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In 1897 the Swedish explorer Andreé tried to reach the North Pole in a balloon. The balloon was filled with hydrogen gas. The hydrogen gas was prepared from iron splints and diluted sulfuric acid. The reaction is
Fe(s)+H2?SO4?(aq)?FeSO4?(aq)+H2?(g)
The volume of the balloon was 4800m3and the loss of hydrogen gas during filling was estimated at 20.%.What mass of iron splints and 98% (by mass) H2?SO4?were needed to ensure the complete filling of the balloon? Assume a temperature of 0°C,a pressure of 1.0 atm during filling, and 100%yield.
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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