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1. Sodium dodecyl sulfate is a detergent with a charged hydrophilic sulfate head group and a 12 carbon hydrocarbon tail. In solid form it exists as a monomeric molecule but upon dissolving in water at room temperature (298 K) it assembles spontaneously (ΔG = -16.4 kJ/mol) into a higher ordered micelle with the structure shown below.
A. Measurements of this process at room temperature show an enthalpy of micelle formation (ΔH) of -1.42 kJ/mol. Calculate the entropy for this reaction. Is micelle formation accompanied by an increase or decrease in the disorder of the system? Explain your answer.
B. Micelle formation is a good example of what type of noncovalent interaction?
C. Micelle formation in the presence of 0.5 M NaCl results in a more negative ΔH value of -8.49 kJ/mol with no further change in entropy compared to micelle formation in water. Is micelle formation more energetically favored in water or 0.5 M NaCl? What noncovalent interaction could account for this change in enthalpy?
It is the demagnetising force which is necessary to neutralize completely the magnetism in the magnetism material after the external magnetic field is reduced to zero.
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