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A particle in a box model can be applied in a simplistic manner to the consideration of mobile pi electrons in a conjugated system consider vitamin A2 with 12 pi electrons. If these electrons fill the first 6 pi particle in a box energy levels by pairing spin up/ spin down then the absorption of a photon of light can occur from n=6 to the vacant n=7 level. If we consider the box containing the pi electrons to have infinite potentenian beyond the ~1210 pm length of the conjugated chain and zero potential inside: a. what are the energies of the n=1-7 levels? b. what is the energy difference between n=6 and n=7? c. what does this very approximate calculation compare with experimental values?
Historically, the solid residue that is left after the methylene chloride solution is evaporated has a lower melting point that its literature value, due to impurities. Explain what impurities are present and why.
A 3.00 g sample of a salt dissolves in 9.10 g of water to give a saturated solution at 25°C. What is the solubility (in g salt/100 g of H2O) of the salt?
What percent of the hydrogen peroxide has been decomposed in mixture of (0.10M KI = 15.0mL, H2O= 35.0 mL and 3% hydrogen peroxide= 10.0 mL) when 20.0 mL of O2 gas has been evolved
What is the kinetic energy of the emitted electrons when cesium is exposed to UV rays of frequency \rm 1.5\times 10^{15}~Hz
a solution is prepared by dissolving 396 grams of sucrose in 624 grams of water. what is the vapor pressure of this solution at 30 degrees celsius.
A gaseous reaction occurs at a constant pressure of 30.0 atm and releases 58.0 kJ of heat. Before the reaction, the volume of the system was 9.00 L.
When 7.51 grams of propane reacts with excess oxygen how many grams of carbon dioxide are formed
Calculate the pH during the titration of 29 mL of 0.2 M HNO3(aq) with 0.15 M NaOH after 10 mL of the base
Draw a mechanism to demonstrate how pyridine catalyzes the hydrolysis of acetic anhydride to two molecule of acetic acid. Is this reaction reversible? why or why not?
If the solution is 98.2 (wt/wt %) sulfuric acid and has a density of 1.83 g/mL, calculate the molarity of concentrated sulfuric acid. FW(H2SO4) = 98.086 Include unit symbol.
When you breathe the following reaction will take place: C6H12O6 (s) + 6O2 (g) --> 6CO2 (g) + 6H2O(g), how many moles of glucose are needed to produce 100.0 g of water?
A rock sample contains traces of 238U, 235U, 232Th, 208Pb, 207Pb, and 206Pb. Careful analysis shows that the ratio of the amount of 238U to 206Pb is 1.164
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