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Chain Lengthening of Aldoses (Killiani-Fischer synthesis)
The conversion of an aldose to the next higher member includes the subsequent steps :
(a) Creation of a cyanohydrin.
(b) Hydrolysis of - CN to - COOH making aldonic acid.
(c) Conversion of aldonic acid into lactone through heating.
(d) The lactone is lastly reduced along with sodium amalgam or sodium borohydride to provide the higher aldose.
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Solvay process
Sometimes more than one valence structure is possible and there shows to be no unique assignment. A familiar organic example is in the disposition of single and double C-C bonds in
After making an ester by heating a carboxylic acid with alcohol in the presence of concentrated sulfuric acid, water is added to the mixture and the ester seperates out as oily lay
The frequency corresponding to transition n= 2 to n =1 in hydrogen atom is: (1) 15.66 x 10 10 Hz (2) 24.66 x 10 14 Hz (3) 30.5
Halogen Containing Compounds Compounds that are derived from hydrocarbons by the replacement of one or more than one hydrogen atoms by the corresponding number of halogen atoms
Methods yielding mixture of amines - Hofmann's method Hofmann's method: The mixture of amines (1°, 2° and 3°) is made by the alkylation of ammonia along with alkyl halides.
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