atomic absorption troublshouting, Chemistry

Assignment Help:
Dear sir,
We need your consultancy in a technical problem that we are confronting, and we would really appreciate your help
We are in the process of implementing the heavy metal analysis in fish and water by atomic atomic absorption spectroscopy,
I’m still in the sample preparation optimization phase, and I’m confronting some problems,

Il explain in brief the problem in my last results obtained:
For arsenic analysis, 0.2 g sample is digested with Nitric acid At 90?C for 45 min ,then placed in oven for 2 hours at 130 ?C, then diluted to desired volume

1- 0.2 g Unknown fish sample spiked with (2.5ml) 1000ppb arsenic standard, after dilution in 25 ml H2O,the theoretical value must be 100 ppb, but the practical value came out 75 ppb
2- 0.2 g Fish muscle certified reference material ,containing 12.7 mg/kg of arsenic, and since the dilution is in 50 ml, then the theoretical value must be 50.8 ppb, the practical value came out 0.57ppb

Knowing that both samples were treated in the same condition and in the same time, the difference in the end results is very weird, please advise concerning any note that can improve our work,
or detect any mistake has been made,
waiting for your reply,many thanks in advance

Related Discussions:- atomic absorption troublshouting

Enegey, explain the cooling curve

explain the cooling curve

Eectrochemistry, Difference between activity coefficient and mean activity...

Difference between activity coefficient and mean activity coefficiet

Analysis, factors affecting TLC in points

factors affecting TLC in points

Which bond is more strong covalent or ionic .and why? , Generally ionic bon...

Generally ionic bonds are stronger than covalent bonds. This is because in ionic bonds, electrostatic forces of attractin are involved. The positive ion (cation) and the negative

Mention the role of insoluble fibres from wheat bran, Q. Mention the role o...

Q. Mention the role of insoluble fibres from wheat bran? The insoluble fibres from the wheat bran are resistant to fermentation by colonic bacteria and increase fecal bulk by r

Explain the molecular basis for the rigor state, 1.  The pH of a 0.02 M sol...

1.  The pH of a 0.02 M solution of an acid was measured as 4.6.              a) What is the [H + ] of the solution?             b) What is the acid dissociation constant K an

Jim, If 4.5 grams of Nitrogen reacted with 2.6 grams of Hydrogen, identify ...

If 4.5 grams of Nitrogen reacted with 2.6 grams of Hydrogen, identify the following: Limiting Reactant- Excess Reactant- and Theoretical Yield:

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd