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Addition polymerization: It involves following three mechanisms:
1. Free radical polymerization
2. Ionic polymerization mechanism
3. Coordination polymerization mechanism
Free-radical polymerization: It involves following steps:
Initial step
1. Production of free radicals by the decomposition of compounds called initiators
R-R = 2R
Initiator free radicals
The decomposition of the initiator is splitting into two identical fragments called homiletic decomposition, where each fragment carrier's one unpaired electron with it called free radical.
Chain propagation step: The free radical (R) produced in the chain initiation step adds to an alkenes to form a new free radical, which then reacts with additional monomers in a chain reaction:
R + H2C = RCH2CH2
RCH2CH2 +CH2 = RCH2CH2 :CH2
The total magnetic quantum numbers for d-orbital is given by: (1) 2 (2) 0, ± 1, ± 2 (3) 0, 1, 2 (4) 5 ans: 5
How to find the atomic structure of H
Physical properties Alkyl Halides (i) CH 3 F,CH 3 Cl, CH 3 Br and C 2 H 5 Cl are gases at room temperature. The alkyl halides up to be colourless liquids whereas higher members
cis-2-butene is a symmetrical alkene Because cis-2-butene is a symmetrical alkene, it reacts to give the similar product in either oxymercuration- reduction or hydroboration-ox
Elements upto atomic number 103 have been synthesized and studied. If a newly discovered element is found to have an atomic number 106, its electronic configuration will be: (1
In the addition of the hydrogen, halide to unsaturated alkenes in the presence of peroxides the halide adds to the carbon atom correlated to more number of hydrogen atoms and hydro
determine the no of atom in 4.5g of k
free energy and spontaeity
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Why magnesium does not impart any colour to Bunsen flame while calcium does
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