atomic absorption troublshouting, Chemistry

Assignment Help:
Dear sir,
We need your consultancy in a technical problem that we are confronting, and we would really appreciate your help
We are in the process of implementing the heavy metal analysis in fish and water by atomic atomic absorption spectroscopy,
I’m still in the sample preparation optimization phase, and I’m confronting some problems,

Il explain in brief the problem in my last results obtained:
For arsenic analysis, 0.2 g sample is digested with Nitric acid At 90?C for 45 min ,then placed in oven for 2 hours at 130 ?C, then diluted to desired volume

1- 0.2 g Unknown fish sample spiked with (2.5ml) 1000ppb arsenic standard, after dilution in 25 ml H2O,the theoretical value must be 100 ppb, but the practical value came out 75 ppb
2- 0.2 g Fish muscle certified reference material ,containing 12.7 mg/kg of arsenic, and since the dilution is in 50 ml, then the theoretical value must be 50.8 ppb, the practical value came out 0.57ppb

Knowing that both samples were treated in the same condition and in the same time, the difference in the end results is very weird, please advise concerning any note that can improve our work,
or detect any mistake has been made,
waiting for your reply,many thanks in advance

Related Discussions:- atomic absorption troublshouting

Atomic absorption spectrophotometry, Atomic absorption spectrophotometry: ...

Atomic absorption spectrophotometry: Atomic absorption spectrophotometry (AAS) concerns the absorption of radiation by the atomised analyte element in the ground state. The at

Relative density of mercury, The temperatre of an air bubble while rising f...

The temperatre of an air bubble while rising from bottom to surface of lake remains constant but its diameter is doubled . if the pressure is equivalent to h meter of mercury colum

Chm 221.., what is surface chemistry?

what is surface chemistry?

Types of interferences - atomic fluorescence spectrometry, Types of interfe...

Types of interferences: Within an atomic spectrometric method, interferences are produced through the non- analyte elements of the sample. The probable interferences that coul

Sets of quantum numbers is correct for an electron, Which of the following ...

Which of the following sets of quantum numbers is correct for an electron in 4f orbital: (1) n-=4, l=3. m+1, s= +1/2              (2) n-=4, l=4. m-4, s= -1/2

Phenol, Draw the structure of anisole and phenetole

Draw the structure of anisole and phenetole

Uses of cellulose - biomolecules, Uses of Cellulose - biomolecules (i) ...

Uses of Cellulose - biomolecules (i) Cellulose is used as such in the manufacture of cloth (cotton), canvas and gunny bags (jute) and paper (wood, bamboo, straw, etc.) (ii)

When is fresh produce to harvest, When is fresh produce to harvest? ...

When is fresh produce to harvest? Optimum quality of fruits and vegetables is obtained only when they are harvested at the optimal stage of maturity. A critical time for

Antipyretics, chemistry and mechanism of action

chemistry and mechanism of action

Write Your Message!

Captcha
Free Assignment Quote

Assured A++ Grade

Get guaranteed satisfaction & time on delivery in every assignment order you paid with us! We ensure premium quality solution document along with free turntin report!

All rights reserved! Copyrights ©2019-2020 ExpertsMind IT Educational Pvt Ltd