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Chemiluminescence Lab Questions
Intent of lab: To synthesize 1,2-dioxetanedione which reacts with a polyaromatic molecule to produce light. 0.37g sodium percarbonate (containing 0.0035 mol H2O2) is added to test tube with 1mL of prepared (COCl)2 solution in it. (Note: in 10mL of prepared (COCl)2 solution there is 0.4mL (COCl)2 in 9.6mL CH2Cl2). 5 test tubes are used in this experiment overall.
1. What one reagent should "re-energize" the light solution after it has faded? Explain using moles and limiting reagents.
2. Draw the mechanistic arrows showing how 1,2-dioxetanedione breaks down to 2 CO2 molecules.
A balloon 15m in diameter is inflated with helium at 20 degrees Celsius. How much work is done during inflation against an external pressure 1atm.
Question about Ideal gas law, Cyclopropane is used as a general anesthetic. If a sample of cyclopropane stored in a 2.00L container at 10.0 atm
Concrete used in road construction is reinforced using steel bars in a grid, known collectively as "rebar." After many years, rebar will begin to corrode, and the concrete will weaken.
What volume of .2 M Na2SO4 will completely react with 50 mL of .135 M Ba(NO3)2
What is the pH of the solution if [OH-] of an ammonia solution is 1.0 X 10-2M?
A balloon filled with helium has a volume of 2.41 L on a warm day at 311 K. It is brought into an air-conditioned room where the temperature is 295 K. What is its new volume.
The dimerization of Nitrogen Dioxide has a rate constant of 2.45 x 10-2 L/mol min at 25 °C. What will be the concentration of NO2 after 2 minutes? given a starting concentration of NO2 = 11.5 mol/L
Compute the atomic mass of 109Ag if natural abundance of 107Ag is 51.87% & atomic mass =106.905 amu and determine the probability of particle would be located in the range
Determine which ion will precipitate first and at what concentration of sulfate ion will the first precipitate begin to form?
For each reaction, calculate the mass (in grams) of the product formed when 10.1g of the underlined reactant completely reacts. Assume that there is more than enough of the other reactant.
Enough of a monoprotic acid is dissolved in water to produce a 0.0189 M solution. The pH of the resulting solution is 6.25. Calculate the Ka for the acid.
How many mL Hydrochloric acid of 0.1 M must be added to 100 mL of a 0.2 M solution of tris base to form a buffer ( pH 7.8)?
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