Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

Kinetic particle theory, 2 thermometers, A and B, are wrapped in pieces of ...

2 thermometers, A and B, are wrapped in pieces of gauze. The gauze around thermometer A is moistened with water and the gauze around thermometer B is moistened with Ether(a volatil

Iodoform, what is reaction for propanone in iodoform test

what is reaction for propanone in iodoform test

Science, unique prperties of colloids

unique prperties of colloids

Uses of selenium, Q. Uses of selenium? Uses of selenium include photoco...

Q. Uses of selenium? Uses of selenium include photocopying process of xerography, decobrisation of glasses and as a catalytic agent particularly in the isomerisation of certain

Show the structure of sulphuric acid, Q. Show the Structure of sulphuric ac...

Q. Show the Structure of sulphuric acid? Theoretical considerations require that the reaction be carried out at low temperature and high pressure. However, at low temperature,

Halides and halide complexes, Halides and halide complexes Almost all e...

Halides and halide complexes Almost all elements create thermodynamically stable halides. The general stability sequence is F>Cl>Br>I, that in covalent compounds follows the su

Trihydric alcohol, What are trihydric alcohols? What are their preparation ...

What are trihydric alcohols? What are their preparation methods? What are their physical properties?

Electronic configuration exhibits, 3d 10 4s0 electronic configuration exhi...

3d 10 4s0 electronic configuration exhibits by; (1) Zn ++                                (2) Cu ++                          (3) Cd ++                      (4) Hg ++

Intrinsic semiconductor become an extrinsic semiconductor, When does intrin...

When does intrinsic semiconductor become an extrinsic semiconductor? Illustrate. Semiconductor doping is the process which changes an intrinsic semiconductor to an extrinsic se

Explain about the defect breakdown, Explain about the Defect breakdown ...

Explain about the Defect breakdown It is because of cracks and pores at the surface. Moisture from atmosphere can collect on the surface and result in breakdown. Glazing is

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd