Define gas constant, Chemistry

Assignment Help:

The gas constant, also known as the universal, usually denoted by symbol R is a physical constant which is featured in a large number of fundamental equations in the physical sciences, such as the ideal gas law and the Nernst equation. It is equivalent to the Boltzmann constant, and is expressed in units of energy per Kelvin per mole.

Its value is:

R  = 8.314472(15) J ·K -1  · mol -1

Where the number in parentheses represents the uncertainty in the last two digits.

The gas constant occurs in the simplest equation of state, the ideal gas law.

The gas constant is the constant of proportionality (R) in the equation

                        PV = nRT

Where P is the absolute Pressure, V is the Volume,  n is the number of moles, T is the absolute Temperature.

The above equation relates the pressure and volume of a quantity of gas to the absolute temperature. The specific gas constant  of a gas or a mixture of gases ( R ) isgiven by the universal gas constant, divided by the molar mass ( M) of the gas/mixture.
The gas constant can also be defined as the pressure of the gas multiplied by its volume, divided by the number of moles of the gas multiplied by its temperature in Kelvin. Ideal gases are hypothetical i.e., they strictly obey all gas laws and have a molar volume of 22.4141 liters at standard temperature and pressure (STP), which is 273 Kelvin,     1 atmosphere. At STP, however, most gases behave like ideal gases, so the value of R is generally 0.0821 L atm / mol K or 8.3145 J / mol K. At a low temperature or under high pressure conditions the gas molecules are moving closer together and more slowly, so intermolecular forces, called Vander Waals, cause the measured pressure to be lower than expected. When the molecules are closer together, the volume of the actual molecules also becomes a higher fraction of the total volume of the gas.


Related Discussions:- Define gas constant

Chemical properties proteins - oxidation, Chemical Properties Proteins - Ox...

Chemical Properties Proteins - Oxidation Oxidation : Proteins are oxidised on putrefaction and burning. The products comprise amines, nitrogen, carbon dioxide and water. The un

Reduction of alkyne - hydrocarbon, Reduction of Alkyne: Alkynes add on ...

Reduction of Alkyne: Alkynes add on hydrogen in existence of appropriate catalysts like finely divided Ni, Pd. Determine if the triple bond is not found at the end of t

Compute the atomic packing factor, Question: (i) Differentiate between...

Question: (i) Differentiate between ionic, metallic, covalent and dipole-dipole bonds. Provide examples in each case. (ii) With regard to electronic con?guration, what do a

Moist silver oxide or dry silver oxide, Ethyl bromide can be converted into...

Ethyl bromide can be converted into ethyl alcohol using- Moist silver oxide or dry silver oxide?

.amines, Why secondary and tertiary amine doesn''t give carbylamine reactio...

Why secondary and tertiary amine doesn''t give carbylamine reaction

How many electrons can be accommodated in a sub-shell, How many electrons c...

How many electrons can be accommodated in a sub-shell for which n=3, l=1: (1) 8        (2) 6        (3) 18      (4) 32 Ans: 6

What are metal carbonyls and its classifications?, Metal carbonyls of trans...

Metal carbonyls of transition elements constitute another important class of organometallic compounds. All d-block elements which contain only carbonyl ligands are called homolepti

Relative strength of the bases, Relative strength of the bases (Basic natur...

Relative strength of the bases (Basic nature of -NH2) The dissimilarity in base strength in several amines can be described on the basis of inductive effect. The +I effect incr

THE F BLOCK ELEMENTS, DISCUSS THE WEAKNESSES OF THE VALENCE BOND THEORY AND...

DISCUSS THE WEAKNESSES OF THE VALENCE BOND THEORY AND CRYSTAL FIELD THEORY

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd