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Q. Describe Coordinated octahedral complexes?
Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd, Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2
type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In the latter (mer-). one set of these ligands art arranged around an edge of the octahedron whereas the other set occupies the opposite edge as shown in Fig.(b).
Q. At 298.15K, the partial molar volume of CO 2 (aq) is 33cm 3 mol -1 . Estimate the percent change in the value of the Henry's law constant kH,B for aqueous CO 2 at 298.15K when
The set of quantum numbers not applicable for an electron in an atom is: (1) n= 1, l=1, m 1 = 1, m s = +1/2 (2) n= 1, l=0, m 1 = 0, m s = +1/2 (3) n= 1, l=0 m
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Draw a reaction scheme with line-bond structures that illustrates how two amino acids combine to form a dipeptide. What conformation does the peptide bond usually adopt?
The mathematical expression used for expressing the rates of chemical reaction is given below by taking two different set of chemical reactions. Reactions involving same s
Ammonia is oxidised with air to form nitric oxide in the first step to produce nitric acid. The reaction occurs in a well insulated continuous reactor based on the stoichiometry:
Q. What is Peroxodisulphuric Acid? It is also known as perdisulphuric acid or simply persulphuric acid. The acid can be obtained by the action of chlorosulphonic acid on H 2 0
lithium and beryllium markedly differ from other members of their respstive groups
Structure of Aldehydes and Ketones Carbonyl carbon atom is connected to three atoms by sigma bonds. As these bonds use Sp 2 -orbitals, they found in the same plane and are 120°
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