Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

What is optical isomerism, Isomers, which vary in the rotation of the plane...

Isomers, which vary in the rotation of the plane polarized light, are known as Optical Isomerism.

Stoichiometry Review, The combustion of propane occurs via the reaction: C3...

The combustion of propane occurs via the reaction: C3H8(g)+5O2(g)-->3C02(g)+4H2O(g) Hoe many grams of oxygen are required to burn completely 10.0g of propane?

The sulphate of a metal has the formula, The sulphate of a metal has the fo...

The sulphate of a metal has the formula M 2 (SO 4 ) 3 .   The formula for its phosphate will be: (1) M(HPO 4 ) 2                                           (2) M 3 (PO

Basic structure of polymers, Q.Illustrate the Basic structure of polymers? ...

Q.Illustrate the Basic structure of polymers? Ans. Polymers are large organic compounds made of regularly repeating units. Plastics are made of polymers. Polymers ar

Salt bridge, how does salt bridge works??

how does salt bridge works??

Law of chemical combination, law of chemical combination with aim,introduct...

law of chemical combination with aim,introduction and conclution

Nomenclature of bicyclic compounds, Nomenclature of Bicyclic compounds ...

Nomenclature of Bicyclic compounds Several hydrocarbons and their derivatives include two fused or bridged rings. The carbon atoms are common to both rings are known as bridge

Stoichiometry, What is the difference between reaction stoichiometry and co...

What is the difference between reaction stoichiometry and composition stoiciometry?

Gas stoichiometry, dry air near sea level has the following composition by ...

dry air near sea level has the following composition by volume N2=78.08 percent,O2=20.94 percent. Calculate the partial pressure of each gas if atmospheric pressure is 1.00 atm

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd