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What is the origin of the high absorptivity absorptions

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Reference no: EM13897478

1. a) Match the five complexes grven below (by letter) with the proper spectral data in the chart below. Al1 of these complexes have low spin d6 configurations and display t'*ro d-d transitions (low absorptivity). Two additional absorptions with high molar absorptivity are observed for the bromo complexes.

A. [Co(OH2)6]3+
B [Rh(OH2)6]3+
C [RhBr6]3-

D [Rh(NH3)6]3+
E [rBr6]3-

Comnlex                       λmax(cm-1)
22.400 (low)  25.900 (low)  36,800 (high)  41,700 (high)
18.100 (low)  22200 (low)  30.100 (high)  33.900 (high)
23-900 (low)  30-100 (low)

32,700 (low)  39.100 (low)

16.600 (low)  24900 (low)

b) what is the origin of the high absorptivity absorptions and why are they only observed for two of the complexes?

Reference no: EM13897478

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