atomic absorption troublshouting, Chemistry

Assignment Help:
Dear sir,
We need your consultancy in a technical problem that we are confronting, and we would really appreciate your help
We are in the process of implementing the heavy metal analysis in fish and water by atomic atomic absorption spectroscopy,
I’m still in the sample preparation optimization phase, and I’m confronting some problems,

Il explain in brief the problem in my last results obtained:
For arsenic analysis, 0.2 g sample is digested with Nitric acid At 90?C for 45 min ,then placed in oven for 2 hours at 130 ?C, then diluted to desired volume

1- 0.2 g Unknown fish sample spiked with (2.5ml) 1000ppb arsenic standard, after dilution in 25 ml H2O,the theoretical value must be 100 ppb, but the practical value came out 75 ppb
2- 0.2 g Fish muscle certified reference material ,containing 12.7 mg/kg of arsenic, and since the dilution is in 50 ml, then the theoretical value must be 50.8 ppb, the practical value came out 0.57ppb

Knowing that both samples were treated in the same condition and in the same time, the difference in the end results is very weird, please advise concerning any note that can improve our work,
or detect any mistake has been made,
waiting for your reply,many thanks in advance

Related Discussions:- atomic absorption troublshouting

Assignment, How can we get assignment and earn money,?

How can we get assignment and earn money,?

Iodine value - analysis of oils and fats, Iodine value - Analysis of oils a...

Iodine value - Analysis of oils and fats Iodine value of a oil or fat is a measure of its amount of unsaturation. It is proved as the number of grams of iodine taken up by 100

Packing of atoms, how can i make an assignment on this topic?

how can i make an assignment on this topic?

Biological sicckness of soil, what is biological sickness of soil and its m...

what is biological sickness of soil and its management

Cu2+ will have the following electronic configuration, Cu 2+ will have the...

Cu 2+ will have the following electronic configuration: (1) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 6 , 3d 10 , (2) 1s 2 , 2s 2 , 2p 6 , 3s 2 , 3p 9 , 4s 1     (3) 1s 2 , 2s 2 ,

Scale formation and sludge formation in boilers, Q. Explain scale formation...

Q. Explain scale formation and sludge formation in boilers. How are they formed?     Ans Boilers are used for steam generation. When hard water is evaporated, progressively

TGA, factors affecting TGA

factors affecting TGA

Explain pseudo first order reaction, Give an example of a pseudo first orde...

Give an example of a pseudo first order reaction. Write the IUPAC name of the following: (CH 3 ) 2 C=CHCOCH 3

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd