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Q Calculate the longest wavelength that can be analysed by a rock salt crystal of spacing d = 2.82 Ao in the first order.
Data: d = 2.82 Å = 2.82 × 10-10 m; n = 1 ; λmax = ?
Solution: For longest wavelength, (sin θ) max = 1
∴ 2d (sin θ) max = λmax
(Or) λmax = 2 ×2.82 × 10-10 ×1 / 1
λmax = 5.64 × 10-10 m
Derivation
TA=300 TB=400 rA= rA=6.3(10)^12
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