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The potential energy of the atoms in a molecule can sometimes be approximated by the Morse Function
U=A[(e^((R-r)/S) -1)^2-1]
where r is the distance between the two atoms and A,R and S positive constants with S<<R Find the equilibrium separation ro at which U(r) is minimum. Write r=ro+x so so that x is the displacement from equilibrium and show that, for small displacements, U has the approximate form U=const+1/2 kx^2. What is the force constance k?
I solved for ro, and got ro = R, and then substituted r=ro+x to get
U=A[(e^(-x/S) -1)^2-1] .
I'm not sure how to do the next step to show for small displacements, U has the approximate form U=const+1/2 kx^2.
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