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1. The mass percentage of chloride ion in a 25.00-mL sample of seawater was determined by titrating the sample with silver nitrate, precipitating silver chloride. It took 42.58 mL of 0.2997 M silver nitrate solution to reach the equivalence point in the titration What is the mass percentage of chloride ion in the seawater if its density is 1.025 g/mL
2. The arsenic in a 1.22-g sample of a pesticide was converted to AsO43- by suitable chemical treatment. It was then titrated using Ag+ to form Ag3AsO4 as a precipitate.
(a) What is the oxidation state of As in AsO43- ?
(b) Name Ag3AsO4 by analogy to the corresponding compound containing phosphorus in place of arsenic.
(c) If it took 25.0 mL of 0.102 M Ag+ to reach the equivalence point in this titration, what is the mass percentage of arsenic in the pesticide?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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