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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
Q. What do you mean by Isomers? Ans. Compounds like butane and 2-methylpropane which have the same molecular formula but different molecular structures are called isomers
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Ratio of radii of second and first Bohr orbits of H atom: (1) 2 (2) 4 (3) 3 (4) 5 Ans: 4
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Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a primary alkyl halide and undergo SN2 rapidly.
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