atomic absorption troublshouting, Chemistry

Assignment Help:
Dear sir,
We need your consultancy in a technical problem that we are confronting, and we would really appreciate your help
We are in the process of implementing the heavy metal analysis in fish and water by atomic atomic absorption spectroscopy,
I’m still in the sample preparation optimization phase, and I’m confronting some problems,

Il explain in brief the problem in my last results obtained:
For arsenic analysis, 0.2 g sample is digested with Nitric acid At 90?C for 45 min ,then placed in oven for 2 hours at 130 ?C, then diluted to desired volume

1- 0.2 g Unknown fish sample spiked with (2.5ml) 1000ppb arsenic standard, after dilution in 25 ml H2O,the theoretical value must be 100 ppb, but the practical value came out 75 ppb
2- 0.2 g Fish muscle certified reference material ,containing 12.7 mg/kg of arsenic, and since the dilution is in 50 ml, then the theoretical value must be 50.8 ppb, the practical value came out 0.57ppb

Knowing that both samples were treated in the same condition and in the same time, the difference in the end results is very weird, please advise concerning any note that can improve our work,
or detect any mistake has been made,
waiting for your reply,many thanks in advance

Related Discussions:- atomic absorption troublshouting

Biological or a physical-chemical treatment, A) Explain the purposes of equ...

A) Explain the purposes of equalization basins, grit chambers, primary sedimentation tanks, and waste stabilization ponds in wastewater treatment. B) Would you consider a biolog

Why formal charge does not give an accurate picture, Why Formal charge does...

Why Formal charge does not give an accurate picture Formal charge does not give an accurate picture, due to O is more electronegative than H; most of the positive charge is rea

, calculate the ratio of the fundamental frequency of HI and D

calculate the ratio of the fundamental frequency of HI and DI

Define the hydration rate, The hydration rate of the deuterium-substituted ...

The hydration rate of the deuterium-substituted styrene should vary very little, if at all, from that of styrene itself, because the deuteriums are not transferred in the rate-limi

Valency shell electronic configuration, The atomic number of an element hav...

The atomic number of an element having the valency shell electronic configuration 4s 2 4p 6   is: (1) 35      (2) 36     (3) 37     (4) 38 Ans: 35

How are formalin and trioxane related to methanol, Express the relation amo...

Express the relation among the half-life period of a reactant and its initial concentration if the reaction involved is of second order. How are formalin and trioxane related to

Chemical kinetics is study of the rates of chemical process, Chemical kinet...

Chemical kinetics is study of the rates of chemical processes.                                                                         The detailed explanation at molecular leve

Freezing and Boiling points, Calculate the molarmass of a nonelectrolyte th...

Calculate the molarmass of a nonelectrolyte that lowers the freezing point of 25.00g of water to -3.9 degrees C when 4.27 g of the substance is dissolved in the water.

Uses of glucose - biomolecules, Uses of Glucose (a) Glucose is used in ...

Uses of Glucose (a) Glucose is used in the conservation of fruits and making of jams and jellies. (b) Glucose is used in the preparation of confectionary and as a sweetening

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd