Define ionisation isomerism, Chemistry

Assignment Help:

Q. Define Ionisation Isomerism?

Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04  which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red  isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in  solution. Other examples are:

[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI

[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.


Related Discussions:- Define ionisation isomerism

Determine the crystal field stabilization energy, 1. (a)  Reacting Pt 2+ w...

1. (a)  Reacting Pt 2+ with two equivalents of each of the ligands NO 2 - and en, it is possible to prepare several complexes that could be described as both geometric and  opti

Entropy generation for the process, Two kg Ammonia (mA) at  P A = 300  kPa...

Two kg Ammonia (mA) at  P A = 300  kPa and T A = -10ºC and 1 kg Ammonia (m B ) at P B = 300 kPa and T B = 100ºC  are mixed in a constant pressure and adiabatic process. Find th

The electronic configuration of an element with atomic no., The electronic ...

The electronic configuration of an element with atomic number 7  i.e. nitrogen atom is; (1) 1s 2 , 2s 1 , 2p 3 x                               (2)  1s 2 , 2s 2 , 2p 2 x ,

Explain in detail about the allotropy, Explain in detail about the Allotrop...

Explain in detail about the Allotropy Allotropy refers only to dissimilar forms of an element within the similar phase or state of matter (i.e. different solid, liquid or gas

Electrophilic aromatic substitution reactants, Although cholrine is electro...

Although cholrine is electron withdrawing group.yet it is ortho nd para directing in electrophilic aromatic substitution reactants.why? Solution) Halogens are an exception of th

Oxidation/Reaction, Write a list of reduction half reactions for... Fe, Fe+...

Write a list of reduction half reactions for... Fe, Fe+3 Cu, Cu+1 Pb, Pb+2

What do you mean by dietary fibre, Q. What do you mean by Dietary fibre? ...

Q. What do you mean by Dietary fibre? Dietary fibre is an imporatant ingredient in food and comprises of  a diverse group of plant substances viz. celluloses, hemicelluloses, l

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd