Describe coordinated octahedral complexes, Chemistry

Assignment Help:

Q. Describe Coordinated octahedral complexes?

Six-coordinated octahedral complexes of the type Mubr, Ma3b3, Ma3b2c, Ma3bcd,  Ma2bcd, Ma2bcde, Mabcd of would all give geometrical isomers. Systems with one or two bidentate ligands and rest monodentate would also give geometrical isomers. Thus we-see that with this geometry a large number of isomers are possible whether they can be isolated or separated is a different question which depends on so many factors. As we increase the number of different ligands, the possible number of isomers increases. For example, Mub2

1192_Describe Coordinated octahedral complexes.png

type of complex would give only two isomers cis- and trans-. Similarly for Ma3b3 type of complex we again get two isomers facial (fac-) and meridional (mer-) isomers. In the   former (fac-) three ligands of one type form one triangular face of the octahedron and the other three on the opposite face, Fig. (a). In  the latter (mer-). one set of these ligands art  arranged around an edge of the octahedron whereas the other set occupies the opposite edge  as shown in Fig.(b).


Related Discussions:- Describe coordinated octahedral complexes

Balancing redox equations, Q. How to balance a redox equation? Ans. ...

Q. How to balance a redox equation? Ans. Redox equations may be written and balanced by the ionic half-reaction method. Let's use the half-reaction method to balance the f

Why is the extraction of copper from pyrites is difficult?, Q)why is the ex...

Q)why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction? Ans) The Standard free energy of formation of Cu2S is greater than

Help, what is the trend for ionization energy and metals in the periodic ta...

what is the trend for ionization energy and metals in the periodic table

, calculate the ratio of the fundamental frequency of HI and D

calculate the ratio of the fundamental frequency of HI and DI

Ionization energy, ionization energy vary in 3d seris of d-block elements,h...

ionization energy vary in 3d seris of d-block elements,how and why

Define conjugate acid-base pair and buffer, Q. Define Conjugate acid-base p...

Q. Define Conjugate acid-base pair and buffer? Buffers are substances that resist changes in pH. To "balance pH" means to buffer. Weak acids and bases make good buffers.

What is a mixture experiment, Q. What is a mixture experiment? Mixture ...

Q. What is a mixture experiment? Mixture experiment is an experiment in which food quality indices are assured to depend on the relative proportion of ingredients.

Find the concentration of hydrogen ions, An aqueous solution has a hydroxyl...

An aqueous solution has a hydroxyl concentration of 1.75 x 10^-7mol/L. Find the concentration of hydrogen ions in this solution.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd