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A useful model of interfacial mass transport makes three assumptions:
(i) there is a difference between the concentrations of A at the interface, CA denoted CA in Phases I and II, respectively, and the bulk concentrations.
(ii) the rates of transfer in each phase are proportional to the differences between the bulk an interfacial concentrations:
(iii) the interfacial concentrations are in equilibrium:
(A) Show that the equation
(B) Find the limit of Km in the following cases:
(C) What is the physical significance of the two limits in part (B)?
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The reaction A ? B + C is known to be zero order in A and to have a rate constant of 5.0 x 10-2 mol/L·s at 25 oC. An experiment was run at 25 oC where [A]0 = 1.0 x 10-3 M. a)
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