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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
Q. Illustrate Strengths of Acids and Bases? Ans. Acids and bases can be classified as strong or weak . If an acid or base is strong, it ionizes completely in water. On
Carboxylate salts Carboxylate salts are less reactive than esters in nucleophilic acyl substitution reactions for two reasons. First, resonance stabilization of carboxylate s
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GROUP 2: ALKALINE EARTHS The elements known commonly as alkaline earths have atoms with the (ns) 2 design and almost always have the +2 oxidation state in their compound
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