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Assignment:
1. Please explain how ionization energy changes between the atoms when we move across the row or column in periodic table? How can we relate this to eigenstates of hydrogen atom? What is the fraction dependence of hydrogen atom eigen states that explains the ionization change across a row? How does actual dependence change from that expected from hydrogen atom? What is the physical origin of this difference?
2. In hydrogen atom energy levels (W) with different m are degenerate. Yet while filling 2Px, 2Py and 2P2 of boron, carbon and hydrogen we first fill different p orbitals with one electron before filling same p orbital with 2 electron. Explain why?
3. Ionization energy changes in second row in periodic table in a non monotonic way. Explain why ionization energy drops from Be to B and then from N to O?
Show all the steps in the mechanism for the following reaction, When benzene is mixed with deuterated sulfuric acid, deuterium is slowly incorporated onto the ring. Show the mechanism for this reaction and explain how this relates the sulfonation of ..
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