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1. Sodium dodecyl sulfate is a detergent with a charged hydrophilic sulfate head group and a 12 carbon hydrocarbon tail. In solid form it exists as a monomeric molecule but upon dissolving in water at room temperature (298 K) it assembles spontaneously (ΔG = -16.4 kJ/mol) into a higher ordered micelle with the structure shown below.
A. Measurements of this process at room temperature show an enthalpy of micelle formation (ΔH) of -1.42 kJ/mol. Calculate the entropy for this reaction. Is micelle formation accompanied by an increase or decrease in the disorder of the system? Explain your answer.
B. Micelle formation is a good example of what type of noncovalent interaction?
C. Micelle formation in the presence of 0.5 M NaCl results in a more negative ΔH value of -8.49 kJ/mol with no further change in entropy compared to micelle formation in water. Is micelle formation more energetically favored in water or 0.5 M NaCl? What noncovalent interaction could account for this change in enthalpy?
Q Calculate the longest wavelength that can be analysed by a rock salt crystal of spacing d = 2.82 Ao in the first order. Data: d = 2.82 Å = 2.82 × 10-10 m; n = 1 ; λmax = ?
A metal has a work function of 4.80 eV. Will ultraviolet radiation with a wave length of 385 nm be able to eject a photoelectron from the metal?
Q. Collector current I c =20 mA and base current I b = 50 A. Find current gain β of a transistor. β = I C / I B = 20 X 10 -3 / 50 X 10 -6 = 400
A rectangular surface (0.14 m x 0.39 m) is oriented in a uniform electric field of 440 N/C. What is the maximum possible electric flux through the surface?
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An oil pump is drawing 25 kW of electric power while pumping oil with ρ = 860 kg/m 3 at a rate of 0.1 m 3 /s. The inlet and outlet diameters of the pipe are 8 cm and 12 cm, respec
if 2.13*106J of work must be done on a roller_coaster car to move it 3.00*102m,how large is the net force acting on the car ?
A dual-wavelength spectrometer uses 780 nm and 830 nm. The molar extinction coefficients for oxy-hemoglobin (HbO 2 ) and deoxy-hemoglobin (Hb) at these two wavelengths are: e_HbO 2
COHERENCE : 1) Visible light energy is emitted when the excited electrons in atoms undergo transitions to the ground state. 2) In ordinary light sources, these transitions
Motion Animation A car along with a non-zero initial speed has a constant acceleration whose value could be controlled through the user.
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