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Q. Define Ionisation Isomerism?
Ionisation Isomerism: when coordinated ions exchange positions with ions present in the lattice position, we get ionisation isomers. Thus compounds having the same chemical composition give different ions in solution For example, a compound [Co(NH3)5BrS04 which is violet in colour yields [co(NH3)5Br2+ and SO2-4ions in solution, whereas a red isomer of the compound [co(NH3)5Br2produces [CO(NH3)5SO4+ and Br ions in solution. Other examples are:
[Co(en)2(N02)CIlN02 and [Co(en) 2 (N02]CI
[Pt(NH3)5cI2IBr2 and [Pt(NH3)4Br2]Cl2 etc.
As the electron move away from the nucleus,its potential energy
Isomers, which vary in the orientation of groups around the double bounded carbon atoms, are known as geometrical Isomers. It is also known as Cis-Trans Isomerism.
When a molecule is shown by two or more nearly equal structures, which vary in the arrangement of electrons, then the molecule is said to exhibit resonance.
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