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Q. Describe Coordinated octahedral complexes?
Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd, Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2
type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In the latter (mer-). one set of these ligands art arranged around an edge of the octahedron whereas the other set occupies the opposite edge as shown in Fig.(b).
Explain the following terms: (a) Asymmetric molecule (b) R and S notations
what is attacking reagent
Electro refining of Copper Electrolyte - Aqueous copper sulphate solution (acidified) Cathode - Pure copper metal (thin rod) Anode - Impure copper metal (thick block
Q. Example on Crystal field splitting in octahedral complexes? Here four ligands lie in one plane and the other two in a plane perpendicular to the first plane. Six ligands are
Analytical test of Oxalic acid or Polyprotic acid (a) The aqueous solution turns blue litmus red. (b) The aqueous solution includes effervescences along with NaHCO 3 . (c
SILENT FEATURES OF ELECTROCHEMICAL SERIES.
prperties of s block elements?
In the discussion it asks, what is a possible extension that can be cinsidered, can u please help me , thanks :)
in ecm some have positive eo values
ionic bond has low energy
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