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A useful model of interfacial mass transport makes three assumptions:
(i) there is a difference between the concentrations of A at the interface, CA denoted CA in Phases I and II, respectively, and the bulk concentrations.
(ii) the rates of transfer in each phase are proportional to the differences between the bulk an interfacial concentrations:
(iii) the interfacial concentrations are in equilibrium:
(A) Show that the equation
(B) Find the limit of Km in the following cases:
(C) What is the physical significance of the two limits in part (B)?
Two reactions have identical value of Ea. Does it the mean that they have same rate constant if run at the same temperature?Illustrate.
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