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1) The major mechanism by which five membered aromatic heterocycles react with electrophiles is:
A) nucleophilicaromaticsubstitutionB) electrophilic aromatic substitutionC) ionicadditionD) free radical additionE) oxidation-reduction
2) What is the stereochemical relationship of the products formed by reacting racemic lactic acid with (S)-1-phenylethylamine?
A) enantiomersB) meso compoundsC) racemicmixtureD) diastereomersE) geometric isomers
3) Which of the following reaction sequences will convert p-bromoaniline to p-bromobenzoic acid?
A) 1. NaNO2, HCl 2. CH3CO2H +B) 1. NaNO2, HCl 2. Mg, ether 3. CO2, H3OC) 1. CH3Cl, AlCl3 2. KMnO4 +D) 1. HCl 2. CH3COCl 3. NaCN, H3O +E) 1. NaNO2, HCl 2. KCN, Cu2CN2 3. H3O
Determine which H atom transition (ninitial,nfinal) was responsible for the emission of a photon with a frequency of 6.91 x 1014 Hz.
calculate the individual masses of C, H, and O in the 0.7549 g sample.
Calculate the equilibrium constant of the reaction I2(g)52 I(g) at 1000 K from the following data for I2: # = 214.36 cm
what will be the volume of the blimp at a height of 2300 m, where the temperature is 12°C?
if the syinge colume had been incorrectly read, giving a calculated system volume of 25.6 mL, what would have been the percent error in the calculated value of R?
What is the total pressure in torr of a gas in a sealed flask that contains oxygen at a partial pres. of 0.41atm and water vapor at a partial pres. of 358mmHg?
A feed stream containing a mixture of 40% n-butane, 30% n-pentane and 30% n-hexane flows into a flash unit. The flash temperature is 290 K and the flash pressure is 0.6 bar
Calculate the amount of energy needed in calories to heat 145 g of water from 22.3 degrees celsius to 75.0 degrees celsius. (water in j/g degree celsius = 4.184, cal/ g degree celsius = 1)
Calorimeters and heat capacity, If 2.500 g of Mg is burned in a constant volume calorimeter with a heat capacity of 1.10 kJ/degrees Celsius containing 1.500 L
A balloon filled with helium has a volume of 2.41 L on a warm day at 311 K. It is brought into an air-conditioned room where the temperature is 295 K. What is its new volume.
Metallic magnesium can be made by the electrolysis of molten MgCl2. What mass of Mg is formed by passing a current of 6.40 A through molten MgCl2 for 4.90 days?
an unknown liquid with boiling range of 179-181 C is insoluble in water, gives a blue green suspension with chromic acid and immediately forms a separate layer when shaken with Lucas' reagent.
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