Define gas constant, Chemistry

Assignment Help:

The gas constant, also known as the universal, usually denoted by symbol R is a physical constant which is featured in a large number of fundamental equations in the physical sciences, such as the ideal gas law and the Nernst equation. It is equivalent to the Boltzmann constant, and is expressed in units of energy per Kelvin per mole.

Its value is:

R  = 8.314472(15) J ·K -1  · mol -1

Where the number in parentheses represents the uncertainty in the last two digits.

The gas constant occurs in the simplest equation of state, the ideal gas law.

The gas constant is the constant of proportionality (R) in the equation

                        PV = nRT

Where P is the absolute Pressure, V is the Volume,  n is the number of moles, T is the absolute Temperature.

The above equation relates the pressure and volume of a quantity of gas to the absolute temperature. The specific gas constant  of a gas or a mixture of gases ( R ) isgiven by the universal gas constant, divided by the molar mass ( M) of the gas/mixture.
The gas constant can also be defined as the pressure of the gas multiplied by its volume, divided by the number of moles of the gas multiplied by its temperature in Kelvin. Ideal gases are hypothetical i.e., they strictly obey all gas laws and have a molar volume of 22.4141 liters at standard temperature and pressure (STP), which is 273 Kelvin,     1 atmosphere. At STP, however, most gases behave like ideal gases, so the value of R is generally 0.0821 L atm / mol K or 8.3145 J / mol K. At a low temperature or under high pressure conditions the gas molecules are moving closer together and more slowly, so intermolecular forces, called Vander Waals, cause the measured pressure to be lower than expected. When the molecules are closer together, the volume of the actual molecules also becomes a higher fraction of the total volume of the gas.


Related Discussions:- Define gas constant

Mole concept, 0.45 g of anhydrous oxalic acid is reacted with 50 ml of KMNO...

0.45 g of anhydrous oxalic acid is reacted with 50 ml of KMNO4 . Then normality of KMnO4 is??

Dr., naming a mu-dichloro bridge in coordination compounds

naming a mu-dichloro bridge in coordination compounds

How does the magnitude of decide the real configuration, Draw a figure to s...

Draw a figure to show splitting of degenerate d orbitals in an octahedral crystal field. How does the magnitude of decide the real configuration old orbitals in a difficult enti

Number of neutrons in heavy hydrogen atom is, Number of neutrons in heavy h...

Number of neutrons in heavy hydrogen atom is: (1) 0        (2) 1        (3) 2        (4) 3 Ans:  1

Dipole moment, why dipole moment of CH3CL is more than CH3F

why dipole moment of CH3CL is more than CH3F

Calomel electrode, Construction and working of calomel electrode with a lab...

Construction and working of calomel electrode with a labelled diagram

Determine the equilibrium concentrations for formic acid, Formic acid is a ...

Formic acid is a weak acid along with a pKa of 3.75. Name of this comes through the Latin term "formica" ("ant") since it is extremely plentiful into the secretions of several spec

Criteria of purity of organic compounds, Criteria of purity of organic comp...

Criteria of purity of organic compounds The purity of an organic compound can be determined by ascertaining its some physical constants such as m.p., b.p., defined gravity, re

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd