Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

AP Thermodynamics, Given that ?H°298 for the reaction is -92.2 kJ mol-1, wh...

Given that ?H°298 for the reaction is -92.2 kJ mol-1, which is larger, the total bond dissociation energy of the reactants or the total bond dissociation energy of the products?

Value of x, x grams of calcium carbonate was completely burnt in air.the we...

x grams of calcium carbonate was completely burnt in air.the weight of solid residue formed is 28 g.what is the vlue of x in grams?

Relative density of mercury, The temperatre of an air bubble while rising f...

The temperatre of an air bubble while rising from bottom to surface of lake remains constant but its diameter is doubled . if the pressure is equivalent to h meter of mercury colum

Zinc, GROUP 12: ZINC, CADMIUM, AND MERCURY   Group 12 substance have ...

GROUP 12: ZINC, CADMIUM, AND MERCURY   Group 12 substance have the electron design ( n -1) d 10 ns 2 with n =4, 5 and 6 for Zn, Cd and Hg, respectively. They are formally pa

Decomposition of hydrogen peroxide, how do you convert mL/s to mol/s using ...

how do you convert mL/s to mol/s using the colume of oxygen at satp?

What are the types of emulsions, Q. What are the types of emulsions? Em...

Q. What are the types of emulsions? Emulsions can be of three types: 1) Temporary emulsion: These require vigorous shaking just before they are used, as they separate out e

Empirical formula, Empirical formula Empirical formula of a substance p...

Empirical formula Empirical formula of a substance provides the simplest whole number ratio among the atoms of the various elements exist in one molecule of the elements. For i

Determine the frequency of light wave, Q. Determine the frequency of light ...

Q. Determine the frequency of light wave? Ans. The wavelength of red light is 7.0 x 10 -7 m. What is the frequency?  c = λv The first thing to remember here is that

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd