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Q. Describe Coordinated octahedral complexes?
Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd, Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2
type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In the latter (mer-). one set of these ligands art arranged around an edge of the octahedron whereas the other set occupies the opposite edge as shown in Fig.(b).
Explain the Liquid Water aspect of using phase rule? For a single phase of pure water, P equals 1. If we treat the water as the single species H 2 O, s is 1 and r is 0. The pha
(a) Which aqueous solution has higher concentration 1 molar or 1 molar solution of the same solute? Give reason. (b) 0.5g KCI was dissolved in 100g water and the solution origi
Resonance for the methyl group at room temperature The resonance for the methyl group at room temperature is a singlet. When the temperature is lowered, the resonance of this m
Anomalous behaviour of carbon and silicon
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calculate the volume occupied by 10000000000000000000000 molecules of a gas at 300 K & 760 mm pressure
Q. Can you explain Texture? Texture indicates the characteristic of a food and would include descriptive parameters like graininess, softness, chewiness, brittleness etc. The t
compound reacts with oxygen to form 2 oxide x and y. or analysis 1.535g of x yielded 1.365g of copper and 1.545g of y yielded 1.6 a.determine the chemical compound of x and y.b .
Completeness of a harmitian operator
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