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Q. Describe about Coordination compounds?
The complexes show a wide variety of physical and chemical properties which are quite different from normal salts. These differences arise due to the differences in their structures. In view of a special mode of bonding called coordination' being involved in their formation. They are also termed as coordination compounds. In this unit we shall briefly look at some of the basic definitions related to coordination compounds, familiarise you with different types of isomerism possible in them as well as the basic rules for naming these compounds. We shall then explain the formation of complexes in terms of different prevalent theories. However we shall not deal with some other aspects such as their thermody namic and kinetic stability and reaction mechanism. These cannot be dealt with satisfactory in such course. Finally we shall consider a few applications of complexes in different fields.
Caesiurn chloride crystallises as a body centred cubic lattice and has a density of 4.0 g cm -3 . Calculate the length of the edge of the unit cell of caesium chloride crystal.
Wavelength associated with electron motion: (1) Increases with increase in speed of electron (2)Remains same irrespective of speed of electron (3) Decreases with increa
This of the following occurs when two hydrogen atoms bond with each others: (1) Potential energy is lowered (2) Kinetic energy is lowered (3) Electronic motion ceases
Formation of aniline from chlorobenzene
Assignment on coordination. Compound
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Correct configuration of Fe +3 [26] is: (1) 1s 2 , 2s 2 , 2p 6, 3s 2, 3p 6 , 3d5 (2) 1s 2 , 2s 2, sp 6 , 3s 2 , 3p 6 , 3d 3 , 4s 2 (3) 1s 2 , 2s 2 , 2p
The outer electronic structure 3s 2 3p 5 is possessed by: (1) Cl (2) O (3) Ar (4) Br ans: Cl
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