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1.Would you xpect the α-protons of a thioester to have a lower or higher pKa than an ester? Why? Remember the pKa values for the α-protons of several FG's: aldehyde(17), ketone(21), ester(25), amide(35).
2. Would you expect a thioester to be more or less reactive toward an acul transfer addition elimination reaction than an ester? Why or Why not? Propose a short synthesis of a thioester from the corresponding carboxylic acid, and draw the mechanism of the reaction which forms the new C-S bond.
What total volume of chloroform would be required to remove 99% of the cocaine from 100 mL of water in three successive extractions?
A 3.5 L container is filled with gas at 1.00 atm. A piston then compresses the gas to 0.250 L. What is the new pressure?
A solution composed of an equal number of moles of acetone and chloroform has a vapor pressure of 250 torr at 35 degrees celsius. (a) what would be the vapor pressure of the solution if it exhibited ideal behavior
at a particular temperature and 2.00x10-2 m concentration versus time data were collected for the reaction and a plot
When preparing the solutions for Part A, an aqueous solution of diamine and NaOH is made. Why isn't a solution of NaOH and diacid chloride in cyclohexane made
Picric acid is a monoprotic acid that has been used in the leather industry and in etching copper. However, its' laboratory use has been restricted because it dehydrates on standing and can become shock sensitive
What mass of I2 is needed to add to a 250 mL volumetric flask to produce a solution that is 0.20 M? (Enter unit as g.)
A syrup is added to an empty container with a mass of 115.25g. When 0.100 pint of syrup is added, the total mass of the container and syrup is 182.48g.
What are the concentrations of OH- and H in a 0.00075 M solution of Ba(OH)2 at 25 °C? Assume complete dissociation.
Three gases (8.00 of methane, CH4, 18.0 of ethane, C2H6, and an unknown amount of propane, C3H8) were added to the same 10.0-L container. At 23.0 degrees Celsius, the total pressure in the container is 3.50 atm. Calculate the partial pressure of e..
Discuss the differences observed in the IR and NMR spectra of 3-nitrophthalic acid and luminal that are consistent with reduction of the nitro function to an amino group
magnesium ions can be precipitated from seawater by theaddition of sodium hydroxide.how much sodium hydroxide in grams
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