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1. Sodium dodecyl sulfate is a detergent with a charged hydrophilic sulfate head group and a 12 carbon hydrocarbon tail. In solid form it exists as a monomeric molecule but upon dissolving in water at room temperature (298 K) it assembles spontaneously (ΔG = -16.4 kJ/mol) into a higher ordered micelle with the structure shown below.
A. Measurements of this process at room temperature show an enthalpy of micelle formation (ΔH) of -1.42 kJ/mol. Calculate the entropy for this reaction. Is micelle formation accompanied by an increase or decrease in the disorder of the system? Explain your answer.
B. Micelle formation is a good example of what type of noncovalent interaction?
C. Micelle formation in the presence of 0.5 M NaCl results in a more negative ΔH value of -8.49 kJ/mol with no further change in entropy compared to micelle formation in water. Is micelle formation more energetically favored in water or 0.5 M NaCl? What noncovalent interaction could account for this change in enthalpy?
Mention two salient features of immunity theory of ageing. Write the full form of ESR. What does the increase in ESR indicate?
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Roche limit: The position about a massive body where the tidal forces because of the gravity of the primary equivalent or exceed the surface gravity of a particular satellite.
Action and reaction are always equal and opposite.Then,how does a body moves?
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A dartboard with a mass of 2.20 kg is suspended from the ceiling such that it is initially at rest. A 0.030-kg dart is thrown at the dartboard with a velocity of 1.3 m/s. A
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True or False. The specific gravity of a fluid that sinks in water is greater than 1.00.
APPLICATIONS OF NEWTON'S LAWS - I 1. The conclusion from F = ma is that if F = 0 then a = 0 ! quite easy! yet how powerful ! This says that for anybody which is no
A ray of light is incident normally on an equilateral prism of refractive index 3/2 calculate devition. Ans) since the prism is equilateral therefore angle of prism is 60 0 =
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