Define gas constant, Chemistry

Assignment Help:

The gas constant, also known as the universal, usually denoted by symbol R is a physical constant which is featured in a large number of fundamental equations in the physical sciences, such as the ideal gas law and the Nernst equation. It is equivalent to the Boltzmann constant, and is expressed in units of energy per Kelvin per mole.

Its value is:

R  = 8.314472(15) J ·K -1  · mol -1

Where the number in parentheses represents the uncertainty in the last two digits.

The gas constant occurs in the simplest equation of state, the ideal gas law.

The gas constant is the constant of proportionality (R) in the equation

                        PV = nRT

Where P is the absolute Pressure, V is the Volume,  n is the number of moles, T is the absolute Temperature.

The above equation relates the pressure and volume of a quantity of gas to the absolute temperature. The specific gas constant  of a gas or a mixture of gases ( R ) isgiven by the universal gas constant, divided by the molar mass ( M) of the gas/mixture.
The gas constant can also be defined as the pressure of the gas multiplied by its volume, divided by the number of moles of the gas multiplied by its temperature in Kelvin. Ideal gases are hypothetical i.e., they strictly obey all gas laws and have a molar volume of 22.4141 liters at standard temperature and pressure (STP), which is 273 Kelvin,     1 atmosphere. At STP, however, most gases behave like ideal gases, so the value of R is generally 0.0821 L atm / mol K or 8.3145 J / mol K. At a low temperature or under high pressure conditions the gas molecules are moving closer together and more slowly, so intermolecular forces, called Vander Waals, cause the measured pressure to be lower than expected. When the molecules are closer together, the volume of the actual molecules also becomes a higher fraction of the total volume of the gas.


Related Discussions:- Define gas constant

Question, Hybridisation of sulfury chloride

Hybridisation of sulfury chloride

Sis2 structure, what would be the structure of SiS2 edge sharing linking po...

what would be the structure of SiS2 edge sharing linking polyhedra?

Structure of dna and rna - biomolecules, Structure of DNA and RNA The s...

Structure of DNA and RNA The sequence of bases along with the DNA and RNA chain makes its primary structure that controls the particular properties of the nucleic acid. An RNA

Explain about radioactive dating, Q. What do you know about Radioactive Dat...

Q. What do you know about Radioactive Dating? Ans. Half-life measurements of radioactive elements in rocks and fossils can be used to determine the age of the specimen. On

Define hybridization, The distribution of electrons into Hybrid orbitals is...

The distribution of electrons into Hybrid orbitals is as per the Paulis Exclusion principle and the Hunds rule of Maximum Multiplicity.

Organic, interconversion of phenol to meta-bromo phenol

interconversion of phenol to meta-bromo phenol

Conductometric titration, how to write a good lab report on conductometri t...

how to write a good lab report on conductometri titration?

Illustrate about werners theory, Q. Illustrate about Werners Theory? Ba...

Q. Illustrate about Werners Theory? Based on the study of a large number of compounds. Wermer gave the following postulates: • Metal atoms in complexes possess two types o

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd