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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
The standard EMF of Pt/H2(g)/HCl(aq)//AgCl(aq)/Ag has been experimentally determined from 0-90?C to yield the following; E?/V =0.23659 – 4.856 * 10-4t(?C) – 3.4205 * 10-4t2(?C) +
Q. Explain the Purity Tests of sesame oil? Purity tests for oils/fats would include analyzing the samples for the presence of sesame oil, cottonseed oil, linseed oil, argemone
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