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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
2p orbitals have : (1) n=1, l=2 (2) n=1, l=0 (3) n=2 l=1 (4)n=2, l=0 Ans: n=2 l=1
HOW TOLUENE CAN BE PREPARED
Effects of substituents on the acidity of phenols: Existence of electron attracting group, (for example -NO 2 , -X, - NR + 3 , -CN, -CHO, -COOH) on the benzene ring increases
Q. Illustrate Crystal Field Theory with s-orbitals? Let us start with s-orbitals which are spherically symmetrical. Any effect due to mutual repulsions between the s-electrons
whAT IS SOLID STATE
onductomerty
Q. Show Anomalous Behaviour of Oxygen? Oxygen differs considerably from the rest of the family members. Small size, very high electronegativity and non-availability of d-orbita
Why does methyl ethanoate not give iodoform test while ethyl ethanoate does? Ans) Iodoform test for esters is the test given by its products on hydrolysis methyl ethanoate give
about occurence,properties of the following metal copper.gold,mercury
Describe the process involved inthe Dewar method of separation of inert gases?
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