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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
The electronic configuration of calcium ion ( Ca2 + ) is: (1) 1s 1 , 2s 2, 2p 6 , 3s 2 , 3p 6 , 4s 2 (2) 1s 1 , 2s 2 , sp 6 , 3s 2 , 3p 6 , 4s 1
Ionic Radii The experimentally calculated anion-cation distances in highly ionic solids have to be interpreted on the assumption that each and every ion has a nearly fixed
Chloride of metal is MCl 2 . The formula of its phosphate will be: (1) M 2 PO 4 (2) M 3 (Po 4 ) 2 (3) M 2 (
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