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Antiaromaticity - Hydrocarbon
Planar cyclic conjugated substances, less stable as compared to the relating acyclic unsaturated species are known as antiaromatic. Molecular orbital computation has provided that such compounds comprise 4nΠ electrons. In fact these cyclic elements that have electrons are termed as antiaromatic compounds and this characteristic is termed antiaromaticity.
LIMITATION OF THIRD LAW OF THERMODYNAMICS
No. of KMnO4 required to oxidise 1 mole of Fe(C2O2) in acidic medium? Solution) 1 mole of KMnO4 is required for oxidation of 1 mole of Fe(C2O2). 2KMno4+2Fe(C2O2)+6H2SO4 = K2S
Which one of the following is not isoelectronic with O 2- : (1) N- 3 (2) F - (3) Tl + (4) Na + Ans: Tl +
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Nucleophilic aromatic substitution is possible, but involves substitution of a typical leaving group rather than a hydrogen atom. Remembering that S N 2 and S N 1 mechanisms are no
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