Define gas constant, Chemistry

Assignment Help:

The gas constant, also known as the universal, usually denoted by symbol R is a physical constant which is featured in a large number of fundamental equations in the physical sciences, such as the ideal gas law and the Nernst equation. It is equivalent to the Boltzmann constant, and is expressed in units of energy per Kelvin per mole.

Its value is:

R  = 8.314472(15) J ·K -1  · mol -1

Where the number in parentheses represents the uncertainty in the last two digits.

The gas constant occurs in the simplest equation of state, the ideal gas law.

The gas constant is the constant of proportionality (R) in the equation

                        PV = nRT

Where P is the absolute Pressure, V is the Volume,  n is the number of moles, T is the absolute Temperature.

The above equation relates the pressure and volume of a quantity of gas to the absolute temperature. The specific gas constant  of a gas or a mixture of gases ( R ) isgiven by the universal gas constant, divided by the molar mass ( M) of the gas/mixture.
The gas constant can also be defined as the pressure of the gas multiplied by its volume, divided by the number of moles of the gas multiplied by its temperature in Kelvin. Ideal gases are hypothetical i.e., they strictly obey all gas laws and have a molar volume of 22.4141 liters at standard temperature and pressure (STP), which is 273 Kelvin,     1 atmosphere. At STP, however, most gases behave like ideal gases, so the value of R is generally 0.0821 L atm / mol K or 8.3145 J / mol K. At a low temperature or under high pressure conditions the gas molecules are moving closer together and more slowly, so intermolecular forces, called Vander Waals, cause the measured pressure to be lower than expected. When the molecules are closer together, the volume of the actual molecules also becomes a higher fraction of the total volume of the gas.


Related Discussions:- Define gas constant

Addition reactions, reaction of bisulphite with acid chlorides

reaction of bisulphite with acid chlorides

Metallurgy, Write down the reactions taking place in different zones in the...

Write down the reactions taking place in different zones in the blast furnace during the extraction of iron.

s block, Why do we have Li2Co3 while other akalie metals behaviou

Why do we have Li2Co3 while other akalie metals behaviour

Quantitative Analysis, A hydrocarbon z with molecular mass 78 on combustion...

A hydrocarbon z with molecular mass 78 on combustion gave 3.384g of carbon (IV) oxide and 0.693g of water. Determine the molecular formula of Z and draw its structure. [H=1, C=12,

One of the following compound is ionic, Which one of the following compound...

Which one of the following compound is ionic: (1) KCl                             (2) CH 4               (3) Diamond              (4) H 2 Ans: KCl

Metal-metal sparingly soluble electrodes.., which one will be chosen as cat...

which one will be chosen as cathode, Ag/Ag+ or Ag/Agi/i

Benzylic halide undergo sn1 or sn2 mechanism , Will benzylic halide undergo...

Will benzylic halide undergo SN1 or SN2 mechanism ?Why? Ans) Benzyl chloride is a  primary alkyl halide and undergo SN2 rapidly.

Calculate the initial rate of polymerisation, (a) Given the values below, c...

(a) Given the values below, calculate the concentration of benzoyl peroxide required to prepare polystyrene with a number average molar mass of 400,000 by bulk free radical polymer

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd