atomic absorption troublshouting, Chemistry

Assignment Help:
Dear sir,
We need your consultancy in a technical problem that we are confronting, and we would really appreciate your help
We are in the process of implementing the heavy metal analysis in fish and water by atomic atomic absorption spectroscopy,
I’m still in the sample preparation optimization phase, and I’m confronting some problems,

Il explain in brief the problem in my last results obtained:
For arsenic analysis, 0.2 g sample is digested with Nitric acid At 90?C for 45 min ,then placed in oven for 2 hours at 130 ?C, then diluted to desired volume

1- 0.2 g Unknown fish sample spiked with (2.5ml) 1000ppb arsenic standard, after dilution in 25 ml H2O,the theoretical value must be 100 ppb, but the practical value came out 75 ppb
2- 0.2 g Fish muscle certified reference material ,containing 12.7 mg/kg of arsenic, and since the dilution is in 50 ml, then the theoretical value must be 50.8 ppb, the practical value came out 0.57ppb

Knowing that both samples were treated in the same condition and in the same time, the difference in the end results is very weird, please advise concerning any note that can improve our work,
or detect any mistake has been made,
waiting for your reply,many thanks in advance

Related Discussions:- atomic absorption troublshouting

Show two reactions have identical value of ea, Two reactions have identical...

Two reactions have identical value of Ea. Does it the mean that they have same rate constant if run at the same temperature?Illustrate.

Salt analysis, chemical reactions that takes place during salt analysis for...

chemical reactions that takes place during salt analysis for class 12

Intro chem, formula mass of hemoglobin

formula mass of hemoglobin

Evolution of the modern atomic theory, Beginning in the early nineteenth ce...

Beginning in the early nineteenth century, scientists developed models to explain the structure of the atom. As more information was discovered about the nature of the subatomic pa

Colloids, conclusion for assignment on topic applications of colloids

conclusion for assignment on topic applications of colloids

Explain the statement water has bent geometry, Explain the statement "Water...

Explain the statement "Water has bent geometry" Water has bent geometry; that is, the H-O-H bond angle is approximately tetrahedral. Repulsion among the lone pairs and the bond

Equilibrium concentrations for formic acid-conjugate base, Formic acid is a...

Formic acid is a weak acid along with a pKa of 3.75. The name comes by the Latin term "formica" ("ant") since this is very plentiful into the secretions of several species of ants,

Illustrate relative amount of two co-existing phases, Illustrate and demons...

Illustrate and demonstrate that, for correct mass balance, relative amount of two co-existing phases or micro constituents should be as given by lever rule. The lever rule giv

Define the phenomenon catenation, Carbon has maximum catenation ability. Th...

Carbon has maximum catenation ability. The self-linkage of the atoms of elements to make long chains is known as catenation.

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd