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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
free energy and spontaeity
Q. Show the Isolation of Important Transition Metals? Involved in the extraction of metals. Describe the extraction of important transition metals of the first transition serie
Q. Illustrate about Werners Theory? Based on the study of a large number of compounds. Wermer gave the following postulates: • Metal atoms in complexes possess two types o
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Q. Example of octahedral complexes? Let us now turn our attention to the complexes having transition metal ion with d 2 or d 3 electrons. With these configurations, there are
onductomerty
material required
Why lead and mercury are in 1st and 2nd group of basic radicals
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