uncertainty in the position of an electron is zero, the uncertainty in its momentum would be: (1) Zero    (2) (3) > h/ 2γ                            (4) Infinite

Thermodynamics, Ask question #Minimu1. A laboratory animal exercised on a t...

Ask question #Minimu1. A laboratory animal exercised on a treadmill that was connected to a weight with a mass of 250. g through a pulley. The work done by the animal raised the we

Salt analysis, what is the colour of the residue for nickel in charcoal cav...

what is the colour of the residue for nickel in charcoal cavity test

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd