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Addition polymerization: It involves following three mechanisms:
1. Free radical polymerization
2. Ionic polymerization mechanism
3. Coordination polymerization mechanism
Free-radical polymerization: It involves following steps:
Initial step
1. Production of free radicals by the decomposition of compounds called initiators
R-R = 2R
Initiator free radicals
The decomposition of the initiator is splitting into two identical fragments called homiletic decomposition, where each fragment carrier's one unpaired electron with it called free radical.
Chain propagation step: The free radical (R) produced in the chain initiation step adds to an alkenes to form a new free radical, which then reacts with additional monomers in a chain reaction:
R + H2C = RCH2CH2
RCH2CH2 +CH2 = RCH2CH2 :CH2
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Ionic Radii The experimentally calculated anion-cation distances in highly ionic solids have to be interpreted on the assumption that each and every ion has a nearly fixed
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Complex: A very general definition of complex is, 'A compound that results from the combination of a central atom or ion and a group of atoms/ions/molecules surrounding it'. As
assignment
Electronic configuration of deuterium atom is: (1) 1s 1 (2) 2s 2 (3) 2s 1 (4) 1s 2 Ans: 1s 1
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